An Aqueous Room-Temperature Phosphorescent Probe for Gd3+
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06229H, CommunicationJiazhuo Li, Ying Wang, Xiaoming Jiang, Peng Wu An aqueous room-temperature phosphorescent (RTP) probe for Gd3+ is reported, based on Gd3+-induced intersystem promoting and the oxygen-shielding property of the Gd3+/AMP/fluorescein coordination polymer nanoparticles (CPNs). Besides selective Gd3+ detection,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 18, 2022 Category: Chemistry Authors: Jiazhuo Li Source Type: research

MicroRNA detection using light-up aptamer amplification based on nuclease protection transcription
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06599H, CommunicationYoonseo Hong, Do-Eun Kim, Yu-Jin Park, Dong-Myung Kim, Ju Young Byun, Yong-Beom Shin The quantification of microRNAs (miRNAs) is important because the miRNA expression level is closely associated with the occurrence and development of diseases. Here, we report a simple nuclease protection transcription... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 18, 2022 Category: Chemistry Authors: Yoonseo Hong Source Type: research

A multidentate polymer microreactor route for green mass fabrication of mesoporous NaYF4 clusters
We report a “multidentate polymer microreactor” method for the creation of secondary structures of colloidal nanocrystals. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Yameng Li Source Type: research

Mechanism investigation of the enhanced oxygen storage performance of YBaCo4O7+ δ synthesized by a glycine-complex decomposition method
Chem. Commun., 2022, Advance Article DOI: 10.1039/D1CC06157G, CommunicationTing Ru Chen, Takuya Hasegawa, Sung Hun Cho, Tomoyo Goto, Tohru Sekino, Masato Kakihana, Shu Yin Illustration of the reason for the rapid oxygen storage rate of the low-temperature sample. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Ting Ru Chen Source Type: research

Mismatched fluorescent probes with an enhanced strand displacement reaction rate for intracellular long noncoding RNA imaging
Chem. Commun., 2022, Advance Article DOI: 10.1039/D1CC05270E, CommunicationYan Zhang, Xue-ke Du, Xianwei Su, Xiaoran Zou, Chun-yang Zhang We develop mismatched fluorescent probes to monitor the long noncoding RNA (lncRNA) in living cells. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Yan Zhang Source Type: research

Toroidal versus centripetal arrangement of the magnetic moment in a Dy4 tetrahedron
Chem. Commun., 2022, Advance Article DOI: 10.1039/D1CC06265D, CommunicationQianqian Yang, Liviu Ungur, Liviu F. Chibotaru, Jinkui Tang Aμ4–O bridgedDy4 tetrahedron shows a diamagnetic ground state originating from the toroidal arrangement of the magnetic moment rather than the centripetal anisotropies, as revealed byab initio calculations. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Qianqian Yang Source Type: research

Synthesis of β-nitro ketones from geminal bromonitroalkanes and silyl enol ethers by visible light photoredox catalysis
Chem. Commun., 2022, Advance Article DOI: 10.1039/D1CC06529G, CommunicationHaoying Cao, Shanshan Ma, Yanhong Feng, Yawen Guo, Peng Jiao Photocatalytic coupling reaction between a TMS enol ether and agem-bromonitroalkane furnishes a ketone bearing β-NO2 group on a tertiary carbon, which is easily converted into a β-NH2 ketone. α-Nitro radicals are intermediates. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Haoying Cao Source Type: research

Photoinduced remote regioselective radical alkynylation of unactivated C-H bonds
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06885G, CommunicationQu-Ping Hu, Yu-Tao Liu, Yong-Ze Liu, fei pan A method for the remote regioselective alkynylation of unactivated C(sp3)-H bonds in diverse aliphatic amides by photogenerated amidyl radicals has been developed. The site-selectivity is dominated via a 1,5-hydrogen atom... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Qu-Ping Hu Source Type: research

Correction: Selective light driven reduction of CO2 to HCOOH in water using a {MoV9}n (n = 1332 –3600) based soft-oxometalate (SOM)
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Soumitra Barman, Santu Das, Sreejith S. S., Somnath Garai, Ramudu Pochamoni, Soumyajit Roy To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Soumitra Barman Source Type: research

