Highly efficient CuCr-MMO catalyst for a base-free styrene epoxidation with H2O2 as the oxidant: synergistic effect between Cu and Cr
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT02357G, PaperQian Wang, Xiao Liang, Ruxia Bi, Yanan Liu, Yufei He, Junting Feng, Dianqing Li The synergistic effect of the bimetals and the suitable acid –basic property of CuCr-MMO contributed to the good catalytic performance of the styrene epoxidation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 23, 2019 Category: Chemistry Authors: Qian Wang Source Type: research

Creation and stabilisation of tuneable open metal sites in thiocyanato-bridged heterometallic coordination polymers to be used as heterogeneous catalysts
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03679B, PaperHiroyasu Tabe, Masaaki Matsushima, Rika Tanaka, Yusuke Yamada A series of thiocyanato-bridged heterometallic coordination polymers with 3D reticular network have been synthesised by the reaction of [PtIV(SCN)6]2 – with MII ions to form {MII[PtIV(SCN)6]}n and {[MII(CH3OH)2][PtIV(SCN)6]}n (MII = MnII,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 23, 2019 Category: Chemistry Authors: Hiroyasu Tabe Source Type: research

Regioselective conversions of H4pdta (1,2-propanediaminetetraacetic acid) and H4eed3a to their triacetates on peroxotitanates
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03589C, PaperYu-chen Yang, Qiong-Xin Liu, Zhao-Hui Zhou, Huilin Wan 1,2-Propanediaminetetraacetic acid (H4pdta = C11H18O8N2) is degraded selectively to 1-methyl-1,2-propanediaminetriacetic acid (H3pd3a = C9H16O6N2) with a yield of 75% at room temperature, while N-(2-hydroxyethyl) ethylenediaminetriacetic acid (H4eed3a = C10H18O7N2) is... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 23, 2019 Category: Chemistry Authors: Yu-chen Yang Source Type: research

Reactions of BICAAC with hydroboranes: propensity for Lewis adduct formation and carbene insertion into B-H bond
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03382C, PaperKrishna Kumar Manar, vishal kumar porwal, Rohit S. Kamte, Manu Adhikari, Sandeep Kumar Thakur, Deependra Bawari, Angshuman Roychoudhury, Sanjay Singh The reactivity of bicyclic (alkyl)(amino)carbene (BICAAC) towards different boranes has been examined in the present work. The reactions with boranes BX3 ‧SMe2 (X = H, Cl, Br), BF3∙OEt2 and BCl3 yield... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 23, 2019 Category: Chemistry Authors: Krishna Kumar Manar Source Type: research

Influence of the pyrazine substituent on the structure and magnetic properties of dicyanamide-bridged cobalt(II) complexes
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT02976A, PaperJoanna Palion-Gazda, Katarzyna Choroba, Barbara Machura, Anna Świtlicka, Rafał Kruszyński, Joan Cano, Francesc Lloret, Miguel Julve Substituted pyrazines were successfully used to prepare two new coordination polymers of formula {[Co(dca)2(NH2pyz)2].H2O}n (1) and [Co3(dca)6(HOpyz)5(H2O)2]n(2) [dca = dicyanamide, NH2pyz = 2-aminopyrazine and HOpyz = 2-hydroxypyrazine] whose structures... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 23, 2019 Category: Chemistry Authors: Joanna Palion-Gazda Source Type: research

LiMnPO4-Olivine Deposited on Nanoporous Alloy as Additive-Free Electrodes for Lithium Ion Batteries
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT02879J, PaperLyuben Mihaylov, Tanya Boyadzhieva, Rumen I Tomov, Ramachandran Vasant Kumar, Violeta Koleva, Radostina Stoyanova, Tony Spassov A new strategy for fabrication of binder- and carbon-free electrodes for Lithium ion batteries is demonstrated. The strategy is based on the employment of a nanoporous metallic structure as mechanically... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 23, 2019 Category: Chemistry Authors: Lyuben Mihaylov Source Type: research

