Isosmaragdyrin with N3C2 core: Stabilization of Rh(I) and Organo-Pt(II) complexes
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00214C, CommunicationMainak Das, Sangya Chitranshi, Murugavel M, B. Adinarayana, Cherumuttathu Hariharan Suresh, A Srinivasan Isosmaragdyrin with N3C2 core is successfully achieved by introducing a 2,6-Di-m-phenylpyridine unit. The core is utilized to stabilize Rh(I) ion with N-Rh(I)-N bonding mode and Pt(II) ion with (N^C)N fashion... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 18, 2020 Category: Chemistry Authors: Mainak Das Source Type: research

Oxygen-rich nanoflakes-interlaced carbon microspheres for potassium-ion battery anodes
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00357C, CommunicationWei Xiong, Jianqiao Zhang, Yi Xiao, Youhuan Zhu, Zhenyu Wang, Zhou-Guang Lu A new kind of oxygen-rich carbon microspheres with nanoflakes-interlaced architecture has been successfully prepared by a facile surfactant-assisted precipitation polymerization method. This hierarchical infrastructure can efficiently buffer the volume change... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 18, 2020 Category: Chemistry Authors: Wei Xiong Source Type: research

Fused tetraphenylethylene –triphenylamine as an efficient hole transporting material in perovskite solar cells
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC09901H, CommunicationXianfu Zhang, Zi ’an Zhou, Shuang Ma, Gao Wu, Xuepeng Liu, Muhammad Mateen, Rahim Ghadari, Yunzhao Wu, Yong Ding, Molang Cai, Songyuan Dai A new facile fused tetraphenylethylene –triphenylamine hole transporting material has been developed, which shows obviously higher performance than the non-fused counterpart in perovskite solar cells. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 17, 2020 Category: Chemistry Authors: Xianfu Zhang Source Type: research

Keto –enol tautomerization drives the self-assembly of leucoquinizarin on Au(111)
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC09915H, CommunicationRoberto Costantini, Luciano Colazzo, Laura Batini, Matus Stredansky, Mohammed S. G. Mohammed, Simona Achilli, Luca Floreano, Guido Fratesi, Dimas G. de Oteyza, Albano Cossaro Leucoquinizarin is found to assemble on Au(111) surfaces in its keto –enolic tautomeric configuration and to form nanometric porous structures. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 17, 2020 Category: Chemistry Authors: Roberto Costantini Source Type: research

Designing Cr complexes for a neutral Fe –Cr redox flow battery
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC09704J, CommunicationWenqing Ruan, Jiatao Mao, Shida Yang, Chuan Shi, Guochen Jia, Qing Chen Through the design of polydentate ligands, we revamp the iron –chromium flow battery with neutral electrolytes for stable cycling performance. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 17, 2020 Category: Chemistry Authors: Wenqing Ruan Source Type: research

Fabrication of 2D extended cocrystal on Au(111) surface via I ···Oaldehyde halogen bond
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00199F, CommunicationXue-Qing Yang, Zheng-Yu Yi, Shengfu Wang, Ting Chen, Dong Wang 2D extended organic cocrystals were fabricated by 1,4-diiodotetrafluorobenzene and aromatic aldehydes via I ···Oaldehyde halogen bond on Au(111) surface. The competition and synergy of halogen bond and hydrogen bond in 2D... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 17, 2020 Category: Chemistry Authors: Xue-Qing Yang Source Type: research

Three-dimensional printing of black phosphorous/polypyrrole electrode for energy storage using thermoresponsive ink
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/C9CC08605F, CommunicationRuizhe Xing, Yinqiang Xia, Renliang Huang, Wei Qi, Rongxin Su, Zhimin He Three-dimensional (3D) printing techniques bring the possibility of making electronic devices in any desired shape and dimensions. Here, we report on a printable black phosphorous nanosheet /polypyrrole composite ink for... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 17, 2020 Category: Chemistry Authors: Ruizhe Xing Source Type: research

Pressure-Induced Inclusion of Neon in the Crystal Structure of a Molecular Cu2(pacman) Complex at 4.67 GPa
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Nico Giordano, Christine Beavers, K. Kamenev, Jason Love, James R Pankhurst, Simon Teat, Simon Parsons Crystals of a Cu complex of the macrocyclic Schiff-base calixpyrrole or ‘Pacman’ ligand, Cu2(L), do not contain any solvent-accessible void space at ambient pressure, but adsorbs neon at 4.67 GPa,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 17, 2020 Category: Chemistry Authors: Nico Giordano Source Type: research

