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Introducing I-/Formic Acid as a Green Reagent for the Reduction of Sulfinates and Sulfoxides
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Jes ús Armando Luján Montelongo, Luis Javier García de la Cuesta, Alicia Elvira Cruz-Jiménez, Perla Esmeralda Hernández, Alberto Vela We present a convenient and efficient deoxygention method for the syntheses of disulfides and thioethers. The reaction involves an iodide-catalyzed reduction of methyl sulfinates or sulfoxides, respectively, employing formic acid... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Green Chem. latest articles - September 23, 2023 Category: Chemistry Authors: Jes ús Armando Luján Montelongo Source Type: research

Structural diversity of copper(I) ethylene complexes with 2,4-bis(2-pyridyl)pyrimidine directed by anions
Dalton Trans., 2023, Accepted Manuscript DOI: 10.1039/D3DT02618C, PaperMasahiko Maekawa, Terumasa Hayashi, Kunihisa Sugimoto, Takashi Okubo, T. Kuroda-Sowa Novel four di-, tetranuclear and polymeric Cu(I) –bpprd/C2H4 complexes were anion-dependently prepared by the reactions of [Cu(C2H4)n]X (X = ClO4–, NO3–, BF4–) with 2,4-bis(2-pyridyl)pyrimidine (bpprd) in Me2CO under C2H4 and they... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Dalton Trans. latest articles - September 23, 2023 Category: Chemistry Authors: Masahiko Maekawa Source Type: research

Mononuclear copper(I) complexes bearing 3-phenyl-5-(pyridin-4-yl)-1, 2, 4-triazole ligand: synthesis, crystal structure, TADF-luminescence, and mechanochromic effects
Dalton Trans., 2023, Accepted Manuscript DOI: 10.1039/D3DT02633G, PaperAlexey N. Gusev, Elena Braga, Ekaterina Zamnius, Mikhail A. Kiskin, Amjad Ali, Glib Baryshnikov, Wolfgang Linert Three new mononuclear heteroleptic copper(I) halide complexes, [CuL(PPh3)2X] (X = Cl, Br, I), based on 3-phenyl-5-(pyridin-4-yl)-1,2,4-triazole (L) and triphenylphosphine (PPh3) ligands, have been prepared by reaction of CuX (X =... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Dalton Trans. latest articles - September 23, 2023 Category: Chemistry Authors: Alexey N. Gusev Source Type: research

Co-substitution Design: A New Glaserite-type Rare-earth Phosphate K2RbSc(PO4)2 with High Structural Tolerance
Dalton Trans., 2023, Accepted Manuscript DOI: 10.1039/D3DT02494F, PaperJingfang Zhou, Pifu Gong, Mingjun Xia, Qian Wu An alkali rare-earth phosphate K2RbSc(PO4)2 was successfully obtained by the derivative of glaserite-type K3Na(SO4)2 by co-substitution of K(1)O12 →RbO12, K(2)O10→KO7, NaO6→ScO6 and SO4→PO4, meanwhile maintaining the original anionic framework. K2RbSc(PO4)2 exhibits... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Dalton Trans. latest articles - September 23, 2023 Category: Chemistry Authors: Jingfang Zhou Source Type: research

C –H hydrogen bond and halogen bond directed self-assembly of ethereal podands and C–X⋯F−/HF2− halogen bonding in solution
CrystEngComm, 2023, Advance Article DOI: 10.1039/D3CE00599B, PaperDipjyoti Dutta, Anamika Gogoi, Rupjyoti Dutta, Sarvesh S. Harmalkar, Prem Lama, Sandeep Kumar Dey Crystallization of halophenyl-functionalized ethereal podands is largely facilitated by C –H hydrogen bonds and halogen bonds of similar strength, and anion binding in the solution state is exclusively governed by halogen bonding. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - CrystEngComm latest articles - September 23, 2023 Category: Chemistry Authors: Dipjyoti Dutta Source Type: research

Chiral Probes for Biosensing
Chem. Commun., 2023, Accepted Manuscript DOI: 10.1039/D3CC03660J, Feature ArticleChuanlai Xu, Changlong Hao, Hua Kuang Chiral inorganic nanomaterials have emerged as a highly promising area of research in nanoscience due to their exceptional light-matter interaction and vast potential applications in chiral sensing, asymmetric catalysis, enantiomer... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - September 23, 2023 Category: Chemistry Authors: Chuanlai Xu Source Type: research

Background free in vivo29Si MR imaging with hyperpolarized PEGylated silicon nanoparticles
This study demonstrated the potential of 50 nm PEGylated Si NPs for high-resolutionin vivo29Si MR imaging, emphasizing their biocompatibility and water dispersibility. The acquisition of in vivo Si... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Analyst latest articles - September 23, 2023 Category: Chemistry Authors: Seung-Hyun Yang Source Type: research

Light-up split aptamers: binding thermodynamics and kinetics for sensing
Analyst, 2023, Accepted Manuscript DOI: 10.1039/D3AN01368E, PaperYichen Zhao, Nikesh Patel, Peihuan Sun, Karen Faulds, Duncan Graham, Juewen Liu Due to their programmable structures, many aptamers can be readily split into two halves while still retaining their target binding function. While split aptamers are prevalent in the biosensor field,... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Analyst latest articles - September 23, 2023 Category: Chemistry Authors: Yichen Zhao Source Type: research

