Tailoring Component and Morphology of Discharge Products towards Highly Rechargeable Li-CO/CO2 Batteries
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC03676D, CommunicationShiyu Ma, Hong-Chang Yao, Dongling Lei, Xiaoqing Guo, Youcai Lu, 清朝 刘, Zhongjun Li A new non-aqueous Li-CO/CO2 battery with the main discharge products being Li2CO3 and carbon is firstly introduced. Our findings demonstrate that with the addition of CO, the component and morphology... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 22, 2018 Category: Chemistry Authors: Shiyu Ma Source Type: research

Rhodium-Catalyzed Asymmetric Synthesis of [small beta]-Branched Esters from Allylic Amines
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC02612B, CommunicationSummer D. Laffoon, Zhao Wu, Kami Hull Allylic amines are converted to chiral, [small beta]-branched esters under rhodium catalysis in the presence of alcohol nucleophiles. Allylic amines with aliphatic and aromatic vinylic substituents are converted to ester products... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 22, 2018 Category: Chemistry Authors: Summer D. Laffoon Source Type: research

Uniform poly(phosphazene-triazine) porous microspheres for highly efficient iodine removal
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04242J, CommunicationShaohui Xiong, Jian Tao, Yuanyuan Wang, Juntao Tang, Cheng Liu, Qingquan Liu, Yan Wang, Guipeng Yu, Chunyue Pan Rich heteroatom-doped conjugated nanoporous polymers with uniform microspherical morphology exhibit remarkablly high capacity up to 450 wt% in removing iodine from vapor phase (at 348 K and atmosphere pressure). The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 22, 2018 Category: Chemistry Authors: Shaohui Xiong Source Type: research

Orthogonal Reactivity of Ni(I)/Pd(0) Dual Catalysts for Ullman C-C Cross-Coupling: Theoretical Insight
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04127J, CommunicationBo Zhu, Li-Kai Yan, Li-Shuang Yao, Hang Ren, Run-Han Li, Wei Guan, Zhong-Min Su Dual catalysis has become a desirable alternative because of the synergetic effect of two distinct catalysts, but little is known about the mechanism of dual catalysis and its effect on... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 22, 2018 Category: Chemistry Authors: Bo Zhu Source Type: research

Unusual High-Temperature Reversible Phase-Transition Containing Dielectric and Nonlinear Optical Switch in a Host-Guest Supramolecular Crown Ether Clathrate
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC03885F, CommunicationYan-Li Wei, Jing Jing, Chao Shi, Heng-Yun Ye, Zhongxia Wang, Yi Zhang A novel high-temperature dielectric and quadratic nonlinear optical switching material, 3,4-difluoroanilinium 18-crown-6 perchlorate, was synthesized. It exhibits two successive structural phase transitions at 347 K and 240 K, respectively. Gradually... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 22, 2018 Category: Chemistry Authors: Yan-Li Wei Source Type: research

Supramolecular chemotherapeutic drug constructed from pillararene-based supramolecular amphiphile
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04334E, CommunicationDan Wu, Yang Li, Jie Shen, Zaizai Tong, Qinglian Hu, Liping Li, Guocan Yu Based on the host-guest interaction between a CPT-conjugated prodrug amphiphile (CPT-ss-Py) and a water-soluble pillar[5]arene (P5), a GSH-responsive supramolecular chemotherapeutic drug (P5[superset]CPT-ss-Py) was established. Through this supramolecular formulation, the internalization... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 22, 2018 Category: Chemistry Authors: Dan Wu Source Type: research

A robust two-dimensional zirconium-based luminescent coordination polymer built on V-shaped dicarboxylate ligand for vapor phase sensing of volatile organic compounds
We report herein a new two-dimensional zirconium-based luminescent coordination polymer Zr6(sdba)4([small mu ]3-O)4([small mu ]3-OH)4(HCOO)2(OH)2(H2O)2 (1) [sdba = 4,4'-sulfonyldibenzoate] exhibiting selective fluorescence responses towards a variety of volatile organic compounds upon exposure in the... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 22, 2018 Category: Chemistry Authors: Peiyao Du Source Type: research

Ca2+, Redox, Thermoresponsive Supramolecular Hydrogel with Programmed Quadruple Shape Memory Effect
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC03304H, CommunicationLinya Tang, Lanfang Wen, shouping xu, Pi-hui Pi, Xiufang Wen A new shape memory hydrogel, which can be programmed with quadruple geometries when stimuli are applied sequentially, is presented. With new redox-responsive stimulus coupled with two other common regulation mechanisms,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 22, 2018 Category: Chemistry Authors: Linya Tang Source Type: research