Complete post-synthetic modification of a Spin Crossover complex
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03587G, CommunicationAlejandro Enriquez-Cabrera, Lucie Routaboul, Lionel Salmon, Azzedine Bousseksou The post-synthetic reaction between p-anisaldehyde and the spin-crossover compound [Fe(NH2-trz)3](NO3)2 was explored, obtaining different degrees of transformation from 23% to a full conversion varying the reaction time. The post-synthetic SCO... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 23, 2019 Category: Chemistry Authors: Alejandro Enriquez-Cabrera Source Type: research

Designed Asymmetric Coordination Helicates with bis- β-diketonate Ligands
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03398J, CommunicationGuillem Aromi, Mohanad Darawsheh, Rosa Diego, Leon í Alejandra Barrios, Anna Sadurní, Jordi Garcia Gomez, Paul Lloyd, Simon Teat, Olivier Roubeau, David Aguilà A new bis-( β-diketone) ligand featuring built-up structural asymmetry yields the non-symmetric Fe(III) and Ga(III) dinuclear, triple-stranded helicates by design. Their structural properties have been studied, both in solid state and... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 23, 2019 Category: Chemistry Authors: Guillem Aromi Source Type: research

B-SBA-16 encaged functional tungstosilicic acid type ionic liquid to catalyze ketal reaction
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03077H, PaperYingjie Xie, Qian Zhao, Guo-Fang Gao, Tingshun Jiang There is special significance of composite catalysts using SBA-16 nano-cages as carrier in acid catalysis field. A method of embedding boron atoms onto SBA-16 to increase acid sites and enhance... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 23, 2019 Category: Chemistry Authors: Yingjie Xie Source Type: research

Smart Nanoprobe Based on Gadolinium Complex Encapsulated by ZIF-8 with Enhanced Room Temperature Phosphorescence for Synchronous Oxygen Sensing and Photodynamic Therapy
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03955D, PaperZhongli Zhao, Jiaxi Ru, Panpan Zhou, Yunsheng Wang, Chang-Fu Shan, Xiaoxi Yang, Jing Cao, Wei-Sheng Liu, Huichen Guo, Yu Tang Phosphorescence lifetime approach based on the room temperature phosphorescence (RTP) property has achieved many attentions in recent years due to its excellent performance in precise measurement of oxygen. Herein, a... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 23, 2019 Category: Chemistry Authors: Zhongli Zhao Source Type: research

PbMnTeO6: a chiral quasi 2D magnet with all cations in octahedral coordination and the space group problem of trigonal layered A2+M4+TeO6
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03154E, PaperMaria D. Kuchugura, Alexander Kurbakov, Elena A. Zvereva, Tatyana M. Vasilchikova, Grigoriy V. Raganyan, Alexander Vasiliev, Victor A. Barchuk, Vladimir B. Nalbandyan Antiferromagnetic PbMnTeO6, also known as mineral kuranakhite, was reported recently to have all three cations in trigonal prismatic coordination, extremely unusual for both Mn(4+) and Te(6+). In the present work,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 23, 2019 Category: Chemistry Authors: Maria D. Kuchugura Source Type: research

Thermal- and light-induced switchable one-dimensional rare looped-like spin crossover coordination polymer
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03285A, PaperWenlong Lan, Francisco Javier Valverde-Mu ñoz, Yong Dou, Xiaoyun Hao, Carmen Muñoz, Zhen Zhou, Hui Liu, Qingyun Liu, José Antonio A Real Cabezos, Daopeng Zhang The rare looped-like isostructural one-dimensional coordination polymer (1D-CP) system formulated as {Fe(DPIP)2(NCSe)2]}n •4DMF (1) and {Fe(DPIP)2(NCSe)2]}n•4DMF (2) has been obtained by self-assembling FeII and pseudhalide NCX-(X = S, Se) ionsin presence... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 23, 2019 Category: Chemistry Authors: Wenlong Lan Source Type: research

