Recent progress and perspectives on metal-organic frameworks as solid-state electrolytes for lithium batteries
Chem Commun (Camb). 2024 Apr 30. doi: 10.1039/d4cc01340a. Online ahead of print.ABSTRACTSolid-state electrolytes (SSEs) are the key materials in the new generation of all-solid-state lithium ion/metal batteries. Metal-organic frameworks (MOFs) are ideal materials for developing solid electrolytes because of their structural diversity and porous properties. However, there are several significant issues and obstacles involved, such as lower ion conductivity, a smaller ion transport number, a narrower electrochemical stability window and poor interface contact. In this review, a comprehensive analysis and summary of the uniqu...
Source: Chemical Communications - April 30, 2024 Category: Chemistry Authors: Xin Wang Sheng Jin Zhiliang Liu Source Type: research
Nonafluorobutyl Ether Enhancing Stability of Fluorobenzene-based Diluted High-Concentration Electrolyte in High-Voltage Lithium Metal Batteries
J. Mater. Chem. A, 2024, Accepted Manuscript DOI: 10.1039/D4TA01083C, PaperXinlan Wang, Ziqi Zeng, Han Zhang, Yixuan Dong, Shijie Cheng, Jia Xie The development of stable electrolytes for high-voltage lithium metal batteries (LMBs) is crucial for advancing battery technology. Diluted high-concentration electrolytes (DHCE) have shown promise in enhancing interfacial stability, yet challenges... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - J. Mater. Chem. latest articles)
Source: RSC - J. Mater. Chem. latest articles - April 30, 2024 Category: Chemistry Authors: Xinlan Wang Source Type: research
A bifunctional surfactant-like electrolyte additive for a stable lithium metal anode
Chem. Commun., 2024, Accepted Manuscript DOI: 10.1039/D4CC01082E, CommunicationHanxu Yang, Jiahang Zou, Zhengquan Xiao Nonafluorobutanesulfonyl fluoride (NtF) was developed as a bifunctional additive for enhancing the stability of the lithium metal anode. NtF can yield Nt+ and LiF. The presence of lithiophobic and lithiophilic... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - April 30, 2024 Category: Chemistry Authors: Hanxu Yang Source Type: research
Molecules, Vol. 29, Pages 2071: A Computational and Spectroscopic Analysis of Solvate Ionic Liquids Containing Anions with Long and Short Perfluorinated Alkyl Chains
. Burba
Anion-driven, nanoscale polar–apolar structural organization is investigated in a solvate ionic liquid (SIL) setting by comparing sulfonate-based anions with long and short perfluorinated alkyl chains. Representative SILs are created from 1,2-bis(2-methoxyethoxy)ethane (“triglyme” or “G3”), lithium nonafluoro-1-butanesulfonate, and lithium trifluoromethanesulfonate. Molecular dynamics simulations, density functional theory computations, and vibrational spectroscopy provide insight into the overall liquid structure, cation–solven...
Source: Molecules - April 30, 2024 Category: Chemistry Authors: Karina Shimizu Adilson Alves de Freitas Jacob T. Allred Christopher M. Burba Tags: Article Source Type: research
Investigation of the lithium plating triggering criterion in graphite electrodes
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Jiani Li, Lubing Wang, Jun Xu The lithium plating onset time was detected precisely, and models incorporating a concentration criterion and a potential criterion were established to further elucidate the mechanisms governing the onset of lithium plating. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - J. Mater. Chem. latest articles)
Source: RSC - J. Mater. Chem. latest articles - April 29, 2024 Category: Chemistry Authors: Jiani Li Source Type: research
31. The Effect of Family History and Polygenic Risk Scores for Psychiatric Disorders on Lithium Response
Bipolar disorder (BD) is a heritable mental illness with complex genetic architecture. Polygenic risk scores (PRS) can complement family history (FH) in predicting treatment response. We aimed to investigate the association of FH and PRS for psychiatric disorders with lithium response in BD. (Source: Biological Psychiatry)
Source: Biological Psychiatry - April 29, 2024 Category: Psychiatry Authors: Mete Ercis, Brandon J. Coombes, Marin Veldic, Katherine M. Moore, Hannah K. Betcher, Francisco Romo-Nava, Aysegul Ozerdem, David J. Bond, Alfredo Cuellar- Barboza, Miguel Prieto, Susan L. McElroy, Joanna M. Biernacka, Mark A. Frye, Balwinder Singh Source Type: research
Longitudinal Brain Age in Young People With First-Episode Mania Treated With Lithium or Quetiapine
Previous studies suggest that lithium may have a neuroprotective effect on regional brain areas, even in First-Episode Mania (FEM) and early stages of bipolar and schizoaffective disorders. Here, an age-related multivariate measure of brain structure (i.e., brain age) at baseline and changes over time in response to treatment were examined. (Source: Biological Psychiatry)
Source: Biological Psychiatry - April 29, 2024 Category: Psychiatry Authors: Laura Han, Niousha Dehestani, Chao Suo, Michael Berk, Lianne Schmaal Tags: Symposium Source Type: research
245. The Effects of Ebselen on Brain Neurochemistry in Depressed Patients on Antidepressants
Lithium can augment conventional antidepressant medication in treatment-resistant depression, but its use is limited due to significant adverse effects. Previous studies in healthy volunteers reported that the inositol monophosphatase inhibitor, ebselen, reduced brain inositol levels, a proposed mechanism of action for lithium. We aimed to evaluate the effects of ebselen on brain neuroch emistry in a clinically depressed population. (Source: Biological Psychiatry)