Ultrafast Proton-Assisted Tunneling Through ZrO2 in Dye-Sensitized SnO2-core/ZrO2-Shell Films
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04189J, CommunicationJohn R Swierk, Nicholas McCool, Jason Rohr, Svante Hedstrom, Steven J Konezny, Coleen T Nemes, Pengtao Xu, Victor S Batista, Thomas E Mallouk, Charles Schmuttenmaer Core-shell architectures are used to modulate injection and recombination in dye-sensitized photoelectrochemical cells. Here, we demonstrate that exposing SnO2-core/ZrO2-shell films to acid permits photoinduced electron transfer through ZrO2-shells at least... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 22, 2018 Category: Chemistry Authors: John R Swierk Source Type: research

Fusing Triphenylphosphine with Tetraphenylborate: Introducing the 9-Phosphatriptycene-10-phenylborate (PTB) Anion
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04321C, CommunicationMarcus W. Drover, Koichi Nagata, Jonas C Peters In a fusion of two ubiquitous organometallic reagents, triphenylphosphine (PPh3) and tetraphenylborate (BPh4-); the 9-phosphatriptycene-10-phenylborate (PTB) anion has been prepared for the first time. This borato species has been fully... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 22, 2018 Category: Chemistry Authors: Marcus W. Drover Source Type: research

Visible-light induced three-component alkynyl-difluoroalkylation of unactivated alkenes
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC03105C, CommunicationWeiwei Jin, Mingchang Wu, Zhimin Xiong, Gangguo Zhu A visible-light induced three-component reaction of difluoroalkyl halides, unactivated alkenes, and alkynyl sulfones is described, providing a direct and general approach to the construction of synthetically valuable [small beta]-difluoroalkylated alkynes under... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 22, 2018 Category: Chemistry Authors: Weiwei Jin Source Type: research

Chiral modulation of amyloid beta fibrillation and cytotoxicity by enantiomeric carbon dots
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC03235A, CommunicationRavit Butbul, elad arad, Susanta Bhunia, Shira Shaham-Niv, Sofiya Kolusheva , Ehud Gazit, Raz Jelinek Enantiomeric carbon dots (C-dots) synthesized from L-lysine or D-lysine, modulate aggregation and cytotoxicity of amyloid beta-42 (Ab42), the primary constituent of the amyloid plaques associated with Alzheimer's disease. In particular,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 22, 2018 Category: Chemistry Authors: Ravit Butbul Source Type: research

Rhodium-catalyzed [(3+2)+1] carbocyclizations of alkynylidenecyclopropanes with carbon monoxide: construction of polysubstituted bicyclohexa-2,5-dienones
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC02269K, CommunicationAndrew J. Burnie, P. Andrew Evans A rhodium-catalyzed carbocyclization reaction of alkynylidenecyclopropanes with carbon monoxide to prepare bicyclohexa-2,5-dienones is described. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Andrew J. Burnie Source Type: research

Mercury nanoladders: a new method for DNA amplification, signal identification and their application in the detection of Hg(II) ions
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03851A, CommunicationYuxiang Feng, Xiangli Shao, Kunlun Huang, Jingjing Tian, Xiaohong Mei, Yunbo Luo, Wentao Xu A biosensor based on Hg(II) nanoladders integrated with graphene oxide (GO) for Hg(II) detection was developed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Yuxiang Feng Source Type: research

Supramolecular hydrogel based on a sodium deep eutectic solvent
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03266A, CommunicationCatarina Florindo, Lucas G. Celia-Silva, Luis F. G. Martins, Luis C. Branco, Isabel M. Marrucho Supramolecular hydrogel based on a metal containing deep eutectic solvent (DES) is presented here for the first time. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Catarina Florindo Source Type: research

Discovery and synthesis of the first selective BAG domain modulator of BAG3 as an attractive candidate for the development of a new class of chemotherapeutics
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03399D, CommunicationStefania Terracciano, Gianluigi Lauro, Alessandra Russo, Maria Carmela Vaccaro, Antonio Vassallo, Margot De Marco, Bianca Ranieri, Alessandra Rosati, Maria Caterina Turco, Raffaele Riccio, Giuseppe Bifulco, Ines Bruno The first selective BAG3BD modulator has been discovered. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Stefania Terracciano Source Type: research