Manganese oxides with hierarchical structures derived from coordination polymers and their enhanced catalytic activity at low temperature for selective catalytic reduction of NOx
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT03043C, PaperByeonggab Ji, Junhyung Lee, Seung-Yeop Kwak Hierarchical manganese oxides for enhancing catalytic performance have been successfully synthesizedvia simple thermal annealing manganese coordination polymer, which is a facile, cost-effective, and environmentally benign preparation method. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 22, 2019 Category: Chemistry Authors: Byeonggab Ji Source Type: research

Structural Characterization of Potassium Salts of the Decamethylmanganocene Anion Cp*2Mn-
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03551F, PaperMoritz Malischewski, Konrad Seppelt For the first time a crystal structure of a permethylated metallocene anion has been obtained. The 17 valence electron complex decamethylmanganocene Cp*2Mn is reduced by molten potassium in THF to... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 22, 2019 Category: Chemistry Authors: Moritz Malischewski Source Type: research

Facile synthesis of Fe-P-amionphenol nanoparticles for photothermal therapy
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03664D, CommunicationYing Liu, Sainan Liu, Chunling Hu, Yanwei Li, Maolin Pang Fe-P-amionphenol (Fe-PAP) nanoparticle as a newly developed photothermal agent (PTA) was successfully synthesized via a one-pot method at room temperature. The resultant product exhibited good photothermal effect with a photothermal... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 22, 2019 Category: Chemistry Authors: Ying Liu Source Type: research

An iron-doped cobalt phosphide nano-electrocatalyst derived from a metal –organic framework for efficient water splitting
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT03619A, PaperCan Lin, Pengyan Wang, Huihui Jin, Jiahuan Zhao, Ding Chen, Suli Liu, Chengtian Zhang, Shichun Mu Fe0.27Co0.73P NPs exhibit excellent oxygen evolution reaction activity, which is even higher than that exhibited by the commercial IrO2 and the most recently reported transition metal-based electrocatalysts. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 22, 2019 Category: Chemistry Authors: Can Lin Source Type: research

Excellent Supercapacitor and Sensor Performance of Robust Cobalt Phosphinate Ferrocenyl Organic Framework Materials Achieved by Intrinsic Redox and Structure Properties
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03592C, PaperMikhail Khrizanforov, Ruslan Petrovich Shekurov, Miluykov Vasili, Leysan Gilmanova, Olga Kataeva, Zilya Yamaleeva, Tatiana Gerasimova, Vadim Ermolaev, Aidar Timergalievich Gubaidullin, Artem Laskin, Yulia H Budnikova A new redox active coordination polymer [Co(H2O)2(Fc(PHOO)2) ·2H2O]n (Fc = ferrocene) has been synthesized by a diffusion method and characterized by single-crystal X-ray diffraction. Phosphinate fragments form infinite chains connected through... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton T...
Source: RSC - Dalton Trans. latest articles - October 22, 2019 Category: Chemistry Authors: Mikhail Khrizanforov Source Type: research

Reactions of In –Zn Bonds with Organic Azides: Products that Result from Hetero- and Homo-bimetallic Behaviour
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03990B, PaperMathew David Anker, Yasir Altaf, Matthias Lein, Martyn P Coles The indyl anion, K[In(NONDipp)] (NONDipp = [O(SiMe2NDipp)2]2 –, Dipp = 2,6-iPr2C6H3) reacts with group 12 compounds M(BDIR)Cl (M = Zn, Cd; BDI = [HC{C(Me)NR}2]–, R = 2,4,6-Me3C6H2 (Mes), Dipp) to afford... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 21, 2019 Category: Chemistry Authors: Mathew David Anker Source Type: research

