Highly Boosted Energy Storage Performance of Few-Layered MoS2 Utilized by Improved Electrode Fabrication: Experimental and Theoretical Studies
J. Mater. Chem. A, 2024, Accepted Manuscript DOI: 10.1039/D4TA01713G, PaperZeyad M. Abdulhamid, Abhishek C. Lokhande, Adewale Hammed Pasanaje, Daniel S Choi, Nirpendra Singh, Kyriaki Polychronopoulou, Dalaver H. Anjum Few-layer two-dimensional (2D) molybdenum disulfide (MoS2) has great potential in designing high-performance supercapacitors due to its high theoretical specific capacity, tunable bandgap, and fascinating 2D layered structure. However, the lack... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - J. Mater. Chem. latest articles)
Source: RSC - J. Mater. Chem. latest articles - April 22, 2024 Category: Chemistry Authors: Zeyad M. Abdulhamid Source Type: research

Homoleptic Hexa and Penta Coordinated Gallium(I) Amide Complexes of Ruthenium and Molybdenum
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Raphael B ühler, Richard Johannes Josef Weininger, Johannes Stephan, Maximilian Muhr, Balasai Marie-Teres Bock, Christian Gemel, Roland A. Fischer Reaction of neutral olefin complexes of ruthenium and molybdenum with GaTMP (TMP = 2,2,6,6-tetramethylpiperidinyl) by substitution leads to the formation of respective five and six coordinated homoleptic products. [Ru(GaTMP)5] (1)... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 21, 2024 Category: Chemistry Authors: Raphael B ühler Source Type: research

Molecules, Vol. 29, Pages 1858: Recent Progress in Two-Dimensional Nanomaterials for Flame Retardance and Fire-Warning Applications
ei Wang Graphene-like 2D nanomaterials, such as graphene, MXene, molybdenum disulfide, and boron nitride, present a promising avenue for eco-friendly flame retardants. Their inherent characteristics, including metal-like conductivity, high specific surface area, electron transport capacity, and solution processability, make them highly suitable for applications in both structural fire protection and fire alarm systems. This review offers an up-to-date exploration of advancements in flame retardant composites, utilizing pristine graphene-like nanosheets, versatile graphene-like nanosheets with multiple functions, and co...
Source: Molecules - April 19, 2024 Category: Chemistry Authors: Weiliang Lin Yao Yuan Lulu Xu Wei Wang Tags: Review Source Type: research

Computational design of cooperatively acting molecular catalyst systems: carbene based tungsten- or molybdenum-catalysts with rhodium- or iridium-complexes for the ionic hydrogenation of N2 to NH3
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Totan Mondal, Walter Leitner, Markus H ölscher Low activation barriers allow for NH3 synthesis from N2/H2 using cooperatively acting catalysts based on carbene pincer complexes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 18, 2024 Category: Chemistry Authors: Totan Mondal Source Type: research

A bioinspired sulfur-surrounded iron catalyst for ammonia synthesis
J. Mater. Chem. A, 2024, Advance Article DOI: 10.1039/D4TA00710G, PaperNa Zhang, Yubing Si, Qiang Fu, Xing Chen A nitrogenase-inspired inorganic compound consisting of iron (Fe) and molybdenum disulfide (MoS2) is designed with a promising capability of N2 fixation using first principles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - J. Mater. Chem. latest articles)
Source: RSC - J. Mater. Chem. latest articles - April 18, 2024 Category: Chemistry Authors: Na Zhang Source Type: research

Bis[tris(diisobutyldithiocarbamato)- μ 3-sulfido-tri- μ 2-disulfido-trimolybdenum(IV)] sulfide tetrahydrofuran monosolvate
The title compound, [Mo3(C9H18NS2)3(S2)3S]2S, crystallizes on a general position in the monoclinic space group P21/n (No. 14). The cationic [Mo3S7(S2CNiBu2)3]+ fragments are joined by a monosulfide dianion that forms close S...S contacts to each of the disulfide ligands on the side of the Mo3 plane opposite the μ 32 − ligand. The two Mo3 planes are inclined at an angle of 40.637   (15) ° , which gives the assembly an open clamshell-like appearance. One μ 6-S2 − ...S22 − contact, at 2.4849   (14)   Å , is appreciably shorter than the remaining five, which are in the range 2.7252   (13) – 2.8077   (14) ...
Source: Acta Crystallographica Section E - April 18, 2024 Category: Chemistry Authors: Fraker, A. Donahue, J.P. McSkimming, A. Tags: molybdenum sulfide cluster dithiocarbamate ligand μ 6-sulfide ligand crystal structure research communications Source Type: research

Shared functions of FeS cluster assembly and Moco biosynthesis
Biochim Biophys Acta Mol Cell Res. 2024 Apr 15:119731. doi: 10.1016/j.bbamcr.2024.119731. Online ahead of print.ABSTRACTMolybdenum cofactor (Moco) biosynthesis is a complex process that involves the coordinated function of several proteins. In the recent years it has become evident that the availability of FeS clusters play an important role for the biosynthesis of Moco. First, the MoaA protein binds two [4Fe-4S] clusters per monomer. Second, the expression of the moaABCDE and moeAB operons is regulated by FNR, which senses the availability of oxygen via a functional [4Fe4S] cluster. Finally, the conversion of cyclic pyran...
Source: Biochimica et Biophysica Acta - April 17, 2024 Category: Biochemistry Authors: Muhammad Abrar Hasnat Silke Leimk ühler Source Type: research