Ni2[LnCl6] (Ln = EuII, CeII, GdII): the first LnII compounds stabilized in a pure inorganic lattice
Chem. Commun., 2018, Advance Article DOI: 10.1039/C7CC09921E, CommunicationBianca Baldo, Francisco Rubio, Erwin Flores, Andres Vega, Nathalie Audebrand, Diego Venegas-Yazigi, Veronica Paredes-Garcia Here we report the first examples of 3d-4f compounds based on LnII cations. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Bianca Baldo Source Type: research

Novel gradient-diameter magnetic nanowire arrays with unconventional magnetic anisotropy behaviors
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC02294A, CommunicationJing Wang, Zhili Zuo, Liang Huang, Muhammad Asif Warsi, John Q. Xiao, Jun Hu Gradient-diameter magnetic nanowires exhibited tailorable magnetic anisotropy that can be used to switch magnetic nanowires easily and unconventional temperature-dependent coercivity. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Jing Wang Source Type: research

PVP-assisted transformation of a metal-organic framework into Co-embedded N-enriched meso/microporous carbon materials as bifunctional electrocatalysts
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC02646G, CommunicationZuozhong Liang, Chaochao Zhang, Haitao Yuan, Wei Zhang, Haoquan Zheng, Rui Cao A PVP-assisted pyrolysis strategy that can simply but efficiently transform zeolitic imidazolate framework-67 (ZIF-67) into a Co-embedded N-enriched meso/microporous carbon material (Co-NC) is reported for the first time. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Zuozhong Liang Source Type: research

Formal water oxidation turnover frequencies from MIL-101(Cr) anchored Ru(bda) depend on oxidant concentration
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Asamanjoy Bhunia, Ben A. Johnson, Joanna Czapla-Masztafiak, Jacinto Sa, Sascha Ott [Ru(bda)(L)2] incorporated into the MIL-101(Cr) metal-organic framework catalyzes water oxidation faster than a homogenous reference, with the number of active catalysts depending on oxidant concentration. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Asamanjoy Bhunia Source Type: research

Use of a benzyl ether as a traceless hydrogen donor in the anti-Markovnikov hydrofunctionalization of alkenes with xanthates
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC02971G, CommunicationHirohito Hayashi, Atsushi Kaga, Bin Wang, Fabien Gagosz, Shunsuke Chiba A new protocol for the anti-Markovnikov hydrofunctionalization of alkenyl alcoholO-Bn ethers was developed using xanthates as functionalizing agents in the presence of lauroyl peroxide as a radical initiator and a stoichiometric oxidant. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Hirohito Hayashi Source Type: research

Unexpected halide anion binding mode in meso-bis-ethynyl picket-calix[4]pyrroles: Effects of meso - [small pi] (ethynyl) extension
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04393K, CommunicationRanjan Dutta, Dikhi Firmansyah , Jihoon Kim, Hongil Jo, Kang Min Ok, Chang-Hee Lee Meso-ethynyl extended aryl-picket calix[4]pyrroles 2 and 3 are designed and synthesized by directly anchoring arylethynyl groups at diametrically opposed meso-positions. Critical roles of direct ethynyl linker are manifested through the... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Ranjan Dutta Source Type: research

On the non-innocence of the imidazolium cation in a rapid microwave synthesis of oleylamine-capped gold nanoparticles in an ionic liquid
We report a very fast (10-30 s) microwave method to prepare oleylamine-capped, monodisperseca. 8-11 nm gold nanoparticles in an ionic liquid To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Nakara Bhawawet Source Type: research

Cleave and couple: toward fully sustainable catalytic conversion of lignocellulose to value added building blocks and fuels
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC02937G, Feature ArticleZhuohua Sun, Katalin Barta Cleave and couple: sustainable catalytic pathways to value added chemicals and fuels from lignocellulose. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Zhuohua Sun Source Type: research

Amphiphilic composite material of titanosilicate@mesosilica/carbon as Pickering catalyst
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC03267J, CommunicationYu Ding, Hao Xu, Hai-Hong Wu, Ming Yuan He, PENG WU Hierarchically core/shell-structured TS-1@silica/carbon composite material, synthesized from titanosilicate crystals and surfactant-mediated mesosilica/resol precursors via self-assembly and nanocasting route, fabricated stable oil-water-solid Pickering emulsions in the alkene/H2O2 media and thus exhibited... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Yu Ding Source Type: research