Migratory Cycloisomerization of 1,3-Dien-5-ynes Conjugated with Pseudopeptides in Assembly of Benzo[7]annulenes
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06533E, CommunicationHormoz Khosravi, Helya Janatian Ghazvini, Mohammad Kamangar, Frank - Rominger, Saeed Balalaie A novel domino cycloisomerization of 1,3-dien-5-ynes for the synthesis of 7H-benzo[7]annulenes is reported. The noticeable feature of this domino reaction involves the assembly of the fused bicyclic motifs through a... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Hormoz Khosravi Source Type: research

In situ generation of radical initiators with amine-borane complexes for carbohalogenation of alkenes
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06390A, CommunicationVirginie Liautard, Marine Delgado, Boris Colin, Laurent Chabaud, Guillaume Michaud, Mathieu Pucheault Atom Transfer Radical Additions of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Virginie Liautard Source Type: research

Ionic Liquids and Deep Eutectics as a Transformative Platform for the Synthesis of Nanomaterials
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Anja-Verena Mudring, Oliver Hammond Ionic liquids (ILs) are becoming a revolutionary synthesis medium for inorganic nanomaterials, permitting more efficient, safer and environmentally benign preparation of high quality products. A smart combination of ILs and... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Anja-Verena Mudring Source Type: research

Improving the kinetics and dark equilibrium of donor-acceptor Stenhouse adduct by triene backbone design
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06235B, CommunicationJulie A Peterson, Friedrich Stricker, Javier Read de Alaniz DFT calculations were used to find an optimal substitution site on the triene backbone of a donor-acceptor Stenhouse adduct photoswitch to tune the equillibrium and switching kinetics of DASA without... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Julie A Peterson Source Type: research

Unusual O2-/F- distribution in the new pyrochlore oxyfluorides: Na2B2O5F2 (B= Nb, Ta)
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06760E, CommunicationEdouard Boivin, Fr éderique Pourpoint, Sébastien Saitzek, Pardis Simon, Pascal Roussel, Houria Kabbour Two new oxyfluorides with a pyrochlore-type structure, Na2Nb2O5F2 and Na2Ta2O5F2, have been obtained and for which the XRD crystallographic study coupled with19F solid state NMR reveals an unusual O/F... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Edouard Boivin Source Type: research

Bisulfate as a Redox-active Ligand in Vanadium-based Electrocatalysis for CH4 Functionalization
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06596C, CommunicationDanlei Xiang, Sheng-Chih Lin, Jiao Deng, Hao Ming Chen, Chong Liu The roles of the unforgiving H2SO4 solvent in CH4 activation with molecular catalysts have not been experimentally well-illustrated despite computational predictions. Here we provide experimental evidence that metal-bound bisulfate ligand... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Danlei Xiang Source Type: research

Determination of IC50 value of anticancer drugs on cell by D2O -single cell Raman spectroscopy
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06857A, CommunicationWanxue Lv, Boqiang Fu, Manli Li, Yu Kang, Shouli Bai, Chao Lu A simple, sensitive and repeatable D2O-single cell Raman spectroscopy method is developed to quantify the inhibitory activity of anticancer drug on cancer cell metabolism. The IC50 values obtained from A549... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Wanxue Lv Source Type: research

Hidden Silylium-Type Reactivity of a Siloxane-Based Phosphonium –Hydroborate Ion Pair
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC07016A, CommunicationNicol ò Fontana, Noel Angel Espinosa-Jalapa, Michael Seidl, Jonathan O. Bauer A new class of siloxane-based cations with hidden silylium-type reactivity is provided, which, in combination with an arylborate counteranion, initiates a highly selective para-C(sp2) –F defunctionalization of a perfluorinated aryl group.... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Nicol ò Fontana Source Type: research

N-Confused Porphyrin-based Conjugated Microporous Polymers
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06572F, CommunicationQichuan He, Jialing Kang, Jinhui Zhu, Senhe Huang, Chenbao Lu, Hai-Wei Liang, Yuezeng Su, Xiaodong Zhuang Metal porphyrins, which possess metal-N coordination centers, are important building blocks for construction of porous organic materials with catalytic performance. However, most of previous work focused on controlling metal elements... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 17, 2022 Category: Chemistry Authors: Qichuan He Source Type: research

Pyrene-pyridyl nanooligomer as a methoxy-triggered reactive probe for highly specific fluorescence assaying of hypochlorite
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06606D, CommunicationLi Zhang, Yi Xiao, Wensheng Mao, Jiyan Huang, hongmei huang, Rong-Hua Yang, Youyu Zhang, Xiaoxiao He, Kemin Wang A novel pyrene-pyridyl conjugated oligomer (OPP-OMe) was conveniently prepared by one-pot Sonogashira coupling. Intriguingly, it was found that introducing only one methoxy moiety at the 4-pyridyl position can be sufficient... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 16, 2022 Category: Chemistry Authors: Li Zhang Source Type: research

