Facile access to C-substituted piperazin-2-ones and mianserin derivative enabled by chemoselective carbene insertion and cyclization cascade
Chem. Commun., 2024, Accepted Manuscript DOI: 10.1039/D4CC00959B, CommunicationDharmendra Kumar, Urmila Unnikrishnan, Malleswara Rao Kuram The chemoselective N-H insertion of unsymmetrical diamines into carbene is a longstanding challenge. A simple copper-catalyzed strategy for synthesizing C-substituted piperazinones is described, employing easily accessible diazo compounds and 1,2-diamines.... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 6, 2024 Category: Chemistry Authors: Dharmendra Kumar Source Type: research

Mesoporous supraparticles with a tailored solid-liquid-gas interface for visual indication of H2 gas and NH3 vapours
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Andreas Zink, Jakob Reichstein, Nico Ruhland, Nina Stockinger, Boris S. Morozov, Carlos Cuadrado Collados, Matthias Thommes, Evgeny Kataev, Susanne Wintzheimer, Karl Mandel Dual-gasochromic supraparticles that undergo rapid eye-readable and gas-specific colour changes upon reaction with hydrogen or ammonia are reported. This functionality is achieved by tailoring the solid –liquid–gas interface within the mesoporous... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 6, 2024 Category: Chemistry Authors: Andreas Zink Source Type: research

Highly Bifunctional Rh2P on N, P-Codoped Carbon for Hydrazine Oxidation Assisted Energy-Saving Hydrogen Production
Chem. Commun., 2024, Accepted Manuscript DOI: 10.1039/D4CC01267D, CommunicationSimeng Zhao, Yu Sun, Haibo Li, Suyuan Zeng, Qingxia Yao, Rui Li, Hongyan Chen, Konggang Qu The highly pure Rh2P nanoparticles on N,P-codoped carbon were synthesized by a simple ‘‘mix-and-pyrolyze’’ method using one kind of low-cost nucleotide as carbon, nitrogen and phosphorus sources, which exhibits excellent... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 6, 2024 Category: Chemistry Authors: Simeng Zhao Source Type: research

Luminescence center modulation for the synthesis of a narrow-band green phosphor: mechanism and backlighting display application
Chem. Commun., 2024, Advance Article DOI: 10.1039/D4CC01093K, CommunicationGongli Chen, Yaxin Cao, ZhenHua Li, Xicheng Wang, Yuhua Wang A highly efficient and stable green phosphor with a narrow emission-band was developed based on the energy transfer between Eu2+ and Mn2+ luminescence centers. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 4, 2024 Category: Chemistry Authors: Gongli Chen Source Type: research

Promoting C –C coupling for CO2 reduction on Cu2O electrocatalysts with atomically dispersed Rh atoms
Chem. Commun., 2024, Advance Article DOI: 10.1039/D4CC01254B, CommunicationChengcheng Feng, Ruizhi Duan, Haibo Chi, Fengyuan Liu, Rui Song, Mingrun Li, Wenguang Yu, Chunmei Ding, Can Li Cu2O doped with atomically dispersed Rh shows higher performance for CO2 reduction to C2+ products due to the promoted CO2 adsorption, *CO hydrogenation to *CHO and their coupling to O*CCHO intermediates. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 4, 2024 Category: Chemistry Authors: Chengcheng Feng Source Type: research

Nanoelectrochemistry monitoring of intracellular reactive oxygen and nitrogen species induced by nanoplastic exposure
Chem. Commun., 2024, Advance Article DOI: 10.1039/D4CC01516A, CommunicationHui-Qian Wu, Yu-Ting Qi, Bing-Yi Guo, Yi Zhao, Xin-Wei Zhang, Wei-Hua Huang This work achieved the quantitative discrimination, dynamic monitoring and sources exploration of four main ROS/RNS (NO2−, NO, H2O2, ONOO−) within individual alveolar epithelial cells treated by polystyrene nanoplastics using SiC@Pt nanowire electrodes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 4, 2024 Category: Chemistry Authors: Hui-Qian Wu Source Type: research

Lewis Base Adducts of NpCl4
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Lauren Marie Lopez, Madeleine Uible, Suzanne Cathleen Bart, Matthias Zeller Np(IV) Lewis base adducts were prepared by ligand substitution of NpCl4(DME)2. Using acetonitrile and pyridine, NpCl4(MeCN)4 (1) and NpCl4(pyr)4 (2), were isolated, respectively. Addition of t-butylbipyridine and triphenylphosphine oxide generated... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 4, 2024 Category: Chemistry Authors: Lauren Marie Lopez Source Type: research