Conductive two-dimensional metal-organic frameworks as multifunctional materials
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC02871K, Feature ArticleMichael Ko, Lukasz Mendecki, Katherine A. Mirica Two-dimensional (2D) conductive metal-organic frameworks (MOFs) have emerged as a unique class of multifunctional materials with broad applicability in electronics, chemical sensing, gas capture, catalysis, and energy conversion and storage. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Michael Ko Source Type: research

Isotope effect on the spin dynamics of single-molecule magnets probed by muon spin spectroscopy
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04703K, CommunicationLorenzo Tesi, Zaher Salman, Irene Cimatti, Fabrice Pointillart, Kevin Bernot, Matteo Mannini, Roberta Sessoli Muon spin relaxation ([small mu ]SR) experiments on a single molecule magnet enriched in different Dy isotopes detect unambiguously a slowing down of the zero field spin dynamics for the non-magnetic isotope.... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Lorenzo Tesi Source Type: research

2D amphiphilic organoplatinum(II) metallacycles: syntheses, self-assembly in water and their potential application in photodynamic therapy
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04423F, CommunicationYong Yao, Ruibo Zhao, Yujun Shi, Yan Cai, Jiao Chen, siyu Sun, Wei Zhang, Ruikang Tang Two 2D amphiphilic organoplatinum(II) metallacycles with porphyrin unit as the core and hydrophilic glycol unit as the tail were designed and fabricated successfully through a new method called "coordination driven... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 21, 2018 Category: Chemistry Authors: Yong Yao Source Type: research

A conjugated microporous polymer based visual sensing platform for aminoglycoside antibiotics in water
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC02865F, CommunicationSubhajit Bhunia, Nilanjan Dey, Anirban Pradhan, Santanu Bhattacharya A conjugated microporous polymer has been designed for stereo-specific "Turn ON" biosensing of neomycin in water. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 20, 2018 Category: Chemistry Authors: Subhajit Bhunia Source Type: research

Selective hydrogenation of amides to alcohols in water solvent over a heterogeneous CeO2-supported Ru catalyst
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC02697A, CommunicationMasazumi Tamura, Susumu Ishikawa, Mii Betchaku, Yoshinao Nakagawa, Keiichi Tomishige CeO2-supported Ru (Ru/CeO2) worked as an effective and reusable heterogeneous catalyst for the selective dissociation of the C-N bond in amides, particularly primary amides, with H2 in water solvent at low reaction temperature of 333 K. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 20, 2018 Category: Chemistry Authors: Masazumi Tamura Source Type: research

Diazonium Salt Chemistry For The Design Of Nano-Textured Anti-Icing Surfaces
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC02601G, CommunicationSarra Gam, Jean Pinson, Philippe Decorse, Yun Luo, Remy Herbaut, Laurent Royon, Claire Mangeney Aryl diazonium salts have emerged as a new generation of robust surface modifiers for a wide range of applications. However, their use for creating anti-icing surfaces has never been investigated... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 20, 2018 Category: Chemistry Authors: Sarra Gam Source Type: research

Controllable Transformation Between 3D and 2D Perovskites through Cation Exchange
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04261F, CommunicationWeixin Huang, Yuanxing Wang, Subila K. Balakrishnan A facile post-synthetic cation exchange approach has been employed to controllably tune the optical and structural properties of colloidal perovskite nanocrystals (NCs). These optical changes are attributed to the structural... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 20, 2018 Category: Chemistry Authors: Weixin Huang Source Type: research

Unusual rearrangement of an N-heterocyclic carbene via a ring-opening and ring-closing process
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC03589J, CommunicationChu-Fan Yang, Taotao Lu, Xue-tai Chen, Zi-Ling Xue Reaction of a pentadentate NHC ligand precursor with Ni(OAc)2 ∙4H2O or Pd(OAc)2 in the presence of a base yields four-coordinate square-planar Ni(II) and Pd(II) complexes with an unusual ligand generated in-situ.... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 20, 2018 Category: Chemistry Authors: Chu-Fan Yang Source Type: research

Hyper-cross-linked Polymer with Controlled Multiscale Porosity via Polymerization-induced Microphase Separation within High Internal Phase Emulsion
We report preparation of hierarchically porous polymer containing fully interconnected and controlled micro-, meso-, and macropores, where hyper-cross-linked microporous polymer skeleton forms reticulating mesoporous wall that supports a highly porous... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 20, 2018 Category: Chemistry Authors: Jongmin Park Source Type: research

