Shared functions of FeS cluster assembly and Moco biosynthesis
Biochim Biophys Acta Mol Cell Res. 2024 Apr 15:119731. doi: 10.1016/j.bbamcr.2024.119731. Online ahead of print.ABSTRACTMolybdenum cofactor (Moco) biosynthesis is a complex process that involves the coordinated function of several proteins. In the recent years it has become evident that the availability of FeS clusters play an important role for the biosynthesis of Moco. First, the MoaA protein binds two [4Fe-4S] clusters per monomer. Second, the expression of the moaABCDE and moeAB operons is regulated by FNR, which senses the availability of oxygen via a functional [4Fe4S] cluster. Finally, the conversion of cyclic pyran...
Source: Biochimica et Biophysica Acta - April 17, 2024 Category: Biochemistry Authors: Muhammad Abrar Hasnat Silke Leimk ühler Source Type: research

Enhanced visible light photo ‐Fenton catalysis by Fe‐doping oligo‐layer natural molybdenite with efficient carrier spatial‐driven Fe3+/Fe2+ cycle
This study serves as a crucial reference for the advancement of photo-Fenton catalysts based on molybdenite in the treatment of organic wastewater. AbstractDeveloping cost-effective and efficient photo-Fenton catalysts is crucial for advancing photo-Fenton technology. MoS2 is a representative transition metal disulfide with attractive photoresponsiveness, making it ideal for preparing composite photo-Fenton catalysts. In this study, natural molybdenite was innovatively utilized as a source of MoS2 (OM) to synthesize a low-cost and efficient Fe@MoS2 (OMF) composite photo-Fenton catalyst by comminution and adsorption, which ...
Source: Photochemistry and Photobiology - April 16, 2024 Category: Science Authors: Rong Zhang, Zhuannian Liu, Taoli Chen Tags: RESEARCH ARTICLE Source Type: research

Bimetallic nickel molybdenum nitride catalyst with low pressure and reduced hydrogen consumption for hydrogenation of dimethyl oxalate to ethanol: the impact of reduction temperature on catalytic performance
Green Chem., 2024, Advance Article DOI: 10.1039/D4GC00142G, PaperJiang Gong, Hanqing Zhang, Weihan Shu, Fengling Zheng, Chuancai Zhang, Hao Wang, Ni Zhang, Bin Dai The bimetallic nickel molybdenum nitride (Ni3Mo3N) catalyst exhibits exceptional performance with a high EtOH yield (>97.5%) under low pressure (0.5 MPa) and minimal hydrogen consumption (H2/DMO (mol)) conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Green Chem. latest articles)
Source: RSC - Green Chem. latest articles - April 15, 2024 Category: Chemistry Authors: Jiang Gong Source Type: research

Intercalating potassium-aqua complex cation into α-MoO3 layer without reducing molybdenum: a potential storage system
Chem. Commun., 2024, Accepted Manuscript DOI: 10.1039/D4CC01400F, CommunicationDebu Jana, Shalini Sanjay Mishra, Samar K Das We have demonstarted a green aqueous synthesis of rod-shaped MoO3 material, [MoVI3O9{K(H2O)4}(CH3COO)] ∙H2O (2) intercalating potassium-aqua-complex acetate into its lamellar space, simply by ion-exchange of Co(II)-aqua-complex in compound [MoVI4O12(CH3COO)2{CoII(H2O)6}]∙2H2O (1) by... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - April 15, 2024 Category: Chemistry Authors: Debu Jana Source Type: research

Cobalt Molybdate Nanoflowers Decorated Bio-waste Derived Porous Activated Carbon Nanocomposite: A High Performance Electrode Material for Supercapacitors
This study reveals the exceptional electrochemical properties of β-CoMoO4@POAC which could be considered as a potential material for advanced energy storage devices.PMID:38621491 | DOI:10.1016/j.chemosphere.2024.141965 (Source: Chemosphere)
Source: Chemosphere - April 15, 2024 Category: Chemistry Authors: Vaishali M S Priyadarshini N Kiran Kumar Tadi Ilaiyaraja P Source Type: research

Cobalt Molybdate Nanoflowers Decorated Bio-waste Derived Porous Activated Carbon Nanocomposite: A High Performance Electrode Material for Supercapacitors
This study reveals the exceptional electrochemical properties of β-CoMoO4@POAC which could be considered as a potential material for advanced energy storage devices.PMID:38621491 | DOI:10.1016/j.chemosphere.2024.141965 (Source: Chemosphere)
Source: Chemosphere - April 15, 2024 Category: Chemistry Authors: Vaishali M S Priyadarshini N Kiran Kumar Tadi Ilaiyaraja P Source Type: research

Deoxygenative Coupling of Carbonyl Compounds with Alkynes under Molybdenum Catalysis
Synfacts 2024; 20: 0502- DOI: 10.1055/s-0043-1763913 Georg Thieme Verlag KG Rüdigerstraße 14, 70469 Stuttgart, GermanyArticle in Thieme eJournals: Table of contents  |  Full text (Source: Synfacts)
Source: Synfacts - April 15, 2024 Category: Chemistry Tags: Metals in Synthesis Source Type: research

Vacancy engineering in MoS2 nanolayers coupled with dual-carbon confinement for potassium storage
New J. Chem., 2024, Accepted Manuscript DOI: 10.1039/D4NJ00785A, PaperXiaotong Wei, Shuang Tian, Tengteng Wang, Xue Zhang, Jingyi Huang, Peibo Gao, Yu Feng, Huanian Zhang, Jin Zhou, Tong Zhou Molybdenum disulfide (MoS2) has gained a lot of interest as a potassium storage material with a high anode capacity. However, the slow reaction kinetics, as well as its highly unstable... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - New J. Chem. latest articles)
Source: RSC - New J. Chem. latest articles - April 14, 2024 Category: Chemistry Authors: Xiaotong Wei Source Type: research

