Green-synthesized lignin nanoparticles enhance Zea mays resilience to salt stress by improving antioxidant metabolism and mitigating ultrastructural damage
Chemosphere. 2024 May 14;359:142337. doi: 10.1016/j.chemosphere.2024.142337. Online ahead of print.ABSTRACTSoil salinity poses a substantial threat to agricultural productivity, resulting in far-reaching consequences. Green-synthesized lignin nanoparticles (LNPs) have emerged as significant biopolymers which effectively promote sustainable crop production and enhance abiotic stress tolerance. However, the defensive role and underlying mechanisms of LNPs against salt stress in Zea mays remain unexplored. The present study aims to elucidate two aspects: firstly, the synthesis of lignin nanoparticles from alkali lignin, which...
Source: Chemosphere - May 16, 2024 Category: Chemistry Authors: Muhammad Haseeb Javaid Nana Chen Muhammad Umair Yasin Xingming Fan Asifa Neelam Muhammad Rehman Zulqarnain Haider Syed Asad Hussain Bukhari Raheel Munir Irshan Ahmad Yinbo Gan Source Type: research

Structure, chemical modification, and functional applications of mucilage from Mimosa pudica seeds - A review
Int J Biol Macromol. 2024 May 14:132390. doi: 10.1016/j.ijbiomac.2024.132390. Online ahead of print.ABSTRACTMimosa pudica (MP) is an ornamental plant due to seismonastic movements that close leaves and fall petioles in response to touch, wind, light, heat, cold, and vibration. The seeds of MP secrete smart, biocompatible, and non-toxic mucilage that has captivated researchers due to its widespread use in various fields such as pharmaceuticals and biotechnology. The mucilage is responsive to pH, salt solutions, and solvents and acts as a binder in tablet formulations for targeted drug delivery. The mucilage is chemically mo...
Source: International Journal of Biological Macromolecules - May 16, 2024 Category: Biochemistry Authors: Manahil Noor Gulzar Muhammad Hina Hanif Muhammad Ajaz Hussain Muhammad Mudassir Iqbal Uqba Mehmood Parham Taslimi Zahid Shafiq Source Type: research

Green-synthesized lignin nanoparticles enhance Zea mays resilience to salt stress by improving antioxidant metabolism and mitigating ultrastructural damage
Chemosphere. 2024 May 14;359:142337. doi: 10.1016/j.chemosphere.2024.142337. Online ahead of print.ABSTRACTSoil salinity poses a substantial threat to agricultural productivity, resulting in far-reaching consequences. Green-synthesized lignin nanoparticles (LNPs) have emerged as significant biopolymers which effectively promote sustainable crop production and enhance abiotic stress tolerance. However, the defensive role and underlying mechanisms of LNPs against salt stress in Zea mays remain unexplored. The present study aims to elucidate two aspects: firstly, the synthesis of lignin nanoparticles from alkali lignin, which...
Source: Chemosphere - May 16, 2024 Category: Chemistry Authors: Muhammad Haseeb Javaid Nana Chen Muhammad Umair Yasin Xingming Fan Asifa Neelam Muhammad Rehman Zulqarnain Haider Syed Asad Hussain Bukhari Raheel Munir Irshan Ahmad Yinbo Gan Source Type: research

Biochar-Enhanced Three-Dimensional Conductive Network Thick Electrodes for Efficient Lithium Extraction from Salt Lake Brines with High Magnesia-lithium Ratios
In this study, we developed a biochar-based, 3D-conductive network thick electrode (∼20 mg·cm-2) by in-situ deposition of LiFePO4 (LFP) onto watermelon peel biomass (WB). Utilizing Density Functional Theory (DFT) calculations complemented by experimental data, we confirmed that this The thick electrode exhibits outstanding kinetic properties and a high capacity for lithium intercalation in brines, even in environments where the Magnesia-lithium ratios are significantly high. The electrode showed an impressive intercalation capacity of 30.67 mg·g-1 within 10 minutes in a pure lithium solution. It also maintained high in...
Source: Chemosphere - May 16, 2024 Category: Chemistry Authors: Junyi Zhang Wencheng Pan Yuan Zhou Chunxi Hai You Xu Yan Zhao Yanxia Sun Shengde Dong Xin He Qi Xu Jitao Chen Hongli Su Luxiang Ma Source Type: research

Comprehensive rheological analysis of structurally related acetan-like heteroexopolysaccharides from two Kozakia baliensis strains in surfactants and galactomannan blends
This study shows that heteroexopolysaccharides of K. baliensis are capable of further extending the portfolio of bio-based rheological modifiers.PMID:38750817 | DOI:10.1016/j.nbt.2024.05.003 (Source: New Biotechnology)
Source: New Biotechnology - May 16, 2024 Category: Biotechnology Authors: Julia Schilling Jochen Schmid Source Type: research