Source: Biological Psychiatry - April 29, 2024 Category: Psychiatry Authors: Fitri Fareez Ramli, Nisha Singh, Philip Cowen, Beata Godlewska Source Type: research
214. Uridine for Veterans With Suicidal Ideation: A Mechanistic Clinical and Neuro-Imaging Trial
Suicide remains an urgent concern of the Department of Veterans Affairs (VA). Uridine is a novel treatment with a broad mechanistic overlap with ketamine and lithium, two drugs with anti-suicidal effects. The aims of this double blind randomized controlled clinical trial VA-funded study are to determine if uridine decreases suicidal ideation (SI) in Veterans, and to measure rapid changes in GABA, Glutamate, and Glutamate+Glutamine (Glx) associated with uridine compared to placebo. (Source: Biological Psychiatry)
Source: Biological Psychiatry - April 29, 2024 Category: Psychiatry Authors: Nicolas Nunez, Danielle Boxer, Xian-Feng Shi, Young-Hoon Sung, Colleen Fitzgerald, Yasmin Peralta, Deborah Yurgelun-Todd, Perry Renshaw, Douglas Kondo Source Type: research
129. The Effects of Novel Small Molecules in a Preclinical Model of Positive Affective State
We examined the effects of lithium and two novel small molecule GSK3β inhibitors on amphetamine-induced positive appetitive ultrasonic vocalizations (USVs), a validated model of positive affective state. (Source: Biological Psychiatry)
Source: Biological Psychiatry - April 29, 2024 Category: Psychiatry Authors: Sarina Mohanty, Amanda Roberts, Daniel Levy, Stephen Haggarty, Pablo Lapuerta Source Type: research
115. GrimAge and DunedinPACE in Bipolar Disorder: Exploring Suicide Attempt and Lithium Use
Bipolar disorder (BD) has been associated with premature mortality and accelerated aging. Prior research from our group has shown that suicide attempts (SA) are associated with epigenetic aging (GrimAge) in BD, but less is known about the pace of aging and how medications, particularly lithium, given its neuroprotective effects, may be associated with the aging process. (Source: Biological Psychiatry)
Source: Biological Psychiatry - April 29, 2024 Category: Psychiatry Authors: Emese Kov ács, Jenny Gringer Richards, Aislinn Williams, John Wemmie, Vincent Magnotta, Jess Fiedorowicz, Marie Gaine Source Type: research
Lithium rescues cultured rat metatarsals from dexamethasone-induced growth failure
CONCLUSIONS: LiCl has the potential to partially rescue from dexamethasone-induced bone growth impairment in an ex vivo model. Transcriptomics identified cell renewal and proliferation as candidates for the underlying mechanisms. Our observations may open up the development of a new treatment strategy for bone growth disorders.IMPACT: LiCl is capable to prevent glucocorticoid-induced growth failure in rat metatarsals in vitro. The accompanying drug-induced transcriptomic changes suggested cell renewal and proliferation as candidate underlying mechanisms. Wnt/beta-catenin pathway could be one of those novel mechanisms.PMID:...
Source: Cell Research - April 29, 2024 Category: Cytology Authors: Ondrej Soucek Ondrej Cinek Lilly Velentza Valerij Semjonov Martin Bezdicka Farasat Zaman Lars S ävendahl Source Type: research
Lithium rescues cultured rat metatarsals from dexamethasone-induced growth failure
CONCLUSIONS: LiCl has the potential to partially rescue from dexamethasone-induced bone growth impairment in an ex vivo model. Transcriptomics identified cell renewal and proliferation as candidates for the underlying mechanisms. Our observations may open up the development of a new treatment strategy for bone growth disorders.IMPACT: LiCl is capable to prevent glucocorticoid-induced growth failure in rat metatarsals in vitro. The accompanying drug-induced transcriptomic changes suggested cell renewal and proliferation as candidate underlying mechanisms. Wnt/beta-catenin pathway could be one of those novel mechanisms.PMID:...
Source: Pediatric Research - April 29, 2024 Category: Pediatrics Authors: Ondrej Soucek Ondrej Cinek Lilly Velentza Valerij Semjonov Martin Bezdicka Farasat Zaman Lars S ävendahl Source Type: research
Lithium rescues cultured rat metatarsals from dexamethasone-induced growth failure
CONCLUSIONS: LiCl has the potential to partially rescue from dexamethasone-induced bone growth impairment in an ex vivo model. Transcriptomics identified cell renewal and proliferation as candidates for the underlying mechanisms. Our observations may open up the development of a new treatment strategy for bone growth disorders.IMPACT: LiCl is capable to prevent glucocorticoid-induced growth failure in rat metatarsals in vitro. The accompanying drug-induced transcriptomic changes suggested cell renewal and proliferation as candidate underlying mechanisms. Wnt/beta-catenin pathway could be one of those novel mechanisms.PMID:...
Source: Pediatric Research - April 29, 2024 Category: Pediatrics Authors: Ondrej Soucek Ondrej Cinek Lilly Velentza Valerij Semjonov Martin Bezdicka Farasat Zaman Lars S ävendahl Source Type: research
Broadband frequency comb generation through cascaded quadratic nonlinearity in thin-film lithium niobate microresonators
Broadband frequency comb generation through cascaded quadratic nonlinearity remains experimentally untapped in free-space cavities with ... (Source: Optics Letters)
Source: Optics Letters - April 29, 2024 Category: Physics Authors: Chao Tang Mingming Nie Jia-yang Chen Zhaohui Ma Zhan Li Yijun Xie Yong Meng Sua Shu-Wei Huang Yu-Ping Huang Source Type: research