Solid state transformation of TMA-magadiite into zeolite omega and the highly insights of the crystallization process
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT02945A, PaperTianming Lv, Yu Wang, Shoulei Zhang, Zhe Feng, Jiqi Zheng, Jing Yang, Xin Liu, Xiaoyu Liu, Changgong Meng Here, we have studied the crystallization of zeolite omega by solid state transformation of TMA-magadiite at 100 oC for 12 h. The samples prepared at different time are measured by... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 21, 2019 Category: Chemistry Authors: Tianming Lv Source Type: research

Formation of Uniform Porous Yolk-Shelled MnCo2O4 Microrugbys with Enhanced Electrochemical Performance for Lithium Storage and Oxygen Evolution Reaction
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03609A, PaperJia Li, Yongxing Zhang, Li Li, Yanming Wang, Lei Zhang, Baojie Zhang, Fei Wang, Bing Li, Xinyao Yu Abstract: Mixed transition metal oxides with favorable electrochemical properties are promising electrode materials in energy storage and conversion systems. In this work, uniform porous yolk-shelled MnCo2O4 microrugbys (denoted as YSM-MCO)... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 19, 2019 Category: Chemistry Authors: Jia Li Source Type: research

A Functionalized UiO-66 MOF for Turn-On Fluorescent Sensing of Superoxide in Water and Efficient Catalysis of Knoevenagel Condensation
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03638E, PaperAniruddha Das, Anbu Nagaraj, Mostakim SK, Amarajothi Dhakshinamoorthy, Shyam Biswas In the present work, a new MOF material from UiO-family called Zr-UiO-66-NH-CH2-Py (1) has been obtained by solvothermal technique and successfully characterized. The MOF structure is contains 2-((pyridin-4-ylmethyl) amino) terephthalic... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 19, 2019 Category: Chemistry Authors: Aniruddha Das Source Type: research

Mechanistic insights on the non-innocent role of electron donors: reversible photocapture of CO2 by RuII-polypyridyl complexes
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Nicolas Queyriaux, Wesley B. Swords, Hemlata Agarwala, Ben A. Johnson, Sascha Ott, Leif Hammarstrom The ability of [RuII(tButpy)(dmbpy)(MeCN)]2+ (1-MeCN) to capture CO2, with the assistance of triethanolamine (TEOA), has been assessed under photocatalytically-relevant conditions. The photolability of1-MeCN has proven essential to generate a... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 19, 2019 Category: Chemistry Authors: Nicolas Queyriaux Source Type: research

Four new dual-functional electro-catalysts formed from small molybdenum clusters and Cu-pyridyl complexes
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT03560E, PaperWanli Zhou, Ping Liu, Yanping Zheng, Xuekun Liu, Yong Zhang, Gang Yuan, Jun Peng Four new isopolymolybdates-based organic –inorganic hybrids decorated with Cu-pyridyl complexes were prepared by using one-pot methods. Compounds1 –4 display discrepant dual-functional electro-catalytic activities toward reduction of nitrite and oxidation of ascorbic acid. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 18, 2019 Category: Chemistry Authors: Wanli Zhou Source Type: research

A (2-(Naphthalen-2-yl)phenyl)rhodium(I) Complex formed by a Proposed Intramolecular 1,4-Ortho-to-Ortho ’ Rh Metal-atom Migration and its Efficacy as an Initiator in the Controlled Stereospecific Polymerisation of Phenylacetylene
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT02953B, PaperNicholas Sheng Long Tan, Gareth Nealon, Jason Martin Lynam, Alexandre N. Sobolev, Matthew Ryan Rowles, Mark Ian Ogden, Massimiliano Massi, Andrew B Lowe The synthesis of a novel Rh(I)-aryl complex is detailed and its ability to serve as an initiator in the stereospecific polymerisation of phenylacetylene evaluated. Targeting the Rh(I) species, (2-phenylnaphthalen-1-yl)rhodium(I)(2,5-norbornadiene)tris(para-fluorophenylphosphine), Rh(nbd)(P(4-FC6H4)3)(2-PhNapth),... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 18, 2019 Category: Chemistry Authors: Nicholas Sheng Long Tan Source Type: research