Role of the median preoptic nucleus in the development of chronic deoxycorticosterone acetate (DOCA) ‐salt hypertension
AbstractWe have previously reported that the subfornical organ (SFO) does not contribute to the chronic hypertensive response to DOCA-salt in rats, and yet the organum vasculosum of the lamina terminalis (OVLT) plays a significant role in the development of deoxycorticosterone acetate (DOCA)-salt hypertension. Since efferent fibers of the OVLT project to and through the median preoptic nucleus (MnPO), the present study was designed to test the hypothesis that the MnPO is necessary for DOCA-salt hypertension in the rat. Male Sprague-Dawley rats underwent SHAM (MnPOsham;n = 5) or electrolytic lesion of the MnPO (MnPOx;n...
Source: Physiological Reports - May 16, 2024 Category: Physiology Authors: John P. Collister, Nora Fritcher, David Nahey Tags: ORIGINAL ARTICLE Source Type: research

Hydrophobic TaOx Species Overlayer Tuning Light ‐Driven Methane Chlorination with Inorganic Chlorine
Hydrophobic TaOx species overlayer is in situ fabricated on the surface of sodium tantalate to promote the concentration and effective activation of methane on photocatalyst surface in gas-liquid-solid three phase reaction. Without any noble metal assistance, TaOx/NaTaO3 photocatalyst induces the change from nonactivity over NaTaO3 to the efficiently photocatalytic methane chlorination in sodium chloride solution. AbstractHalogenated methane serves as a universal platform molecule for building high-value chemicals. Utilizing sodium chloride solution for photocatalytic methane chlorination presents an environmentally friend...
Source: Small - May 16, 2024 Category: Nanotechnology Authors: Dongmiao Li, Min Lin, Jiangjie Zhang, Chengwei Qiu, Hui Chen, Zhen Xiao, Jinni Shen, Yuanhui Zheng, Jinlin Long, Wenxin Dai, Xuxu Wang, Xianzhi Fu, Zizhong Zhang Tags: Research Article Source Type: research

Unlocking the Power of Magnesium Batteries: Synergistic Effect of InSb ‐C Composites to Achieve Superior Electrochemical Performance
In this study, the InSb-10%C anode is synthesized by a two-step high-energy ball milling process. The InSb-10%C anode exhibits a remarkably high capacity of up to 448 mA h g−1, significantly improved cycle performance (234 mA h g−1 at 100 cycles) and rate performance (168 mA h g−1 at 500 mA g−1). The above-mentioned superior performance of the InSb-10%C anode for RMBs is attributed to the cellular graphitized amorphous carbon composite structure (CGA) which effectively refines the particle size and restricts the volume expansion. Additionally, the reduced surface electron density of InSb combined with the high cond...
Source: Small - May 16, 2024 Category: Nanotechnology Authors: Xianhao Peng, Yuan Yuan, Dachong Gu, Xingwang Zheng, Dajian Li, Liang Wu, Guangsheng Huang, Jingfeng Wang, Fusheng Pan Tags: Research Article Source Type: research

The Simpler the Better: Ultrafast Air ‐Plasma Synthesis of 3D Crosslinked Graphene Nanoscroll‐Nanosheet Aerogels at Room Temperature for Capacitive Deionization
The graphene nanoscroll-nanosheet aerogel is synthesized using ultrafast air-plasma method within 1 s. Benefiting from its unique 1D-2D-3D structure, the as-prepared material shows superior figure of merits for capacitive deionization. This air-plasma strategy with obvious advantages of simplicity, time-saving and cost-effective opens a new pathway to large-scale synthesis of high-quality nanostructured graphene materials for their practical applications. AbstractGraphene nanoscroll (GNS) is an important 1D tubular form of graphene-derivative materials, which has garnered widely attention. However, conventional fabrication...
Source: Small - May 16, 2024 Category: Nanotechnology Authors: Weiqing Kong, Xu Ge, Xiaoyuan Lu, Qingao Zhang, Meng Zhang, Yuanyuan Feng Tags: Research Article Source Type: research

Synthetic, structural and reactivity studies of a boryl-ethynyl Silylene
Chem. Commun., 2024, Advance Article DOI: 10.1039/D4CC00922C, CommunicationWenhao Chen, Haisheng Hu, Jie Feng, Lei Zhu, Di Wu The salt metathesis of a boryl-ethynyl lithium salt {[(HCDipN)2]B-CC-Li} with a monochlorosilylene [LSi(:)Cl; L = PhC(NtBu)2] gave rise to an isolable ethynyl silylene {[(HCDipN)2]B-CC-Si(L)}, confirmed by X-ray diffraction analysis and DFT calculations. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 15, 2024 Category: Chemistry Authors: Wenhao Chen Source Type: research