Shape-Tunable Polymeric Janus Nanoparticles with Hollow Cavities Derived from Polymerization Induced Self-Assembly Based Crosslinked Vesicles
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06966G, CommunicationShanshan Li, Xiaobo Liu, Hao Zhang, Yuhua Mao, Tangxin Zhang, Jianli Wang Fabrications of shape-tunable polymeric Janus nanoparticles with hollow cavities derived from polymerization induced self-assembly based crosslinked vesicles are reported firstly in this work. These novel polymeric JNPs can be applied... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 15, 2022 Category: Chemistry Authors: Shanshan Li Source Type: research

A biodegradable amphiphilic poly(aminoester) dendrimer for safe and effective siRNA delivery
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06655B, CommunicationChi Ma, Dandan Zhu, Wenyi Lin, Ying Li, Yuanzheng Huang, Huiling Zhu, Mengyun Ye, Yang Wang, Ling Peng, Xiaoxuan Liu Small interfering RNA (siRNA)-based therapeutics represent a novel and compelling drug modality, provided that safe and competent vectors are available for their delivery. Here, we report a biodegradable amphiphilic poly(aminoester)... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 15, 2022 Category: Chemistry Authors: Chi Ma Source Type: research

Probing a Microviscosity Change at the Nematic-Isotropic Liquid Crystal Phase Transition by a Ratiometric Flapping Fluorophore
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06111A, CommunicationRyo Kimura, Hidetsugu Kitakado, Takuya Yamakado, Hiroyuki Yoshida, Shohei Saito Understanding the microviscosity of soft condensed matter is important to clarify the mechanisms of chemical, physical or biological events occurring at the nanoscale. Here, we report that flapping fluorophores (FLAP)... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 15, 2022 Category: Chemistry Authors: Ryo Kimura Source Type: research

Guanidinium substitution-dependent phase transitions, ionic conductivity and dielectric properties of MAPbI3
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06642K, CommunicationFernando B Minussi, Eduardo M. Bertoleti, Saulo P Reis, J. Carvalho, Eudes Borges Ara újo Over the past few years of boosting studies in halide perovskites, the formulation of guanidinium (GA+)-containing compounds has been proven to be an excellent strategy. A system in particular, namely... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 15, 2022 Category: Chemistry Authors: Fernando B Minussi Source Type: research

Evidenced cucurbit[n]uril-based host –guest interactions using single-molecule force spectroscopy
Chem. Commun., 2022, Advance Article DOI: 10.1039/D1CC06791E, CommunicationMingyang Zhang, Hao Zhang, Lunqiang Jin, Hao Li, Simin Liu, Shuai Chang, Feng Liang Enhanced guest-pair interactions, response to light stimulus or competitive host –guest recognition in cucurbit[8]uril are revealed using single-molecule force spectroscopy. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Mingyang Zhang Source Type: research

Copper(II) tetrakis(pentafluorophenyl)porphyrin: highly active copper-based molecular catalysts for electrochemical CO2 reduction
Chem. Commun., 2022, Advance Article DOI: 10.1039/D1CC05880K, CommunicationKento Kosugi, Hina Kashima, Mio Kondo, Shigeyuki Masaoka Highly active and low-overpotential electrochemical CO2 reduction can be achieved using a copper porphyrin complex bearing strong electron-withdrawing moieties. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Kento Kosugi Source Type: research

Photochemical hydrogen production based on the HCOOH/CO2 cycle promoted by a pentanuclear cobalt complex
Chem. Commun., 2022, Advance Article DOI: 10.1039/D1CC06445B, CommunicationTakuya Akai, Mio Kondo, Yutaka Saga, Shigeyuki Masaoka The first catalytic cycle for hydrogen production based on the photochemical two-electron reduction of carbon dioxide (CO2) and the dehydrogenation of formic acid at ambient temperature was demonstrated using a pentanuclear cobalt complex (Co5). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Takuya Akai Source Type: research