A Dual-Analyte Probe: Hypoxia Activated Nitric Oxide Detection with Phototriggered Drug Release Ability
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC01854E, CommunicationSandipan Biswas, Rajesh Y, Sharabani Barman, Manoranjan Bera, Amrita Paul, Mahitosh Mandal, Pradeep N.D. Singh A new strategy for the detection of hypoxia and NO succeeded by photocontrolled delivery of anticancer agent has been demonstrated. The developed system is able to produce distinct responses (dual... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 20, 2018 Category: Chemistry Authors: Sandipan Biswas Source Type: research

A ruthenium-platinum metal complex that binds to Sarcin Ricin Loop RNA and lowers mRNA expression
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC02131G, CommunicationSwapan Satyen Jain, Craig Anderson, Iden Sapse, Silvie Hannah Lundgren, Abigail Kathryn Freer, Hang Hoang, Kyan Jain, Madeleine Breshears IT127 is a dinuclear transition metal complex that contains a Pt(II) and a Ru(III) metal center. We have shown that IT127 is significantly more effective in binding the 29-base Sarcin... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 20, 2018 Category: Chemistry Authors: Swapan Satyen Jain Source Type: research

One-step synthesis of cyclic compounds towards easy room-temperature phosphorescence and deep blue thermally activated delayed fluorescence
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC03833C, Communicationhu yingyuan, Zhenfeng Wang, Xiaofang Jiang, Xinyi Cai, Shi-Jian Su, Fei Huang, Yong Cao With the advantages of facile one-pot synthesis and THF-irrigating purification, we first developed novel cyclic compounds with deep blue thermally activated delayed fluorescence (TADF) and room-temperature phosphorescence (RTP) dual emission... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 20, 2018 Category: Chemistry Authors: hu yingyuan Source Type: research

Ultra-sensitive fluorescent probes for hypochlorite acid detection and exogenous/endogenous imaging of living cells
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC03963A, CommunicationYin Jiang, Guansheng Zheng, Qinya Duan, Yang Liu, Jie Zhang, Huatang Zhang, Jun He, Hongyan Sun, Derek Ho Two fluorescent probes (Naph-1 and Naph-2), which can be prepared via a facile process, have been developed to detect hypochlorite acid (HOCl). N,N-dimethylthiocarbamate group quenches the fluorescence of the probes... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 20, 2018 Category: Chemistry Authors: Yin Jiang Source Type: research

Dynamic Layer-by-Layer Films on Nanofiber Membrane: A Platform for Ultra-sensitive Bacterial Concentration Detection
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04187C, CommunicationZhenguo Yu, Zhentan Lu, Yu Huang, Mufang Li, Wenwen Wang, Ke Liu, Dong Wang Herein, a new platform was established for ultra-sensitive bacterial concentration detection. The sensing system had linearly relationship with the logarithm of bacterial concentration from 1[times]101 to 1[times] 105 CFU/mL within... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 20, 2018 Category: Chemistry Authors: Zhenguo Yu Source Type: research

An azobenzene-based heteromeric prodrug for hypoxia-activated chemotherapy by regulating subcellular localization
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC03430C, CommunicationShiying Li, Xueyan Jiang, Rongrong Zheng, Shengjia zuo, Linping Zhao, Guiling Fan, Jinghao Fan, Yonghua Liao, Xiyong Xu, Hong Cheng An azobenzene-based heteromeric prodrug (hNDP) was prepared for targeted chemotherapy against hypoxic tumor. hNDP could divert the parent drug from nucleus to cytoplasm with lower toxicity. While the azoreduction of... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 20, 2018 Category: Chemistry Authors: Shiying Li Source Type: research

Aggregation-induced emission of luminol: a novel strategy for fluorescence ratiometric detection of ALP and As(V) with high sensitivity and selectivity
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03725F, CommunicationYuan-Jun Tong, Lu-Dan Yu, Lu-Lu Wu, Shu-Ping Cao, Ru-Ping Liang, Li Zhang, Xing-Hua Xia, Jian-Ding Qiu Luminol is introduced as a ligand for Tb3+ which, combined with GMP, leads to a sensor which is more robust, sensitive, and efficient. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 19, 2018 Category: Chemistry Authors: Yuan-Jun Tong Source Type: research

Redox neutral [4+2] benzannulation of dienals and tertiary enaminones for benzaldehyde synthesis
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03514H, CommunicationLu Yang, Li Wei, Jie-Ping Wan The [4+2] benzannulation reactions between tertiary enaminones and dienals have been developed for the synthesis of polyfunctionalized benzaldehydes, providing a new access to benzaldehydes alongside the classical formylation strategy. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 19, 2018 Category: Chemistry Authors: Lu Yang Source Type: research

