Tuning the D ‐Band Center of Bi2S3─MoS2 Heterostructure Towards Superior Lithium‐Sulfur Batteries
A heterostructure consisting of Bi2S3 and MoS2 with abundant interfacial sites tunes the d-band center of Bi2S3 and MoS2, and thus enhances the electrochemical reaction of adsorbed LiPSs and promotes its conversion. AbstractLithium-sulfur (Li –S) batteries are one of the most promising energy storage devices due to their environmental friendliness, low cost, and high specific capacity. However, the slow electrochemical kinetics and the “shuttle effect” have seriously hindered their commercialization. Herein, the nanoflower Bi2S3─MoS2 (BMS) heterostructure is synthesized by a two-step hydrothermal method, and then t...
Source: Small - May 30, 2024 Category: Nanotechnology Authors: Yanan Li, Tengyu Li, Yirui Deng, Wenhao Tang, Hao Wu, Ming Feng, Peng Yan, Ruiping Liu Tags: Research Article Source Type: research

Recycling Spent Lithium-Ion Batteries Cathode: An Overview
Green Chem., 2024, Accepted Manuscript DOI: 10.1039/D4GC01781A, Tutorial ReviewXun Zhang, Maiyong Zhu The past decades have witnessed the rapid development of lithium-ion batteries (LIBs), whose applications nearly cover every aspect of our life. The increasing number of the spent LIBs (S-LIBs) endows... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Green Chem. latest articles)
Source: RSC - Green Chem. latest articles - May 30, 2024 Category: Chemistry Authors: Xun Zhang Source Type: research

High concentration in situ polymer gel electrolyte for high performance lithium metal batteries
Chem. Commun., 2024, Advance Article DOI: 10.1039/D4CC01784F, CommunicationZehui Zhang, Zhangbin Cheng, Feilong Qiu, Yuchen Jiang, Min Jia, Xiaohong Yan, Xiaoyu Zhang The GPEin situ polymerized electrolyte prepared enables stable cycling of a Li ‖Li battery for over 3200 h. This GPE shows promise for a high-capacity lithium-metal battery by combining high concentration electrolytes within situ polymerization. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Chem. Commun. latest articles)
Source: RSC - Chem. Commun. latest articles - May 30, 2024 Category: Chemistry Authors: Zehui Zhang Source Type: research

Molecules, Vol. 29, Pages 2578: SiOx/C Composite Anode for Lithium-Ion Battery with Improved Performance Using Graphene Quantum Dots and Carbon Nanoparticles
In this study, a composite was manufactured by mixing graphene quantum dots, silicon oxide, and carbon nanoparticles, and the characteristics of the anode materials for secondary batteries were examined. To improve the capacity of the graphene quantum dot (GQD) anode material, the added silicon oxide content was varied among 0, 5, 10, 15, and 30 wt%, and carbon nanoparticles were added as a structural stabilizer to alleviate silicon oxide volume expansion. The physical properties of the prepared GQD/SiOx/C composite were investigated through XRD, SEM, EDS, and powder resistance analysis. Additionally, the electrochemical p...
Source: Molecules - May 30, 2024 Category: Chemistry Authors: Sung Won Hwang Tags: Article Source Type: research

High concentration < em > in situ < /em > polymer gel electrolyte for high performance lithium metal batteries
Chem Commun (Camb). 2024 May 29. doi: 10.1039/d4cc01784f. Online ahead of print.ABSTRACTA high concentration gel polymer electrolyte (GPE) was prepared by simply using LiFSI-LiNO3 dissolved in 1,3-dioxolane. The Li‖Li cell achieves stable battery cycling for over 3200 h. Furthermore, the Li‖Cu cell demonstrates a high CE of 99.2%. Even at a high current density of 8 mA cm-2, a high CE of 98.5% was still achieved. Notably, in a Li‖LiFePO4 cell, this electrolyte enables high capacity retention of 94.5% and an average CE of 99.8% over 500 cycles, showing promising prospects for high-performance lithium metal batteries.P...
Source: Chemical Communications - May 29, 2024 Category: Chemistry Authors: Zehui Zhang Zhangbin Cheng Feilong Qiu Yuchen Jiang Min Jia Xiaohong Yan Xiaoyu Zhang Source Type: research