In Search of Tris(Trimethylsilylcyclopentadienyl) Thorium
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03674A, PaperJustin C. Wedal, Samuel Bekoe, Joseph W Ziller, Filipp Furche, William J Evans Reduction of Cp ′3ThCl, Cp ′3ThBr, and Cp ′3ThI (Cp ′ = C5H4SiMe3) with potassium graphite generates dark blue solutions with reactivity and spectroscopic properties consistent with the formation of Cp ′3Th. The EPR and... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 18, 2019 Category: Chemistry Authors: Justin C. Wedal Source Type: research

Complementary bonding analysis of the N –Si interaction in pentacoordinated silicon compounds using quantum crystallography
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT02772F, PaperMalte Fugel, Maksym V. Ponomarenko, Maxie F. Hesse, Lorraine A. Malaspina, Florian Kleemiss, Kunihisa Sugimoto, Alessandro Genoni, Gerd-Volker R öschenthaler, Simon Grabowsky The unique combination of quantum crystallography and complementary bonding analysis is used to investigate the bonding of pentacoordinated silicon atoms. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 17, 2019 Category: Chemistry Authors: Malte Fugel Source Type: research

Theoretical study of aromatic hydroxylation of the [Cu2(H-XYL)O2]2+ complex mediated by a side-on peroxo dicopper core and Cu-ligand effects
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT02814E, PaperYan Fang Liu, Junliang Shen, Shi-Lu Chen, Weiye Qiao, Suqin Zhou, Kun Hong The newly designed more efficient catalystD1 and the aromatic hydroxylation mechanism of the [Cu2(H-XYL)O2]2+ complex mediated by a peroxo dicopper core. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 17, 2019 Category: Chemistry Authors: Yan Fang Liu Source Type: research

A general benzylic C –H activation and C–C coupling reaction of zirconocenes mediated by C–N bond cleavage in tert-butylisocyanide – unusual formation of iminoacyl complexes
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT03120K, PaperPerdita Arndt, Melanie Rei ß, Anke Spannenberg, Claas Schünemann, Fabian Reiß, Torsten Beweries Reactions of the zirconocene alkyne complex [rac-(ebthi)Zr( η2-Me3SiC2SiMe3)] (rac-(ebthi) =rac-1,2-ethylene-1,1 ′-bis(η5-tetrahydroindenyl)) withtert-butylisocyanide and methylbenzenes were investigated. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 17, 2019 Category: Chemistry Authors: Perdita Arndt Source Type: research

Deoxydehydration of polyols catalyzed by a molybdenum dioxo-complex supported by a dianionic ONO pincer ligand
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT03759D, PaperRandy Tran, Stefan M. Kilyanek Molybdenumcis-dioxo bis-phenolate ONO complexes were synthesized and have been shown to be active for DODH. Catalysts were screened for activity at 190 °C and ambient pressure, and appreciable alkene yields of up to 59% were obtained. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 17, 2019 Category: Chemistry Authors: Randy Tran Source Type: research

Insights into the solvent-assisted degradation of organophosphorus compounds by a Zr-based metal –organic framework
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT03710A, CommunicationJacob A. Harvey, Charles J. Pearce, Morgan G. Hall, Eric J. Bruni, Jared B. DeCoste, Dorina F. Sava Gallis Insights into the MOF-based degradation of organophosphorus compounds in non-/aqueous solvents highlights the effect of solvent size on reaction rates. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 17, 2019 Category: Chemistry Authors: Jacob A. Harvey Source Type: research