Professional identity formation among undergraduate pre-medical students: a scoping review protocol
The objective of this scoping review is to systematically map the literature on professional identity formation among undergraduate pre-medical students.MethodsThis review protocol has been designed following the Arksey and O ’Malley framework. We will search MEDLINE, CINAHL, Embase, and Scopus, as well as relevant grey literature, conference proceedings, and citations of selected articles. Inclusion criteria are articles (1) written in the English language, (2) involving undergraduate pre-medical students in the USA a nd Canada, and (3) containing original data about professional identity formation. Two independent revi...
Source: Systematic Reviews - September 23, 2023 Category: International Medicine & Public Health Source Type: research

IJERPH, Vol. 20, Pages 6810: School Memories about Homophobic Bullying: A Study Based on Cultural-Historical Psychology
This study is based on cultural-historical psychology in intersection with gender and sexuality studies. In-depth online interviews were conducted with three young subjects who identified themselves as non-heterosexual. The interviews were recorded, transcribed, and analyzed through the analytical discourse tool defined as Nuclei of Meanings. The results were organized in two topics of discussion: (a) the problems associated with non-heterosexual identity in schools; (b) the search for other ways of experiencing sexual identity in school. Throughout the article, reflections were held about the challenges participants had t...
Source: International Journal of Environmental Research and Public Health - September 23, 2023 Category: Environmental Health Authors: R ômulo Lopes da Silva Vera Lucia Trevisan de Souza Tags: Article Source Type: research

Functional Characterization of Two Efficient Glycosyltransferases Catalysing the Formation of Rutin from Sophora japonica L.
Org. Biomol. Chem., 2023, Accepted Manuscript DOI: 10.1039/D3OB01281F, CommunicationJianlin Zou, Hongye Li, Zilong Wang, Min Ye Two efficient and selective glycosyltransferases were identified from Sophora japonica L. Sj3GT could regio-selectively catalyse 3-O-glucosylation of quercetin to produce isoquercitrin, and Sj6''RhaT could further catalyse its 6''-O-rhamnosylation to generate... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Organic and Biomolecular Chemistry - September 22, 2023 Category: Molecular Biology Authors: Jianlin Zou Source Type: research

Multicomponent cyclization with azides to synthesize N-heterocycles
Org. Biomol. Chem., 2023, Accepted Manuscript DOI: 10.1039/D3OB01115A, Review ArticleHong Guo, Bei Zhou, Jingjing Chang, Wenxu Chang, Jiyao Feng, Zhenhua Zhang Heterocyclic compounds, both naturally derived and synthetically produced, constitute a wide variety of biologically active and industrially important compounds. The synthesis and application of heterocyclic compounds have garnered significant attention... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Organic and Biomolecular Chemistry - September 22, 2023 Category: Molecular Biology Authors: Hong Guo Source Type: research

Pd@GO catalyzed stereo- and regio-selective addition of arenes to alkynes and synthesis of coumarins via C-H functionalization
Org. Biomol. Chem., 2023, Accepted Manuscript DOI: 10.1039/D3OB01237A, PaperLenida Kyndiah, Fillip Kumar Sarkar, Sushmita Gajurel, Rajib Sarkar, Jasha Momo H. Anal, Amarta Kumar Pal A stereo- and regio-selective addition of arenes to alkynes via C-H bond functionalization has been developed using palladium nanoparticles supported on graphite oxide (Pd@GO) as the reusable catalyst. The prepared... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Organic and Biomolecular Chemistry - September 22, 2023 Category: Molecular Biology Authors: Lenida Kyndiah Source Type: research

Improve emission performance of benzoaphenoxazine in aqueous solution through Host-Guest interaction
Org. Biomol. Chem., 2023, Accepted Manuscript DOI: 10.1039/D3OB01427D, CommunicationShu-Yi Li, Wenli Wang, Chang Wang, Ru Sun, Jian-Feng Ge To evaluate the contribution of Host-Guest chemistry in fluorescent enhancement under aqueous condition, two benzo[a]phenoxazine derivatives with adamantyl group were prepared. After they formed stable complexes with methyl- β-cyclodextrin, their emissions... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Organic and Biomolecular Chemistry - September 22, 2023 Category: Molecular Biology Authors: Shu-Yi Li Source Type: research

Non-Close-Packed Hexagonal Self-Assembly of Janus Nanoparticles on Planar Membranes
Soft Matter, 2023, Accepted Manuscript DOI: 10.1039/D3SM00984J, PaperYu Zhu, Abash Sharma, Eric J Spangler, Mohamed Laradji The adhesion modes of an ensemble of spherical Janus nanoparticles on planar membranes is investigated through large scale molecular dynamics simulations of a coarse-grained implicit-solvent model. We found that the... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Soft Matter latest articles - September 22, 2023 Category: Chemistry Authors: Yu Zhu Source Type: research