Diversely C8-functionalized adenine nucleosides via their underexplored carboxaldehydes
Chem. Commun., 2022, Advance Article DOI: 10.1039/D1CC06686B, CommunicationHari K. Akula, Suyeal Bae, Padmanava Pradhan, Lijia Yang, Barbara Zajc, Mahesh K. Lakshman Facile synthesis of adenosine and 2 ′-deoxyadenosine 8-carboxaldehydes provides a segue to diversely C8-functionalized adenine nucleoside analogues. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Hari K. Akula Source Type: research

Well-organised two-dimensional self-assembly controlled by in situ formation of a Cu(II)-coordinated rufigallol derivative: a scanning tunnelling microscopy study
Chem. Commun., 2022, Advance Article DOI: 10.1039/D1CC05991B, CommunicationYoshihiro Kikkawa, Mayumi Nagasaki, Seiji Tsuzuki, Thierry N. J. Fouquet, Sayaka Nakamura, Yasumasa Takenaka, Yasuo Norikane, Kazuhisa Hiratani Scanning tunnelling microscopy revealed that thein situ metal coordination of a rufigallol derivative at the solid/liquid interface enables the formation of a well-organized columnar structure. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Yoshihiro Kikkawa Source Type: research

Activation of O2 Across a C(sp3)-C(sp3) Bond
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D2CC00110A, CommunicationRahul Kumar, Stefan Richter, Suvendu Maity, Pallavi Sarkar, Nicolas Dr. Chrysochos, Swapan K. Pati, Prasanta Ghosh, Carola Schulzke, Anukul Jana The activation of atmospheric molecular dioxygen (O2) is reported which occurred across a C(sp3)-C(sp3) bond of a piperazine derivative without any catalyst at ambient condition under the formation of 1,2,4,7-dioxadiazoctane,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Rahul Kumar Source Type: research

Keggin-type Polyoxometalates as Cu(II) chelators in the context of Alzheimer ’s disease.
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC05792H, CommunicationElena Atri án-Blasco, Lucie de Cremoux, Xudong Lin, Rufus Mitchell-Heggs, Laurent Sabater, Sébastien Blanchard, Christelle Hureau Two Keggin polyoxometalates were used as new copper ligands to counteract the effects of CuII(Amyloid- β) interaction. Their ability to remove CuII from CuII(Amyloid-β), to stop CuII(Amyloid-β) induced formation of reactive... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Elena Atri án-Blasco Source Type: research

Prostate-specific membrane antigen (PSMA) targeted singlet oxygen delivery via endoperoxide tethered ligands
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Lei Wang, Lei Tang, Yingjie Liu, Hao Wu, Ziang Liu, Jin Li, Yue Pan, Engin U. Akkaya A PSMA targeting ligand is functionalized with endoperoxides which thermally release singlet oxygen. The results show that this modular design results in significantly more cell death in PSMA-expressing prostate cancer cells. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Lei Wang Source Type: research

Diastereoselective palladium-catalyzed functionalization of prochiral C(sp3) –H bonds of aliphatic and alicyclic compounds
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC05649B, Feature ArticleSrinivasarao Arulananda Babu, Yashika Aggarwal, Pooja Patel, Radha Tomar We highlight the reported developments of the palladium-catalyzed C –H activation and functionalization of the inactive/unreactive prochiral C(sp3)–H bonds of aliphatic and alicyclic compounds. There exist numerous classical methods for generating... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Srinivasarao Arulananda Babu Source Type: research

Enantiopure ferrocene-1,2-disulfoxides: synthesis and reactivity
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC07085A, CommunicationMin Wen, William Erb, Florence Mongin, Marielle Blot, Thierry Roisnel The rational use of directed deprotometallation, sulfur oxidation and sulfoxide/lithium exchange allowed the synthesis of enantiopure ferrocene-1,2-disulfoxide derivatives. Not only they represent the first members of this original family, but... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Min Wen Source Type: research

Exploring the dynamic nature of divalent metal ions involved in DNA cleavage by CRISPR-Cas12a
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Heyjin Son, Jaeil Park, You Hee Choi, Youngri Jung, Joong-Wook Lee, Sang Su Bae, Sanghwa Lee CRISPR-Cas12a has been widely used in genome editing and nucleic acid detection. In both of these applications, Cas12a cleaves target DNA in a divalent metal ion-dependent manner. However, when and... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Heyjin Son Source Type: research

Synthesis of a Large-Cavity Carbazole Macrocycle for Size-Dependent Recognition
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06788E, CommunicationMing Dong, Xiu Liu, Zhi-Yuan Zhang, Cheng-Mao Yu, Bochao Huo, Chunju Li A large-cavity carbazole macrocycle (1) is reported through condensation of a long and rigid monomer and paraformaldehyde. 1 exhibits highly selective binding of large-sized tetra(n-propyl) ammonium cation 3+. The complexation... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Ming Dong Source Type: research