Electrostatics introduce a trade ‐off between mesophilic stability and adaptation in halophilic proteins
AbstractExtremophile organisms have adapted to extreme physicochemical conditions. Halophilic organisms, in particular, survive at very high salt concentrations. To achieve this, they have engineered the surface of their proteins to increase the number of short, polar and acidic amino acids, while decreasing large, hydrophobic and basic residues. While these adaptations initially decrease protein stability in the absence of salt, they grant halophilic proteins remarkable stability in environments with extremely high salt concentrations, where non-adapted proteins unfold and aggregate. The molecular mechanisms by which halo...
Source: Protein Science - May 15, 2024 Category: Biochemistry Authors: Pablo Herrero ‐Alfonso, Alba Pejenaute, Oscar Millet, Gabriel Ortega‐Quintanilla Tags: RESEARCH ARTICLE Source Type: research

A salt bridge of the C ‐terminal carboxyl group regulates PHPT1 substrate affinity and catalytic activity
AbstractPHPT1 is a histidine phosphatase that modulates signaling in eukaryotes through its catalytic activity. Here, we present an analysis of the structure and dynamics of PHPT1 through a combination of solution NMR, molecular dynamics, and biochemical experiments. We identify a salt bridge formed between the R78 guanidinium moiety and the C-terminal carboxyl group on Y125 that is critical for ligand binding. Disruption of the salt bridge by appending a glycine residue at the C-terminus (G126) leads to a decrease in catalytic activity and binding affinity for the pseudo substrate, para-nitrophenylphosphate (pNPP), as wel...
Source: Protein Science - May 15, 2024 Category: Biochemistry Authors: Erik Zavala, Stephen Dansereau, Michael J. Burke, James M. Lipchock, Federica Maschietto, Victor Batista, J. Patrick Loria Tags: RESEARCH ARTICLE Source Type: research

Synthetic, structural and reactivity studies of a boryl-ethynyl Silylene
Chem Commun (Camb). 2024 May 15. doi: 10.1039/d4cc00922c. Online ahead of print.ABSTRACTThe salt metathesis of a boryl-ethynyl lithium salt {[(HCDipN)2]B-CC-Li} with a monochlorosilylene [LSi(:)Cl; L = PhC(NtBu)2] produced an isolable boryl-ethynyl silylene {1; [(HCDipN)2]B-CC-Si(L)}. The Si(II) center in 1 possesses a nonbonding lone pair and forms a covalent bond with the ethynyl group. The characterization of 1 was carried out by multinuclear NMR spectroscopy, single-crystal X-ray structure analysis and DFT calculations. Additionally, a reactivity study of 1 was conducted towards oxygen-containing and aryl C-F substr...
Source: Chemical Communications - May 15, 2024 Category: Chemistry Authors: Wenhao Chen Haisheng Hu Jie Feng Lei Zhu Di Wu Source Type: research

Mobility, bioavailability and distribution of Fe and Cu in mangroves (Avicennia schaueriana and Rhizophora mangle) from a semiarid coast in NE Brazil
An Acad Bras Cienc. 2024 May 10;96(2):e20231075. doi: 10.1590/0001-3765202420231075. eCollection 2024.ABSTRACTMangroves buffer metals transfer to coastal areas though strong accumulation in sediments making necessary to investigate metals' bioavailability to plants at the rhizosphere. This work evaluates the effect of mangrove root activity, through iron plaque formation, on the mobility of iron and copper its influence on metals' uptake, and translocation through simultaneous histochemical analysis. The Fe2+ and Fe3+ contents in porewaters ranged from 0.02 to 0.11 µM and 1.0 to 18.3 µg.l-1, respectively, whereas Cu conc...
Source: An Acad Bras Cienc - May 15, 2024 Category: Science Authors: Luiz D Lacerda Ingra B K Cavalcante Arlete A Soares Rozane V Marins Source Type: research

Use of dishwashers fails to inactivate foodborne pathogens in home-canned model foods
This study aimed to evaluate the inactivation of Shiga toxin-producing Escherichia coli O157:H7, Salmonella enterica (ser. Typhimurium, Enteritidis, and Infantis) and Listeria monocytogenes during home canning with a household dishwasher. The 450 mL of blended tomato (acidic liquid food) and potato puree (non-acidic solid food) were prepared with 1.5 % salt and 25 mL vinegar as model foods in glass jars (660 mL). The two model foods were sterilized, then inoculated with separate cocktails of each pathogen at 106-107 CFU/g. The prepared jars were placed in the bottom rack of a dishwasher and subjected to the following cycle...
Source: International Journal of Food Microbiology - May 15, 2024 Category: Food Science Authors: Seracettin Özcan Sefa I şık Hasan I şık Senem G üner Zeynal Topalcengiz Source Type: research