A new clustering model based on the seminal plasma/serum ratios of multiple trace element concentrations in male patients with subfertility
CONCLUSIONS: Classification of patients based on SP/serum ratios of multiple TEs represents the dominance of fractions of ejaculation samples.PMID:38807752 | PMC:PMC11131575 | DOI:10.1002/rmb2.12584 (Source: Reproductive Biology)
Source: Reproductive Biology - May 29, 2024 Category: Reproduction Medicine Authors: Takazo Tanaka Kosuke Kojo Yoshiyuki Nagumo Atsushi Ikeda Takuya Shimizu Shunsuke Fujimoto Toshiyuki Kakinuma Masahiro Uchida Tomokazu Kimura Shuya Kandori Hiromitsu Negoro Hiroyuki Nishiyama Source Type: research

High concentration < em > in situ < /em > polymer gel electrolyte for high performance lithium metal batteries
Chem Commun (Camb). 2024 May 29. doi: 10.1039/d4cc01784f. Online ahead of print.ABSTRACTA high concentration gel polymer electrolyte (GPE) was prepared by simply using LiFSI-LiNO3 dissolved in 1,3-dioxolane. The Li‖Li cell achieves stable battery cycling for over 3200 h. Furthermore, the Li‖Cu cell demonstrates a high CE of 99.2%. Even at a high current density of 8 mA cm-2, a high CE of 98.5% was still achieved. Notably, in a Li‖LiFePO4 cell, this electrolyte enables high capacity retention of 94.5% and an average CE of 99.8% over 500 cycles, showing promising prospects for high-performance lithium metal batteries.P...
Source: Chemical Communications - May 29, 2024 Category: Chemistry Authors: Zehui Zhang Zhangbin Cheng Feilong Qiu Yuchen Jiang Min Jia Xiaohong Yan Xiaoyu Zhang Source Type: research

A new clustering model based on the seminal plasma/serum ratios of multiple trace element concentrations in male patients with subfertility
CONCLUSIONS: Classification of patients based on SP/serum ratios of multiple TEs represents the dominance of fractions of ejaculation samples.PMID:38807752 | PMC:PMC11131575 | DOI:10.1002/rmb2.12584 (Source: Reproductive Biology)
Source: Reproductive Biology - May 29, 2024 Category: Reproduction Medicine Authors: Takazo Tanaka Kosuke Kojo Yoshiyuki Nagumo Atsushi Ikeda Takuya Shimizu Shunsuke Fujimoto Toshiyuki Kakinuma Masahiro Uchida Tomokazu Kimura Shuya Kandori Hiromitsu Negoro Hiroyuki Nishiyama Source Type: research

Waveguide-integrated van der Waals heterostructure photodetector on a lithium niobate on insulator platform
Lithium niobate (LN) photonics has gained significant interest for their distinct material properties. However, achieving monolithically ... (Source: Optics Letters)
Source: Optics Letters - May 29, 2024 Category: Physics Authors: Ke Xia Huayou Liu Yang Qiu Shaonan Zheng Yaping Dan Qize Zhong Yuan Dong Xingyan Zhao Ting Hu Source Type: research

A Slightly Expanded Graphite Anode with High Capacity Enabled By Stable Lithium ‐Ion/Metal Hybrid Storage
A graphite anode with a slightly expanded structure achieves a well-balance of stable lithium-ion/metal storage in commercial carbonate electrolytes. With a controlled capacity of 558  mAh g-1 for the anode, the full cell coupled with a high-loading LiNi0.8Co0.1Mn0.1O2 cathode under a low N/P ratio (≈1.15) shows good cycling stability. AbstractIntegrating lithium-ion and metal storage mechanisms to improve the capacity of graphite anode holds the potential to boost the energy density of lithium-ion batteries. However, this approach, typically plating lithium metal onto traditional graphite anodes, faces challenges of ...
Source: Small - May 28, 2024 Category: Nanotechnology Authors: Tong Li, Yun Cao, Qiuchen Song, Linkai Peng, Xianying Qin, Wei Lv, Feiyu Kang Tags: Research Article Source Type: research