Helicity Control of a Perfluorinated Carbon Chain Within a Chiral Supramolecular Cage Monitored by VCD
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06861J, CommunicationCarlo Bravin, Giuseppe Mazzeo, Sergio Abbate, Giulia Licini, Giovanna Longhi, Cristiano Zonta Confinement within supramolecular systems is the leading technology to finely tune guest functional properties. In this communication we report the synthesis of a chiral supramolecular cage able to bias the... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Carlo Bravin Source Type: research

Depth prediction of nanotags in tissue using surface enhanced spatially offset Raman scattering (SESORS)
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Matthew E. Berry, Samantha M. McCabe, Neil C. Shand, Duncan Graham, Karen Faulds A model for the prediction of the depth of two ‘flavours’ of surface enhanced Raman scattering (SERS) active nanotags embedded within porcine tissue is demonstrated using ratiometric analysis of the nanotag and tissue intensities in spatially offset Raman spectroscopy (SORS) measurements. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: R...
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Matthew E. Berry Source Type: research

Zn-Catalyzed Enantioselective Allylation and Allenylation of Isatins by virtue of Proline-derived Chiral Ligand
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06563G, CommunicationKuiliang Li, Xiang Sun, Shuangshuang Zhao, Tong Li, Zhenggen Zha, Zhiyong Wang An asymmetric allylation and allenylation of isatins with facile organoboron reagents was developed under the catalysis of Lewis acid. A series of optically pure 3-allyl-3-hydroxyoxindoles and 3-allenyl-3-hydroxyoxindoles can be obtained... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Kuiliang Li Source Type: research

Synthesis and Modification of Polymers by Thiol-Phenylsulfone Substitution Reaction
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06557B, CommunicationHanying Zhao, Lun Wang, Qianyu Yu, Li Liu Thiol chemistry is a type of highly efficient chemical reactions between thiols and functional groups. During the past two decades, thiol chemistry has been widely applied in the synthesis and... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Hanying Zhao Source Type: research

A Cationic Sulfur-Hydrocarbon Triradical with an Excited Quartet State
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06904G, CommunicationShuxuan Tang, Huapeng Ruan, Zhao-Bo Hu, Yue Zhao, You Song, Xinping Wang The triptycene-bridged tris(thianthrene) compound 1 was designed and synthesized. Three-electron oxidation of 1 by NO[Al(OC(CF3)3)4], followed by crystallization at two different temperatures, resulted in the triradical trication salts 2a and... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Shuxuan Tang Source Type: research

Pt/Mn3O4 cubes with high anti-poisoning ability for C1 and C2 alcohol fuel oxidation
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D2CC00105E, CommunicationJia Xue, Xiang Wu, Ligang Feng Pt anchored over Mn3O4 cubes are found to have high anti-CO poisoning ability for C1 and C2 alcohol fuel oxidation in the acid electrolyte resulting from the electronic effect induced... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Jia Xue Source Type: research

Bismuth chromate (Cr2Bi3O11): A new bismuth-based semiconductor with excellent photocatalytic activity
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06734F, CommunicationXinyu Gao, Kelei Huang, Zisheng Zhang, Xiangchao Meng A novel bismuth chromate material (Cr2Bi3O11) was synthesized by a direct mixing method with higher photocatalytic activity in both organic pollutants ’ detoxification and oxygen evolution. Cr2Bi3O11 with a band gap... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: Xinyu Gao Source Type: research

Endogenous cysteine fluorescence monitoring and its usage for tumour demarcation
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06765F, Communicationyongkang yue, tingting zhao, Kaiqing Ma, Fangjun Huo, Caixia Yin A cysteine specific fluorescent probe with wide detectable concentration range was used to monitor cysteine changes in HeLa cells under stress and demarcate the boundary of xenograft tumour. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 14, 2022 Category: Chemistry Authors: yongkang yue Source Type: research

Pinpointing photothermal contributions in photochemical reactions on plasmonic gold nanoparticles
Chem. Commun., 2022, Advance Article DOI: 10.1039/D1CC05780D, CommunicationHao Wang, Zheng Cao, Liqin Zheng, Xian Wang, Mengke Su, Honglin Liu Laser-induced photocatalytic reduction of PNTP to DMAB on plasmonic GNP arrays through hot electron transfer and direct photothermal conversion. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 13, 2022 Category: Chemistry Authors: Hao Wang Source Type: research

