Theoretical, In vitro Anti-proliferative, and In silico Molecular Docking and Pharmacokinetics Studies of Heteroleptic Nickel(II) and Copper(II) Complexes of Thiosemicarbazone-Based Ligands and Pefloxacin
Chem Biodivers. 2023 Aug 1:e202300702. doi: 10.1002/cbdv.202300702. Online ahead of print.ABSTRACTTwelve new heteroleptic nickel(II) and copper(II) complexes of the type [M(L1 - 6)(Pfx)2] (1-12), where L1-6 = 2-benzylidenehydra-zinecarbothioamide (L1), 2-benzylidene-N-methylhydrazinecarbothioamide (L2), 2-benzyl-idene-N-phenylhydrazinecarbothioamide (L3), 2-(4-methylbenzylidene)hydrazinecarbothio-amide (L4), 2-(4-methylbenzylidene)-N-methylhydrazinecarbothioamide (L5) and 2-(4-methylbenzylidene)-N-phenylhydrazinecarbothioamide (L6), Pfx = pefloxacin and M = Ni(II) or Cu(II) have been synthesised, and their structures were ...
Source: Chemistry and Biodiversity - August 2, 2023 Category: Biochemistry Authors: Sumeer Ahmed Dharmasivam Mahendiran Ajmal Rashid Bhat A Kalilur Rahiman Source Type: research
Insight into the Failure Mechanism of Large-scale Cylindrical Lithium-Sulphur Cells
Chem. Commun., 2023, Accepted Manuscript DOI: 10.1039/D3CC02730A, CommunicationSurasak Kaenket, Salatan Duangdangchote, Kan Homlamai, Nattanon Joraleechanchai , Thitiphum Sangsanit, Worapol Tejangkura, Montree Sawangphruk Li-S batteries with a sulphur loading content of 5 mg/cm2 were produced at large-scale 18650 cylindrical cells. We have found that a key failure mode of cylindrical Li-S battery cells... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - July 28, 2023 Category: Chemistry Authors: Surasak Kaenket Source Type: research
Evaluation of the mobility of heavy metals in the sediments originating from the post-galvanic wastewater treatment processes
AbstractThe article presents the assessment of heavy metals mobility in sediments from the process of galvanic wastewater treatment (pH 2.5, Co 1.5 mg/L, Cr6+ < 0.02 mg/L, Cr(total) 62 mg/L, Cu 110 mg/L, Ni 129 mg/L and Pb 59 mg/L) based on the use of hydroxides (Ca(OH)2, NaOH) as well as inorganic and organic sulphur compounds (Na2S, sodium dimethyldithiocarbamate (DMDTC), sodium trithiocarbonate (Na2CS3), trimercapto-s-triazine trisodium salt, TMT). The leachability was assessed after 1, 7, 14 and 21 days of sediment contact with the leaching agent (deionized water). FeCl3 was used as a coagulant. The e...
Source: Environmental Geochemistry and Health - July 26, 2023 Category: Environmental Health Source Type: research
Integrating thermodynamics and mathematical modelling to investigate the stoichiometry and kinetics of sulphide oxidation-nitrate reduction with a special focus on partial autotrophic denitrification
Chemosphere. 2023 Jul 22:139605. doi: 10.1016/j.chemosphere.2023.139605. Online ahead of print.ABSTRACTIn the present study, the stoichiometry of the Sulphur Oxidizing-Nitrate Reducing (SO-NR) process, with a focus on Partial Autotrophic Denitrification (PAD), has been evaluated through a thermodynamic-based study whereas a model-based approach has been adopted to assess process kinetics. Experimental data on process performance and biomass yields were available from a previous work achieving efficient PAD, where a biomass yield of 0.113 gVSS/gS was estimated. First, the free Gibbs energy dissipation method has been implem...
Source: Chemosphere - July 24, 2023 Category: Chemistry Authors: Eric Vald és David Gabriel Daniel Gonz ález Giulio Munz Cecilia Polizzi Source Type: research
Integrating thermodynamics and mathematical modelling to investigate the stoichiometry and kinetics of sulphide oxidation-nitrate reduction with a special focus on partial autotrophic denitrification
Chemosphere. 2023 Jul 22:139605. doi: 10.1016/j.chemosphere.2023.139605. Online ahead of print.ABSTRACTIn the present study, the stoichiometry of the Sulphur Oxidizing-Nitrate Reducing (SO-NR) process, with a focus on Partial Autotrophic Denitrification (PAD), has been evaluated through a thermodynamic-based study whereas a model-based approach has been adopted to assess process kinetics. Experimental data on process performance and biomass yields were available from a previous work achieving efficient PAD, where a biomass yield of 0.113 gVSS/gS was estimated. First, the free Gibbs energy dissipation method has been implem...
Source: Chemosphere - July 24, 2023 Category: Chemistry Authors: Eric Vald és David Gabriel Daniel Gonz ález Giulio Munz Cecilia Polizzi Source Type: research