An air-stable two-dimensional semiconducting metal-thiolate network and its exfoliation into ultrathin nanosheets
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/C9CC09349D, CommunicationQi Zeng, Lei Wang, Yitao Huang, Sai-Li Zheng, Yonghe He, Jun He, Wei-Ming Liao, Gang Xu, Matthias Zeller, Zhengtao Xu The black, small-bandgap semiconducting framework Eu-dfdmat features extensive Eu3+-sulfur bridges from the linear linker 2,5-difluoro-3,6-dimercaptoterephthalate (dfdmt). Each Eu center is chelated to four dfdmt linkers to form an anionic coordination... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 17, 2020 Category: Chemistry Authors: Qi Zeng Source Type: research

An Amalgam Route to Stabilize Potassium Metal Anodes over Wide Temperature Range
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00171F, CommunicationQing Yang, Yi Ding, Guang He Potassium metal anode is very appealing due to the high theoretical capacity (687 mAh g-1), but the violent reactivity and severe dendrite issues hinder its practical development. Here we report... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 17, 2020 Category: Chemistry Authors: Qing Yang Source Type: research

Double Trouble for Viruses: Hydrogel Nanocomposite Catches Influenza Virus While Shrinking and Changing Color
We report a virus responsive hydrogel giving a dual response. The method utilizes the optical property of gold nanoparticles (AuNP) and the high swelling capacity of polyol-based hydrogels to form... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 17, 2020 Category: Chemistry Authors: Rotsiniaina Randriantsilefisoa Source Type: research

Crystal structure of sodium ethoxide (C2H5ONa), unravelled after a 180 years
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/C9CC08907A, CommunicationMaurice Beske, Lukas Tapmeyer, Martin U. Schmidt As early as 1837, Liebig synthesised solid C2H5ONa. Today, C2H5ONa is one of the standard bases in organic synthesis. Here, we report the identification of different solid phases and the... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 17, 2020 Category: Chemistry Authors: Maurice Beske Source Type: research

Synthesis, X-ray characterization and regium bonding interactions of a trichloro(1-hexylcytosine)-gold(III) complex
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.ANGEL TERRON, Jordi Buils, Tiddo Jonathan Mooibroek, Miquel Barcel ó-Oliver, Angel Garcia-Raso, JUAN J J FIOL, Antonio Frontera Herein we report the synthesis and X-ray characterization of a gold(III) complex of 1-hexylcytosine via N(3). The AuCl3N complexes stack on top of each other by reciprocal [Au ···Cl] regium bonding... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 17, 2020 Category: Chemistry Authors: ANGEL TERRON Source Type: research

A cephalosporin-chemiluminescent conjugate increases beta-lactamase detection sensitivity by four orders of magnitude
In this report, we present a beta-lactamase chemiluminescent probe, termed CCP, which can for the first time... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 17, 2020 Category: Chemistry Authors: Santanu Maity Source Type: research

Silver-catalyzed acylative annulation of N-propargylated indoles with α-keto acids: Access to acylated pyrrolo[1,2-a]indoles
This study describes the first carbon centered radical cyclization of N-propargyl indoles involving decarboxylation of α-keto acids in the presence of Ag-catalyst. The present cascade carbon-carbon bond formation reactions provide... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 15, 2020 Category: Chemistry Authors: Raji Reddy Chada Source Type: research

A molecular recognition-activatable DNA nanofirecracker enables signal-enhanced imaging in living cells
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC09682E, CommunicationXiaojing Xing, Jin Li, Liping Qiu, Weihong Tan An aptamer-tethered DNA nanofirecracker probe that realizes molecular recognition-activatable disassembly of the DNA nanostructure for signal-enhanced bioimaging in living cells. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Xiaojing Xing Source Type: research

Zeolitic imidazolate framework-8 templated synthesis of a heterogeneous Pd catalyst for remediation of chlorophenols pollution
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC09494F, CommunicationMeng Xiao, Mengting Pang, Yu Peng, Baicun Hao, Yang Liao, Hui Mao, Fengwei Huo Herein, a heterogeneous Pd catalyst was prepared by embedding Pd nanoparticles in a highly porous nitrogen-doped mesoporous carbon (NMC) synthesized by the ZIF-8 template. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Meng Xiao Source Type: research