The effect of secondary phase on corrosion behaviors of the titanium –zirconium–molybdenum alloy
AbstractAs the range of applications for molybdenum and its alloys has expanded, the corrosive environment for molybdenum alloys has become more demanding. In the past, the content of doping elements has been studied to investigate their influence on the corrosion performance of titanium –zirconium–molybdenum (TZM) alloys. In this paper, it is considered that the second phase in the alloy is the main factor affecting the corrosion performance of TZM alloys. By comparing the corrosion behavior of molybdenum metal and TZM alloy, the effect of the secondary phase on corrosion behav iors of TZM alloy has been investigated....
Source: European Journal of Applied Physiology - April 11, 2024 Category: Physiology Source Type: research

Synthesized molybdenite reference materials for in situ molybdenum and sulfur isotope measurement using laser ablation MC-ICP-MS
J. Anal. At. Spectrom., 2024, Accepted Manuscript DOI: 10.1039/D4JA00008K, PaperJing Tian, Zhian Bao, Kaiyun Chen, Nan Lv, Wenqiang Yang, Xiaojuan Nie, Honglin Yuan Analyzing sulfur (S) and molybdenum (Mo) isotope ratios in molybdenite, the most common sulfide mineral, is crucial for studying the genesis of ore deposits. However, it is necessary to prepare... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - J. Anal. At. Spectrom. latest articles)
Source: RSC - J. Anal. At. Spectrom. latest articles - April 11, 2024 Category: Chemistry Authors: Jing Tian Source Type: research

Preparation of MOF-derived molybdenum-carbide-modified PtCu nano-alloy catalysts and their methanol oxidation performance
New J. Chem., 2024, Advance Article DOI: 10.1039/D3NJ05511F, PaperXuanhua Zhang, Chao Wang, Chao Luan, Mengyin Liao, Wenyuan Xu The catalytic performance of Pt0.10/Cu-MoC catalyst is higher than that of commercial Pt/C. After stability test, the performance has reserved to 79.2% of the initial value, and the onset potential for CO oxidation is lower than that of commercial Pt/C. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - New J. Chem. latest articles)
Source: RSC - New J. Chem. latest articles - April 10, 2024 Category: Chemistry Authors: Xuanhua Zhang Source Type: research

Bioinspired sulfur-surrounded iron catalyst for ammonia synthesis
J. Mater. Chem. A, 2024, Accepted Manuscript DOI: 10.1039/D4TA00710G, PaperNa Zhang, Yubing Si, Qiang Fu, Xing Chen A nitrogenase-inspired inorganic compound consisting of iron (Fe) and molybdenum disulfide (MoS2) is designed with a promising capability of N2 fixation from first principles. Three Fe atoms are anchored on... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - J. Mater. Chem. latest articles)
Source: RSC - J. Mater. Chem. latest articles - April 9, 2024 Category: Chemistry Authors: Na Zhang Source Type: research

Molecules, Vol. 29, Pages 1695: Core & ndash;Shell CoS2@MoS2 with Hollow Heterostructure as an Efficient Electrocatalyst for Boosting Oxygen Evolution Reaction
In this study, a well-designed electrocatalyst featuring a core–shell structure was synthesized with cobalt sulfides as the core and molybdenum disulfide nanosheets as the shell. The core–shell structure can prevent the agglomeration of MoS2, expose more active sites, and facilitate electrolyte ion diffusion. A CoS2/MoS2 heterostructure is formed between CoS2 and MoS2 through the chemical interaction, and the surface chemistry is adjusted. Due to the morphological merits and the formation of the CoS2/MoS2 heterostructure, CoS2@MoS2 exhibits excellent electrocatalytic performance during the oxyge...
Source: Molecules - April 9, 2024 Category: Chemistry Authors: Donglei Guo Jiaqi Xu Guilong Liu Xu Yu Tags: Article Source Type: research

Effects of multiple metals exposure on abnormal liver function: The mediating role of low-density lipoprotein cholesterol
This study may provide critical public health significances in liver injury prevention and scientific evidence for the establishment of environmental standard.PMID:38574647 | DOI:10.1016/j.ecoenv.2024.116283 (Source: Ecotoxicology and Environmental Safety)
Source: Ecotoxicology and Environmental Safety - April 4, 2024 Category: Environmental Health Authors: Xu Han Ziquan Lv Mei'an He Jinquan Cheng Yanwei Zhang Tian Wang Jiaxin Chen Yuewei Liu Dongsheng Hu Xuli Wu Rihong Zhai Hui Huang Suli Huang Source Type: research

Effects of multiple metals exposure on abnormal liver function: The mediating role of low-density lipoprotein cholesterol
This study may provide critical public health significances in liver injury prevention and scientific evidence for the establishment of environmental standard.PMID:38574647 | DOI:10.1016/j.ecoenv.2024.116283 (Source: Ecotoxicology and Environmental Safety)
Source: Ecotoxicology and Environmental Safety - April 4, 2024 Category: Environmental Health Authors: Xu Han Ziquan Lv Mei'an He Jinquan Cheng Yanwei Zhang Tian Wang Jiaxin Chen Yuewei Liu Dongsheng Hu Xuli Wu Rihong Zhai Hui Huang Suli Huang Source Type: research