Osmium(VI) nitride triggers mitochondria-induced oncosis and apoptosis
Chem. Commun., 2022, Advance Article DOI: 10.1039/D1CC05148B, CommunicationMeng Ye, Wan-Qiong Huang, Zi-Xin Li, Chuan-Xian Wang, Tao Liu, YunZhou Chen, Catherine Hong-Huan Hor, Wai-Lun Man, Wen-Xiu Ni A new octahedral osmium(VI) nitrido complex with no labile ligandtrans to the nitride was reported. This complex causes liver cancer cell mitochondrial damage, and induces oncosis and apoptosis. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 13, 2022 Category: Chemistry Authors: Meng Ye Source Type: research

Highly efficient NIR-II luminescent I-III-VI semiconductor nanoprobes based on AgInTe2:Zn/ZnS nanocrystals
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC05533J, CommunicationJiayao Li, Tianyong Guan, Datao Tu, Wei Lian, Peng Zhang, Siyuan Han, Fei Wen, Xueyuan Chen Highly efficient luminescence of AgInTe2:Zn/ZnS nanocrystals with the maximum NIR-II quantum yield of 25.2% has been designed through elaborately manipulating the structure to reduce their internal and surface defects. These... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 13, 2022 Category: Chemistry Authors: Jiayao Li Source Type: research

Synthesis, Characterization, and High-Pressure Studies of a 3D Berkelium(III) Carboxylate Framework Material
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06958F, CommunicationJoseph M. Sperling, Nicholas B Beck, Benjamin Scheibe, Zhuanling Bai, Jacob Preston Brannon, Daniela Gomez Martinez, Dennis Gr ödler, Jason A. Johnson, Xinsong Lin, Brian Matthew Rotermund, Thomas Albrecht-Schoenzart A berkelium(III) mellitate, Bk2[C6(CO2)6](H2O)8 ∙2H2O, was synthesized and rapidly crystallized by reacting mellitic acid, C6(CO2H)6, and BkBr3∙nH2O in an aqueous medium. Single crystal X-ray diffraction shows that the compound crystallizes as... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC -...
Source: RSC - Chem. Commun. latest articles - January 13, 2022 Category: Chemistry Authors: Joseph M. Sperling Source Type: research

Deep eutectic solvents composed of bio-phenol-derived superbase ionic liquids and ethylene glycol for CO2 capture
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06856C, CommunicationZe Wang, Zonghua Wang, Huang Xin, Dezhong Yang, Congyi Wu, Jie Chen Deep eutectic solvents (DESs) formed by bio-phenol-derived superbase ionic liquids (ILs) and ethylene glycol (EG) perform a high CO2 capacity, up to 1.0 mol CO2/ mol DESs, which is much... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 13, 2022 Category: Chemistry Authors: Ze Wang Source Type: research

Hemicubane topological analogs of the oxygen-evolving complex of photosystem II mediating water-assisted propylene carbonate oxidation
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC05825H, CommunicationConnor A. Koellner, Michael Gau, Aleksander Polyak, Manish Bayana, Michael John Zdilla A series of Ca-Mn clusters with the ligand 2-pyridinemethoxide (Py-CH2O) have been prepared with varying degrees of topological similarity to the biological oxygen-evolving complex. These clusters activate water as a... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - January 13, 2022 Category: Chemistry Authors: Connor A. Koellner Source Type: research

Divinylpyrimidine reagents generate antibody-drug conjugates with excellent in vivo efficacy and tolerability
Chem. Commun., 2022, Accepted Manuscript DOI: 10.1039/D1CC06766D, CommunicationStephen J Walsh, Soleilmane Omarjee, Friederike M. Dannheim, Dominique-Laurent Couturier, Dorentina Bexheti, Lee Mendil, Gemma Cronshaw, Toby Fewster, Charlotte Gregg, Cara Brodie, Jodi L Miller, Richard Houghton, Jason S Carroll, David R Spring The development of divinylpyrimidine (DVP) reagents for the synthesis of antibody-drug conjugates (ADCs) with in vivo efficacy and tolerability is reported. Detailed structural characterisation of the synthesised ADCs was first... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: R...
Source: RSC - Chem. Commun. latest articles - January 13, 2022 Category: Chemistry Authors: Stephen J Walsh Source Type: research