Atomic-dispersed platinum anchored on porous alumina sheets as an efficient catalyst for diboration of alkynes
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00598C, CommunicationHuishan Shang, Wenxing Chen, Zhuoli Jiang, Danni Zhou, Jiatao Zhang An atomic-dispersed Pt catalyst (Pt/dp-Al2O3) was fabricatedvia a simple wet impregnation method and demonstrated to be highly active and stable for the diboration of phenylacetylene, which is due to Pt/dp-Al2O3 providing unique catalytic sites. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Huishan Shang Source Type: research

Glycoluril Derived Cucurbituril Analogues and the Emergence of the Most Recent Example: Tiarauril
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/C9CC07233K, Feature ArticleAnthony Day, Rajni Dhiman, Satyavisal Pen, Pradeep Kumar Chandrakumar, Terry James Frankcombe Cucurbituril analogues can bear some of the chemical and physical characteristics of their parental origin and are derived wholly or in part from glycolurils (including homologues). The development of analogues... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Anthony Day Source Type: research

1,3-Carboboration of Iodonium Ylides
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Theo Gazis, Bayan Mohajeri Thaker, Darren Willcox, Darren Ould, Jan Wenz, Jeremy Michael Rawson, Michael Hill, Thomas Wirth, Rebecca Melen Herein, we disclose the utilisation of iodonium ylides to access a range of boron dienolates. Heating of acyclic iodonium ylides in the presence of different aryl boranes lead to the... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Theo Gazis Source Type: research

Di-lacunary [In6S15]12- cluster: building block of a highly negative charged framework for superior Sr2+ adsorption capacities
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00441C, CommunicationKai-Yao Wang, Meng Sun, Dong Ding, Hua-Wei Liu, Lin Cheng, Cheng Wang Presented is the construction of a highly negative charged layered material [CH3CH2NH3]6In6S12 (InS-1) by lacunary cluster as the building block. The pronounced framework negative charge density (5.59 × 10-3) and... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Kai-Yao Wang Source Type: research

Arylation and Alkenylation of Activated Alkyl Halides using Sulfonamides
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00220H, CommunicationMichael Greaney, Stuart Johnson, Ervin Kov ács A variety of quaternary aryl amino acid derivatives can be synthesised using tandem SN2 / Smiles rearrangement chemistry involving aryl sulfonamides and alpha-chloro carbonyl compounds. The reaction harnesses a sulfur... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Michael Greaney Source Type: research

Expedient iron-catalyzed stereospecific synthesis of triazines via cycloaddition of aziridines with diaziridines
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/C9CC10089J, CommunicationTharmalingam Punniyamurthy, Tanumay Sarkar, Kangkan Talukdar, Subhasish Roy Iron-catalyzed stereospecific [3+3]-annulation of aziridines with diaziridines is described to furnish [1,2,4]-triazines in high yield at room temperature. The use of inexpensive iron salt catalyst, substrate scope and enantiomeric purity... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Tharmalingam Punniyamurthy Source Type: research

A bis-vanadyl coordination complex as a 2-qubit quantum gate
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC09817H, CommunicationIvana Borilovic, Pablo J. Alonso, Olivier Roubeau, Guillem Arom í A divanadyl complex anion is isolated through a new bis-hydroxyphenylpyrazolyl ligand and has optimal weak dipolar coupling and quantum coherence to implement electron-mediated nuclear quantum simulations in a 2-qubit molecular architecture. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Ivana Borilovic Source Type: research

Cyclodextrins: from solute to solvent
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00460J, CommunicationTracy El Achkar, Tarek Moufawad, steven ruellan, David Landy, Helene Greige-Gerges, Sophie Fourmentin A supramolecular solvent based on cyclodextrin (CD) is presented here for the first time. Indeed, a low melting mixture was obtained by mixing levulinic acid and a CD derivative, which... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Tracy El Achkar Source Type: research

A sequence-specific plasmonic loop-mediated isothermal amplification (LAMP) assay with orthogonal color readouts enabled by CRISPR Cas12a
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00397B, CommunicationRongxing Zhou, Yongya Li, Tianyu Dong, Yanan Tang, Feng Li Herein, we introduce a sequence-specific plasmonic LAMP assay with dual, complementary color readouts enabled by CRISPR Cas12a. Using this assay, any double-stranded LAMP amplicon containing a 5 ’TTN PAM sequence can... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Rongxing Zhou Source Type: research

