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Cyano disubstituted tetrabenzoindeno[2,1-a]fluorene: open-shell or closed-shell?
We report the unprecedented synthesis of a near-IR absorbing indeno[2,1-a]fluorene derivative that displayed remarkably low LUMO ( −4.15 eV) and a small... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 7, 2024 Category: Chemistry Authors: Priyank Kumar Sharma Source Type: research

Aggregation-induced emission photosensitizer for antibacterial therapy of methicillin-resistant Staphylococcus aureus
Chem. Commun., 2024, Accepted Manuscript DOI: 10.1039/D4CC01022A, CommunicationZheng Zhao, Lin Kong, Rongyuan Zhang, Junyi Gong, Huan Wang, Linyu Zhai, Dongfeng Dang, Qian Liu, Ben-Zhong Tang A cationic aggregation-induced emission photosensitizer (AIE-PS) MNNPyBB has been reported to have antibacterial effects against both gram-positive and gram-negative bacteria. The bacterial kill mechanism has been investigated and elucidated. In... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 7, 2024 Category: Chemistry Authors: Zheng Zhao Source Type: research

Appropriation of group II metals: Synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Siad Wolff, Annabelle Ponsonby, Andre Dallmann, Christian Herwig, Fabian Beckmann, Beatrice Cula, Christian Limberg Nickel carbonite complexes supported by alkaline earth metals have been accessed via salt-metathesis of the corresponding alkali metal precursors. The new complexes undergo Schlenk-like exchange reactions in solution which have... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 7, 2024 Category: Chemistry Authors: Siad Wolff Source Type: research

Molecule engineering strategy of toll-like receptor 7/8 agonists designed for potentiating immune stimuli activation
Chem. Commun., 2024, Advance Article DOI: 10.1039/D4CC00792A, Feature ArticleLiuwei Gu, Xiaojie Kong, Mengyan Li, Rui Chen, Ke Xu, Guo Li, Yulin Qin, Li Wu We highlighted the recent research progress concerning the molecule engineering strategy of toll-like receptor 7/8 agonists for enhancing immunotherapy, including our research work and some related emerging works. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 7, 2024 Category: Chemistry Authors: Liuwei Gu Source Type: research

High adsorption of ammonia in a titanium-based metal –organic framework
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Xiangdi Zeng, Jiangnan Li, Meng He, Wanpeng Lu, Danielle Crawshaw, Lixia Guo, Yujie Ma, Meredydd Kippax-Jones, Yongqiang Cheng, Pascal Manuel, Svemir Rudi ć, Mark D. Frogley, Martin Schröder, Sihai Yang A robust titanium-based metal –organic framework, MFM-300(Ti), exhibits an exceptional NH3 adsorption of 23.4 mmol g−1 with a record-high packing density of 0.84 g cm−3, promoted by strong binding interactions of NH3 to the framework oxygen sites. To cite this article before page numbers are assigned, use the DOI form of citation above...
Source: RSC - Chem. Commun. latest articles - May 7, 2024 Category: Chemistry Authors: Xiangdi Zeng Source Type: research

Crystalline modulation of zirconia for efficient nitrate reduction to ammonia under ambient conditions
Chem. Commun., 2024, Advance Article DOI: 10.1039/D4CC01399A, CommunicationZhiruo Tao, Haitao Yin, Yaxin Lv, Haoran Guo, Jun Song Chen, Xiaoyu Ye, Haohong Xian, Shengjun Sun, Tingshuai Li The crystalline structures of zirconia are modulated by scandium doping and proposed as a robust catalyst for nitrate reduction to ammonia. The tetragonal zirconia achieves a maximum ammonia yield in 0.1 M PBS with 0.1 M NO3−. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 7, 2024 Category: Chemistry Authors: Zhiruo Tao Source Type: research

Inherent directing group enabled Co(III)-catalyzed C-H allylation/vinylation of isoquinolones
Chem. Commun., 2024, Accepted Manuscript DOI: 10.1039/D4CC01146E, CommunicationSachin ., Tamanna Sharma, Devesh Chandra, Sumit ., Upendra Sharma The site-selective C8-allylation and vinylation of isoquinolones has been accomplished using allyl acetate and vinyl acetates and oxo group of isoquinolone as an inherent directing group in the presence of... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 7, 2024 Category: Chemistry Authors: Sachin . Source Type: research

Superior electrocatalytic hydrogen evolution activity of a triply bridged diruthenium(II) complex on carbon cloth support
Chem. Commun., 2024, Accepted Manuscript DOI: 10.1039/D4CC01173B, CommunicationYogita Arya, Toufik Ansari, Sudip Bera, Sanjib Panda, Arindam Indra, Goutam Kumar Lahiri The article described structural authentication of a unique triply bridged [1](ClO4)2 and monomeric [2]ClO4/[3]ClO4. Electrochemical HER on carbon cloth support demonstrated superior performance of [1](ClO4)2 with high TON ( 105) and... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 7, 2024 Category: Chemistry Authors: Yogita Arya Source Type: research