Pd(II)-Catalyzed gamma-C(sp3)-H alkynylation of amides: selective functionalization of R chains of amides R1C(O)NHR
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03445A, CommunicationVinod G. Landge, Ayisha Parveen, Avanashiappan Nandakumar, Ekambaram Balaraman The first example of palladium(II)-catalyzed alkynylation of an unactivated gamma C(sp3)-H bond of alkyl amides (cyclic, linear, and amino acids) is reported. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 19, 2018 Category: Chemistry Authors: Vinod G. Landge Source Type: research

Py A-cluster system for the detection and imaging of miRNAs in living cells through double-three-way junction formation
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03982H, CommunicationJong Jin Ro, Ha Jung Lee, Byeang Hyean Kim Herein, we describe an extended version of a fluorescence probe for detecting miRNAs through the novel application of aPyA-cluster system. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 19, 2018 Category: Chemistry Authors: Jong Jin Ro Source Type: research

Correction: Topology meets MOF chemistry for pore-aperture fine tuning: ftw-MOF platform for energy-efficient separations via adsorption kinetics or molecular sieving
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Dong-Xu Xue, Amandine Cadiau, Lukasz J. Weselinski, Hao Jiang, Prashant M. Bhatt, Aleksander Shkurenko, Lukasz Wojtas, Zhijie Chen, Youssef Belmabkhout, Karim Adil, Mohamed Eddaoudi To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 19, 2018 Category: Chemistry Authors: Dong-Xu Xue Source Type: research

Pd/C-Catalyzed Dehydrogenation of 2-Cinamoylbenzoic Acids to 3-Benzylidene-3H-isochroman-1,4-diones
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC03402H, CommunicationRenhua Liu, Dejun Yang, Xuan Ji, Jie Zhang, Chenyang Zhang, Mingfei Li, Jin Li Pd/C, a widely accepted hydrogenation catalyst, is found to catalytically dehydrogenate 2-cinnamoylbenzoic acids to 3-benzylidene-3-H-isochroman-1,4-diones with H2 as the only byproduct. The synthetic reaction proceeds without oxidants and hydrogen acceptors,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 19, 2018 Category: Chemistry Authors: Renhua Liu Source Type: research

Steric vs. Electronic Stereocontrol in Syndio- or Iso-selective ROP of Functional Chiral [small beta]-Lactones Mediated by Achiral Yttrium-Bisphenolate Complexes
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC03842B, Feature ArticleRomain Ligny, Mikko Hanninen, Sophie M Guillaume, Jean-Francois Carpentier Origins of stereoselectivity in ROP of racemic chiral cyclic esters promoted by achiral yttrium complexes, resulting in the formation of highly heterotactic polylactide, and highly syndiotactic or, more uniquely, highly... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 19, 2018 Category: Chemistry Authors: Romain Ligny Source Type: research

Unsupported Metal Silyl Ether Coordination
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04517H, CommunicationJuergen Pahl, Holger Elsen, Alexander Friedrich, Sjoerd Harder Simple silyl ethers like O(SiMe3)2 are in contrast to normal ethers inert to metal bonding, however, a "naked", highly Lewis-acidic, cationic Mg species enforces complexation. DFT calculations indicate that agostic... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 19, 2018 Category: Chemistry Authors: Juergen Pahl Source Type: research

Sensitized Photon Upconversion in Anthracene-based Zirconium Metal Organic Frameworks
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC01893F, CommunicationJennifer M Rowe, Jie Zhu, Erin M Soderstrom, Wenqian Xu, Andrey Yakovenko, Amanda J Morris Sensitized upconversion is explored in three metal-organic frameworks (MOFs) constructed from the anthracene dicarboxylate (ADC) derivatives and zirconium nodes, 9,10-ADC (9,10-MOF), 2,6-ADC (2,6-MOF) and 1,4-ADC (1,4-MOF). Selective excitation of surface-bound... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 19, 2018 Category: Chemistry Authors: Jennifer M Rowe Source Type: research

Effect of the metal-support interaction on the activity and selectivity of methanol oxidation over Au supported on mesoporous oxides
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04295K, CommunicationSunyoung Oh, You Kyung Kim, Chan Ho Jung, Won Hui DOH, Jeong Y. Park To elucidate the factors affecting the catalytic properties of supported Au catalysts depending on the metal oxide support, we investigated Au NPs deposited on crystallized mesoporous transition-metal oxides (m-oxides: Co3O4,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - June 19, 2018 Category: Chemistry Authors: Sunyoung Oh Source Type: research