Influence of Halide Ions on the Structure and Properties of Copper Indium Sulphide Quantum Dots
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/C9CC08291C, CommunicationRiccardo Marin, Artiom Skripka, Yu-Cheng Huang, Tamie Ai Jie Loh, Viktoras Ma žeika, Vitalijus Karabanovas, daniel h. c. chua, Chung-Li Dong, Patrizia Canton, Fiorenzo Vetrone In the synthesis of CuInS2 quantum dots (QDs), the halide ions present in the copper salts influence the QD growth and optical properties. X-ray absorption spectroscopy allowed rationalizing the halide... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Riccardo Marin Source Type: research

DME carbonylation over a HSUZ-4 zeolite
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00886A, CommunicationZhiping Xiong, Ensheng Zhan, Mingrun Li, Wenjie Shen Zeolite-catalyzed carbonylation of dimethyl ether to methyl acetate represents a new route to synthesize acetyls. A rod-shaped HSUZ-4 zeolite, with intersecting 10-member ring and 8-member ring channels, showed exceptionally high... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Zhiping Xiong Source Type: research

Supramolecular gels derived from nucleoside based bolaamphiphiles as a light-sensitive soft material
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00336K, CommunicationJulie Baillet, Alexandra Gaubert, Dario Bassani, Julien Verget, Laurent Latxague, Philippe Barthelemy Light-sensitive Low Molecular Weight Gelators (LMWGs) derived from glyconucleoside bolaamphiphiles containing a stilbene unit displayed gelation abilities in hydroalcoholic mixtures. These materials showed a gel-sol transition under UV irradiation thanks... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Julie Baillet Source Type: research

Synthesis of a conductive polymer thin film having a choline phosphate side group and its bioadhesive properties
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC09949B, CommunicationMasaru Mukai, Chao-Hung Cheng, Wei Ma, Mi Chin, Chia-Hsin Lin, Shyh-Chyang Luo, Atsushi Takahara A conductive polymer thin film having choline phosphate as the side group was prepared. The polymer thin film can prevent bovine serum albumin binding while present nice fibroblast cell adhesion. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Masaru Mukai Source Type: research

Synthesis of tetrasubstituted thiophenes via a [3+2] cascade cyclization reaction of pyridinium 1,4-zwitterionic thiolates and activated allenes
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00262C, CommunicationShengxian Zhai, Xinping Zhang, Bin Cheng, Hui Li, Yuntong Li, Yixuan He, Yun Li, Taimin Wang, Hongbin Zhai A [3+2] cascade cyclization reaction of pyridinium 1,4-zwitterionic thiolates and activated allenes was developed to access tetrasubstituted thiophenes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Shengxian Zhai Source Type: research

Synthesis, Self-Assembly and Nonlinear Optical Activity of Selenium-Annulated Perylene Diimide
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/C9CC10006G, CommunicationGuo-Bin Huang, Lei Shen, jie Liu, Wen-Fa Zhou , Kaspars Traskovskis, Yinglin Song, Wei Jiang, Z-H Wang, Xiang-Kui Ren A novel Se-annulated perylene diimide derivative tethered with polyhedral oligosilsesquioxane (POSS) nanoparticles (POSS-2SePDI-POSS) was designed and prepared. The introduction of selenium atoms endows POSS-2SePDI-POSS with significant fluorescence quenching but enhanced... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Guo-Bin Huang Source Type: research

Chemoenzymatic, Biomimetic Total Synthesis of ( ‒)-Rugulosin B, C and Rugulin Analogues and its Biosynthetic Implications
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00406E, CommunicationAmit Mondal, Shailesh Kumar Singh, Tanaya Manna, Syed Masood Husain Herein, we report the chemoenzymatic synthesis of a heterodimeric, ( –)-rugulosin B and homodimeric, (–)-rugulosin C and several rugulin analogues in three to four steps starting from anthraquinones. The work supports... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Amit Mondal Source Type: research

Dual Ligand-promoted Palladium-catalyzed Nondirected C-H Alkenylation of Aryl Ethers
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00940G, CommunicationBiao Yin, Manlin Fu, Lei Wang, Jiang Liu, Qing Zhu Direct C-H functionalization of aryl ethers remains challenging due to their low reactivity and selectivity. Herein, an efficient strategy for C-H alkenylation of aryl ethers promoted by dual ligand catalyst... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Biao Yin Source Type: research