Enhanced visible light photo ‐Fenton catalysis by Fe‐doping oligo‐layer natural molybdenite with efficient carrier spatial‐driven Fe3+/Fe2+ cycle
This study serves as a crucial reference for the advancement of photo-Fenton catalysts based on molybdenite in the treatment of organic wastewater. AbstractDeveloping cost-effective and efficient photo-Fenton catalysts is crucial for advancing photo-Fenton technology. MoS2 is a representative transition metal disulfide with attractive photoresponsiveness, making it ideal for preparing composite photo-Fenton catalysts. In this study, natural molybdenite was innovatively utilized as a source of MoS2 (OM) to synthesize a low-cost and efficient Fe@MoS2 (OMF) composite photo-Fenton catalyst by comminution and adsorption, which ...
Source: Photochemistry and Photobiology - April 16, 2024 Category: Science Authors: Rong Zhang, Zhuannian Liu, Taoli Chen Tags: RESEARCH ARTICLE Source Type: research

Bimetallic nickel molybdenum nitride catalyst with low pressure and reduced hydrogen consumption for hydrogenation of dimethyl oxalate to ethanol: the impact of reduction temperature on catalytic performance
Green Chem., 2024, Advance Article DOI: 10.1039/D4GC00142G, PaperJiang Gong, Hanqing Zhang, Weihan Shu, Fengling Zheng, Chuancai Zhang, Hao Wang, Ni Zhang, Bin Dai The bimetallic nickel molybdenum nitride (Ni3Mo3N) catalyst exhibits exceptional performance with a high EtOH yield (>97.5%) under low pressure (0.5 MPa) and minimal hydrogen consumption (H2/DMO (mol)) conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Green Chem. latest articles)
Source: RSC - Green Chem. latest articles - April 15, 2024 Category: Chemistry Authors: Jiang Gong Source Type: research

Intercalating potassium-aqua complex cation into α-MoO3 layer without reducing molybdenum: a potential storage system
Chem. Commun., 2024, Accepted Manuscript DOI: 10.1039/D4CC01400F, CommunicationDebu Jana, Shalini Sanjay Mishra, Samar K Das We have demonstarted a green aqueous synthesis of rod-shaped MoO3 material, [MoVI3O9{K(H2O)4}(CH3COO)] ∙H2O (2) intercalating potassium-aqua-complex acetate into its lamellar space, simply by ion-exchange of Co(II)-aqua-complex in compound [MoVI4O12(CH3COO)2{CoII(H2O)6}]∙2H2O (1) by... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - April 15, 2024 Category: Chemistry Authors: Debu Jana Source Type: research

Cobalt Molybdate Nanoflowers Decorated Bio-waste Derived Porous Activated Carbon Nanocomposite: A High Performance Electrode Material for Supercapacitors
This study reveals the exceptional electrochemical properties of β-CoMoO4@POAC which could be considered as a potential material for advanced energy storage devices.PMID:38621491 | DOI:10.1016/j.chemosphere.2024.141965 (Source: Chemosphere)
Source: Chemosphere - April 15, 2024 Category: Chemistry Authors: Vaishali M S Priyadarshini N Kiran Kumar Tadi Ilaiyaraja P Source Type: research

Cobalt Molybdate Nanoflowers Decorated Bio-waste Derived Porous Activated Carbon Nanocomposite: A High Performance Electrode Material for Supercapacitors
This study reveals the exceptional electrochemical properties of β-CoMoO4@POAC which could be considered as a potential material for advanced energy storage devices.PMID:38621491 | DOI:10.1016/j.chemosphere.2024.141965 (Source: Chemosphere)
Source: Chemosphere - April 15, 2024 Category: Chemistry Authors: Vaishali M S Priyadarshini N Kiran Kumar Tadi Ilaiyaraja P Source Type: research

Deoxygenative Coupling of Carbonyl Compounds with Alkynes under Molybdenum Catalysis
Synfacts 2024; 20: 0502- DOI: 10.1055/s-0043-1763913 Georg Thieme Verlag KG Rüdigerstraße 14, 70469 Stuttgart, GermanyArticle in Thieme eJournals: Table of contents  |  Full text (Source: Synfacts)
Source: Synfacts - April 15, 2024 Category: Chemistry Tags: Metals in Synthesis Source Type: research

Vacancy engineering in MoS2 nanolayers coupled with dual-carbon confinement for potassium storage
New J. Chem., 2024, Accepted Manuscript DOI: 10.1039/D4NJ00785A, PaperXiaotong Wei, Shuang Tian, Tengteng Wang, Xue Zhang, Jingyi Huang, Peibo Gao, Yu Feng, Huanian Zhang, Jin Zhou, Tong Zhou Molybdenum disulfide (MoS2) has gained a lot of interest as a potassium storage material with a high anode capacity. However, the slow reaction kinetics, as well as its highly unstable... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - New J. Chem. latest articles)
Source: RSC - New J. Chem. latest articles - April 14, 2024 Category: Chemistry Authors: Xiaotong Wei Source Type: research

The effect of secondary phase on corrosion behaviors of the titanium –zirconium–molybdenum alloy
AbstractAs the range of applications for molybdenum and its alloys has expanded, the corrosive environment for molybdenum alloys has become more demanding. In the past, the content of doping elements has been studied to investigate their influence on the corrosion performance of titanium –zirconium–molybdenum (TZM) alloys. In this paper, it is considered that the second phase in the alloy is the main factor affecting the corrosion performance of TZM alloys. By comparing the corrosion behavior of molybdenum metal and TZM alloy, the effect of the secondary phase on corrosion behav iors of TZM alloy has been investigated....
Source: European Journal of Applied Physiology - April 11, 2024 Category: Physiology Source Type: research