Tailoring the interface of lithium metal batteries with an in situ formed gel polymer electrolyte
J. Mater. Chem. A, 2024, Advance Article DOI: 10.1039/D4TA01629G, PaperSixin Jia, Jinxin Xue, Hong Huo, Jianjun Zhou, Lin Li In situ formed gel polymer electrolyte with wide electrochemial stability window is obtained with an amide group covalently cross-linked polymer matrix. It can stabilize lithium metal anode and inhibit liquid electrolyte decomposition on the cathode. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - J. Mater. Chem. latest articles)
Source: RSC - J. Mater. Chem. latest articles - May 28, 2024 Category: Chemistry Authors: Sixin Jia Source Type: research

Exploring the unexpected electrochemical dynamics of lithium vanadyl phosphate electrodes in zinc battery systems
J. Mater. Chem. A, 2024, Advance Article DOI: 10.1039/D3TA07860D, PaperDimas Yunianto Putro, Kiki Rezki Lestari, Muhammad Hilmy Alfaruqi, M. Ghalib Alfaza, Zulkifli, Moonsu Song, Seunggyeong Lee, Balaji Sambandam, Vinod Mathew, Jaekook Kim Our study explores the potential of β-LiVOPO4 as a high-energy and stable cathode material for zinc-ion batteries, achieving a high working voltage through comprehensive characterization techniques. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - J. Mater. Chem. latest articles)
Source: RSC - J. Mater. Chem. latest articles - May 28, 2024 Category: Chemistry Authors: Dimas Yunianto Putro Source Type: research

A redox-active porous polymer based on poly(imide-triazine) as a high-performance cathode for lithium-ion batteries
J. Mater. Chem. A, 2024, Advance Article DOI: 10.1039/D4TA00221K, PaperRefka El Oueslati, Badr Jismy, Benjamin Flamme, Nicolas Leclerc, Fouad Ghamouss, Mohamed Abarbri A dual redox-active porous polymer cathode provides very high discharge capacity (422 mA h g−1 at 0.5 A g−1), excellent rate capability (268 mA h g−1 at 10 A g−1) and long-term cycling stability (80% retention after 500 cycles and 65% retention after 4000 cycles). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - J. Mater. Chem. latest articles)
Source: RSC - J. Mater. Chem. latest articles - May 28, 2024 Category: Chemistry Authors: Refka El Oueslati Source Type: research

In Situ Characterizations of the Dynamics of Cathode Electrolyte Interfaces at Different Current Densities
The dynamic change of CEIs under different current densities are characterized by using in situ FTIR. The degradation of battery performance at high current densities may be attributed to the intrinsic component instability of CEIs. AbstractLiNi0.8Mn0.1Co0.1O2 with high nickel content plays a critical role in enabling lithium metal batteries (LMBs) to achieve high specific energy density, making them a prominent choice for electric vehicles (EVs). However, ensuring the long-term cycling stability of the cathode electrolyte interfaces (CEIs), particularly at fast-charge conditions, remains an unsolved challenge. The decay m...
Source: Small - May 28, 2024 Category: Nanotechnology Authors: Huanzhu Lv, Lei Zhou, Qisheng Fang, Jianli Cheng, Jun Mei, Yuanhua Xia, Bin Wang Tags: Research Article Source Type: research

Localized High ‐Concentration Sulfone Electrolytes with High‐Voltage Stability and Flame Retardancy for Ni‐Rich Lithium Metal Batteries
A localized high-concentration electrolyte system is designed with sulfolane as the solvent and applied to 4.5  V-class Ni-rich lithium metal batteries. The diluent is involved in the process of forming the interfaces of both electrodes, which shows good prospects for application. AbstractThe localized high-concentration electrolyte (LHCE) propels the advanced high-voltage battery system. Sulfone-based LHCE is a transformative direction compatible with high energy density and high safety. In this work, the application of lithium bis(trifluoromethanesulphonyl)imide and lithium bis(fluorosulfonyl)imide (LiFSI) in the LHCE s...
Source: Small - May 28, 2024 Category: Nanotechnology Authors: Bo ‐Han Zhang, Pei‐Pei Chen, Yun‐Lei Hou, Jing‐Zhou Chen, Hua‐Ying Wang, Wan‐Xin Wen, Zi‐Ang Li, Jia‐Ting Lei, Dong‐Lin Zhao Tags: Research Article Source Type: research