Beyond biotemplating: Multiscale porous inorganic materials with high catalytic efficiency
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00651C, CommunicationGiulia Magnabosco, Irene Papiano, Michael Aizenberg, Joanna Aizenberg, Giuseppe Falini Biotemplating makes it possible to prepare materials with complex structures taking advantage of nature ’s ability to generate unique morphologies. In this work, we designed and produced a multi-scale porosity (MSP)... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Giulia Magnabosco Source Type: research

Correction: A silver –manganese dual co-catalyst for selective reduction of carbon dioxide into carbon monoxide over a potassium hexatitanate photocatalyst with water
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Xing Zhu, Akira Yamamoto, Shota Imai, Atsuhiro Tanaka, Hiroshi Kominami, Hisao Yoshida To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Xing Zhu Source Type: research

A copper-catalyzed insertion of sulfur dioxide via radical coupling
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00375A, CommunicationJun Zhang, Min Yang, Jin-Biao Liu, Fu-Sheng He, Jie Wu A copper-catalyzed three ‐component reaction of O-acyl oximes, DABCO·(SO2)2, and 2H-azirines under mild conditions has been achieved. This protocol provides an efficient route for the construction of various tetrasubstituted β‐sulfonyl N-unprotected... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Jun Zhang Source Type: research

Rational design of pyrrolopyrrole-aza-BODIPY-based acceptor-donor-acceptor triads for organic photovoltaics application
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00398K, CommunicationRu Feng, Narumi Sato, Takuma Yasuda, Hiroyuki Furuta, Soji Shimizu Acceptor-donor-acceptor triads consisting of diketopyrrolopyrrole (DPP) or pyrrolopyrrole aza-BODIPY (PPAB) or both as acceptors and cyclopentadithiophene as a donor were rationally designed for near infrared (NIR) photovoltaics application. Among them,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Ru Feng Source Type: research

Mass Spectrometry Reveals the Assembly Pathway of Encapsulated Ferritins and Highlights a Dynamic Ferroxidase Interface
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Jennifer Ross, Thomas Lambert, Cecilia Piergentili, Didi He, C. Logan Mackay, Kevin Waldron, Jon Marles-Wright, David Clarke Encapsulated ferritins (EncFtn) are a recently characterised member of the ferritin superfamily. EncFtn proteins are sequestered within encapsulin nanocompartments and form a unique biological iron storage system. Here, we use... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Jennifer Ross Source Type: research

Two-in-one: construction of hydroxyl and imidazolium-bifunctionalized ionic networks in one-pot toward synergistic catalytic CO2 fixation
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/C9CC09643D, CommunicationYadong Zhang, Guojian Chen, Lei Wu, Ke Liu, Hu Zhong, Zhouyang Long, Minman Tong, Zhenzhen Yang, Sheng Dai A succinct strategy was demonstrated for constructing a hydroxyl group and imidazolium-bifunctionalized ionic network via a one-pot quaternization. Key to success lies in the rational design of multi-imidazole precursor and... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Yadong Zhang Source Type: research

High rate asymmetrical supercapacitor based on Cobalt doped birnessite nanotubes and Mn-FeOOH nanotubes
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00749H, CommunicationMan Shen, Shijin Zhu, Ziyang Guo, Xin Fu, Wangchen Huo, Chuan Jing, Xiao Ying Liu, Yuxin Zhang Co doped MnO2 nanotubes (Co-MnO2-5) were prepared as a positive electrode of supercapacitors via a simple one-step hydrothermal method. Co doping and one-dimensional tunneling of nanotubes result in low internal... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Man Shen Source Type: research

Experimental evidence of Chalcogen bonding at oxygen
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/C9CC09896H, CommunicationThomas Fellowes, Benjamin L Harris, Jonathan White An o-nitro-O-aryl oxime was observed to exhibit a short O...O contact, which exhibited characteristics consistent with a chalcogen bond. Topological analysis of the experimental electron density of two analogues shows... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Thomas Fellowes Source Type: research