Unprecedented ROP of quinazolinones to polyacylamidines using a cesium catalyst
Chem. Commun., 2024, Advance Article DOI: 10.1039/D4CC00491D, CommunicationShweta Sagar, Priyanku Nath, Devadkar Ajitrao Kisan, Himadri Karmakar, Aranya Ray, Alok Sarkar, Tarun K. Panda A series of high-performance imine-spaced aromatic polyamide materials, prepared with excellent control of molecular weights and polydispersity index from catalytic ring-opening polymerization of quinazolinones using a cesium catalyst, are reported. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 3, 2024 Category: Chemistry Authors: Shweta Sagar Source Type: research

In situ construction A-site high-entropy Perovskite with interfacial CeO2 for high performance IT-SOFC air-electrode
Chem. Commun., 2024, Accepted Manuscript DOI: 10.1039/D4CC00995A, CommunicationXuelong Li, Shuaihang Chen, Qian Yang, Fengyang Yu, Yunhe Zhang, Lina Su, Jianhua Liu, Li Li Developing intermediate-temperature solid oxide fuel cell (IT-SOFC) is one of the most promising ways for achieving carbon neutrality, but its air-electrode is restricted by the conflict between the sluggish catalytic... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 3, 2024 Category: Chemistry Authors: Xuelong Li Source Type: research

Collaborative manipulation strategy to enhance sodium ion storage capability of Prussian white cathodes
Chem. Commun., 2024, Accepted Manuscript DOI: 10.1039/D4CC01027B, CommunicationZhibin Zhang, Yuan Gao, Jing Gao, Wenyan Si, Xiaolin Sun, Fuhua Zhao, Yuan Zhang, Zhonghua Zhang, Depeng Song, Jianfei Wu Collaboratively manipulating strategy of proper heat treatment and self-customized hydrofluoroether-based electrolyte design has been proposed for boosting sodium-ion storge kinetics of Prussian white cathodes. Improved cubic phase stability and electrolyte-cathode... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 3, 2024 Category: Chemistry Authors: Zhibin Zhang Source Type: research

Preparing glycosyl benzothiazoles from 2-isocyanoaryl thioethers and glycosyl radicals under thermal conditions
Chem. Commun., 2024, Advance Article DOI: 10.1039/D4CC00648H, CommunicationDaqi Liu, Yang Zhang, Dawen Niu Glycosyl radicals generated from readily available and bench-stable allyl glycosyl sulfones, promoting radical cascade cyclization for preparing glycosyl benzothiazoles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 2, 2024 Category: Chemistry Authors: Daqi Liu Source Type: research

Triptycene-based diiron(II) mesocates: spin-crossover in solution
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Riccardo Mobili, Giovanni Preda, Daniele Dondi, Enrico Monzani, Dhanalakshmi Vadivel, Chiara Massera, Dario Pasini, Valeria Amendola A triptycene-based diiron(II) mesocate, synthesized using a rigid ligand containing two pyridylbenzimidazole chelating units, exhibited thermal-induced spin-crossover behaviour in solution. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 2, 2024 Category: Chemistry Authors: Riccardo Mobili Source Type: research

Cooperative heterometallic catalysts: balancing activity and control in PCL-block-PLA copolymer synthesis
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Maisarah Abdul Rahman, Thomas J. Neal, Jennifer A. Garden Heterometallic “ate” complexes show enhanced activities in ε-caprolactone/lactide polymerisation giving well-defined diblock copolymers, yet also enhance transesterification under certain conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 2, 2024 Category: Chemistry Authors: Maisarah Abdul Rahman Source Type: research

Colloidal synthesis of metallodielectric Janus matchsticks
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Yijiang Mu, Wendi Duan, Yuxuan Dai, Patrick A. Sullivan, Leila F. Deravi, Yufeng Wang, Daeyeon Lee Metallodielectric Janus matchsticks with variable aspect ratios are synthesized through a scalable approach that uses silica growth and functionalization at one end of microrods, followed by site-specific gold deposition. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 2, 2024 Category: Chemistry Authors: Yijiang Mu Source Type: research

Chronicles of plutonium peroxides: spectroscopic characterization of a new peroxo compound of Pu(IV)
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Julien Margate, Simon Bayle, Thomas Dumas, Elodie Dalodi ère, Christelle Tamain, Denis Menut, Paul Estevenon, Philippe Moisy, Sergey Nikitenko, Matthieu Virot Although hydrogen peroxide (H2O2) has been highly used in nuclear chemistry for more than 75 years, the preparation and literature description of tetravalent actinide peroxides remain surprisingly scarce. A new... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 2, 2024 Category: Chemistry Authors: Julien Margate Source Type: research