Stereoselective synthesis of an advanced trans-decalin intermediate towards the total synthesis of anthracimycin
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Laksamee Jeanmard, Giacomo Lodovici, Ian George, Joshua T W Bray, Adrian Charles Whitwood, Gavin Thomas, Ian J. S. Fairlamb, William Paul Unsworth, Paul Clarke Progress towards the total synthesis of the macrolide natural product anthracimycin is described. This new approach utilises an intermolecular Diels-Alder strategy followed by epimeirsation to form the key trans-decalin framework.... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 7, 2024 Category: Chemistry Authors: Laksamee Jeanmard Source Type: research

Synthesis and property of an O-doped aromatic belt
Chem. Commun., 2024, Accepted Manuscript DOI: 10.1039/D4CC01667J, CommunicationYing Han, Wei-Chen Guo, Xu-Sheng Du, Chuan-Feng Chen A new macrocyclic arene, dibenzofuran[3]arene, was synthesized, which could be conveniently transformed to O-doped aromatic belt with a rigid ring-shaped structure and deep cavity. Moreover, the O-doped aromatic belt also... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 6, 2024 Category: Chemistry Authors: Ying Han Source Type: research

Solvent-free Transformation of Protic Ionic Liquids into Zwitterions
Chem. Commun., 2024, Accepted Manuscript DOI: 10.1039/D4CC01345J, CommunicationYosuke Nakazono, Ryota Inoue, Ryo Sumitani, Tomoyuki Mochida We synthesized several protic ionic liquids (ILs) composed of onium cations and the (trifluoromethylsulfonyl)(vinylsulfonyl)amide anion. The addition of a base catalytically facilitated their transformation into zwitterions (ZIs) under solvent-free conditions,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 6, 2024 Category: Chemistry Authors: Yosuke Nakazono Source Type: research

Facile access to C-substituted piperazin-2-ones and mianserin derivative enabled by chemoselective carbene insertion and cyclization cascade
Chem. Commun., 2024, Accepted Manuscript DOI: 10.1039/D4CC00959B, CommunicationDharmendra Kumar, Urmila Unnikrishnan, Malleswara Rao Kuram The chemoselective N-H insertion of unsymmetrical diamines into carbene is a longstanding challenge. A simple copper-catalyzed strategy for synthesizing C-substituted piperazinones is described, employing easily accessible diazo compounds and 1,2-diamines.... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 6, 2024 Category: Chemistry Authors: Dharmendra Kumar Source Type: research

Mesoporous supraparticles with a tailored solid-liquid-gas interface for visual indication of H2 gas and NH3 vapours
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Andreas Zink, Jakob Reichstein, Nico Ruhland, Nina Stockinger, Boris S. Morozov, Carlos Cuadrado Collados, Matthias Thommes, Evgeny Kataev, Susanne Wintzheimer, Karl Mandel Dual-gasochromic supraparticles that undergo rapid eye-readable and gas-specific colour changes upon reaction with hydrogen or ammonia are reported. This functionality is achieved by tailoring the solid –liquid–gas interface within the mesoporous... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 6, 2024 Category: Chemistry Authors: Andreas Zink Source Type: research

Highly Bifunctional Rh2P on N, P-Codoped Carbon for Hydrazine Oxidation Assisted Energy-Saving Hydrogen Production
Chem. Commun., 2024, Accepted Manuscript DOI: 10.1039/D4CC01267D, CommunicationSimeng Zhao, Yu Sun, Haibo Li, Suyuan Zeng, Qingxia Yao, Rui Li, Hongyan Chen, Konggang Qu The highly pure Rh2P nanoparticles on N,P-codoped carbon were synthesized by a simple ‘‘mix-and-pyrolyze’’ method using one kind of low-cost nucleotide as carbon, nitrogen and phosphorus sources, which exhibits excellent... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 6, 2024 Category: Chemistry Authors: Simeng Zhao Source Type: research

Luminescence center modulation for the synthesis of a narrow-band green phosphor: mechanism and backlighting display application
Chem. Commun., 2024, Advance Article DOI: 10.1039/D4CC01093K, CommunicationGongli Chen, Yaxin Cao, ZhenHua Li, Xicheng Wang, Yuhua Wang A highly efficient and stable green phosphor with a narrow emission-band was developed based on the energy transfer between Eu2+ and Mn2+ luminescence centers. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 4, 2024 Category: Chemistry Authors: Gongli Chen Source Type: research