Observing structure-dependent electrocatalytic activity of bimetallic Pd-Au nanorods at single-particle level
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00185F, CommunicationMing-Ming Chen, Cong-Hui Xu, Wei Zhao, Hong-Yuan Chen, Jing-Juan Xu We developed an electrochemiluminescence (ECL) microscopy to image the structure-dependent electrocatalytic reactivity of bimetallic Pd-Au nanorods (NRs) at single-particle level. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 14, 2020 Category: Chemistry Authors: Ming-Ming Chen Source Type: research

Asymmetric Synthesis of Quaternary α-Trifluoromethyl α-Amino Acids by Ir-Catalyzed Allylation Followed by Kinetic Resolution
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00845A, CommunicationXi-Shang Sun, Qiu Ou-Yang, Shi-Ming Xu, Xing-Heng Wang, Hai-Yan Tao, Lung Wa Chung, Chun-Jiang Wang A facile access to quaternary α-Trifluoromethyl α-Amino Acids has been developed. This sequential reaction, which involves an Ir-catalyzed asymmetric allylation of α-trifluoromethyl aldimine esters followed by an unprecedented kinetic resolution. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 13, 2020 Category: Chemistry Authors: Xi-Shang Sun Source Type: research

Visible-light photoredox-catalyzed dual C –C bond cleavage: synthesis of 2-cyanoalkylsulfonylated 3,4-dihydronaphthalenes through the insertion of sulfur dioxide
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC10057A, CommunicationYu Liu, Qiao-Lin Wang, Zan Chen, Hua Li, Bi-Quan Xiong, Pan-Liang Zhang, Ke-Wen Tang A novel visible-light photoredox-catalyzed dual C –C bond cleavage of methylenecyclopropanes and cycloketone oximes for accessing 2-cyanoalkylsulfonated 3,4-dihydronaphthalenes is established. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 13, 2020 Category: Chemistry Authors: Yu Liu Source Type: research

Niacin-ligated platinum(IV) –ruthenium(II) chimeric complexes synergistically suppress tumor metastasis and growth with potentially reduced toxicity in vivo
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC09016A, CommunicationLiwei Shu, Lulu Ren, Yuchen Wang, Tao Fang, Zhijian Ye, Weidong Han, Chao Chen, Hangxiang Wang The chimeric Pt(IV) –Ru(II) complex was designed to simultaneously release cytotoxic cisplatin and an antimetastatic Ru(II) –arene compound, thereby producing potent anticancer activity with high drug tolerability in animals. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 13, 2020 Category: Chemistry Authors: Liwei Shu Source Type: research

The affinity of RSK for cylitol analogues of SL0101 is critically dependent on the B-ring C-4 ′-hydroxy
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00128G, CommunicationYu Li, Pedro Seber, Eric B. Wright, Sharia Yasmin, Deborah A. Lannigan, George A. O'Doherty Thede novo asymmetric synthesis of carbohydrates for the SAR-study of the anticancer natural product, SL0101. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 13, 2020 Category: Chemistry Authors: Yu Li Source Type: research

Light-activated semiconducting polymer dots as mimic oxidases with remarkable catalytic efficiency: characteristics, mechanisms, and applications
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC08912H, CommunicationXueli Chen, Junyong Sun, Qiang Zhang, Xuekai Jiang, Feng Gao Herein we demonstrate the characteristics, mechanisms, and applications of light-activated semiconducting polymer dots as mimic oxidases with remarkable catalytic efficiency. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 13, 2020 Category: Chemistry Authors: Xueli Chen Source Type: research

Nucleus-targeting ultrasmall ruthenium(IV) oxide nanoparticles for photoacoustic imaging and low-temperature photothermal therapy in the NIR-II window
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC09728G, CommunicationZhou Liu, Kangqiang Qiu, Xinxing Liao, Thomas W. Rees, Yu Chen, Zizhuo Zhao, Liangnian Ji, Hui Chao In the present study novel ultrasmallCS-RuO2NPs with intrinsic nuclear-targeting properties were developed for photoacoustic imaging and low-temperature photothermal therapy of cancer in the NIR-II window. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 13, 2020 Category: Chemistry Authors: Zhou Liu Source Type: research

Ionic liquid-induced nanoporous structures of polymer films
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC08768K, CommunicationXiao Gong, Jixi Zhang, Shaohua Jiang Nanoporous polymer thin films can be fabricated using strong polyelectrolyte pairs in ionic liquid aqueous solutions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - February 13, 2020 Category: Chemistry Authors: Xiao Gong Source Type: research