Ferrocenyl palladacycles derived from unsymmetrical pincer-type ligands: Evidences of Pd(0) nanoparticles generation during Suzuki-Miyaura reaction and applications in direct arylation of thiazole and isoxazole
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03465J, PaperAnkur Maji, Anshu Singh, Aurobinda Mohanty, Pradip K Maji, Kaushik Ghosh A new family of ferrocenyl-palladacycle complexes Pd(L1)Cl (Pd1) and Pd(L2)Cl (Pd2) were synthesized and characterized by UV-visible, IR, ESI-MS, NMR spectral studies. Molecular structures of Pd1 and Pd2 were determined... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 17, 2019 Category: Chemistry Authors: Ankur Maji Source Type: research

Synthesis, Characterisation and Potent Cytotoxicity of Unconventional Platinum(IV) Complexes with Modified Lipophilicity
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03339D, PaperKrishant Moneesh Deo, Jennette Sakoff, Jayne Gilbert, Yingjie Zhang, Janice R Aldrich-Wright Novel platinum(IV) complexes were synthesised to examine the facile modulation of the lipophilicity of the complex by incorporating axial ligands of increasing length, ranging from 2 –6 carbons. RP-HPLC was used... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 17, 2019 Category: Chemistry Authors: Krishant Moneesh Deo Source Type: research

Relative Stability of M/NHC Complexes (M = Ni, Pd, Pt) against R −NHC, X−NHC and X−X Couplings in M(0)/M(II) and M(II)/M(IV) Catalytic Cycles: a Theoretical Study
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03266E, PaperAlexander Astakhov, Safarmurod Soliev, Evgeniy Gordeev, Victor Chernyshev, Valentine Ananikov Complexes of Ni, Pd, and Pt with N-heterocyclic carbenes (NHCs) catalyze numerous organic reactions via typically proposed M0/MII catalytic cycles comprising intermediates with the metal center in (0) and (II)... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 17, 2019 Category: Chemistry Authors: Alexander Astakhov Source Type: research

Cerium –carbon dative interactions supported by carbodiphosphorane
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT03770E, PaperWei Su, Sudip Pan, Xiong Sun, Lili Zhao, Gernot Frenking, Congqing Zhu The first example of a molecule with two dative bonds between carbone and a rare-earth element was investigated by a joint experimental and theoretical study. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 16, 2019 Category: Chemistry Authors: Wei Su Source Type: research

Mechanistic insights into the non-bifunctional hydrogenation of esters by Co(II) pincer complexes: a DFT study
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT02563D, PaperAnimesh Chowdhury, Santu Biswas, Anup Pramanik, Pranab Sarkar Mechanistic details have been investigated for the catalytic hydrogenation of esters to alcohols by Co(II) pincer complexes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 16, 2019 Category: Chemistry Authors: Animesh Chowdhury Source Type: research

Symmetry correlations between crystallographic and photoluminescence study of ternary β-diketone europium(III) based complexes using 1,10-phenanthroline as the ancillary ligand
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT02580D, PaperOrbett T. Alexander, Robin E. Kroon, Alice Brink, Hendrik G. Visser This work entails deep red emitting EuIII based complexes with a variety of ternary β-diketonate ligands and 1,10-phenanthroline as the ancillary ligand in the system. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 16, 2019 Category: Chemistry Authors: Orbett T. Alexander Source Type: research

Substituents Lead to Differences in the Formation of Two Different Butterfly-shaped Ni Ⅱ2DyⅢ2 Clusters: Structures and Multistep Assembly Mechanisms
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03795K, PaperKai-Qiang Mo, Zhonghong Zhu, Hai-Ling Wang, Xiong-Feng Ma, Jin-Mei Peng, Hua-Hong Zou, Juan Bai, Fu-Pei Liang The most effective way to understand reaction mechanism and kinetics is to identify the reaction intermediates and determine the possible reaction patterns. The influencing factors that must be considered in... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 16, 2019 Category: Chemistry Authors: Kai-Qiang Mo Source Type: research

A comparative study on the nickel binding ability of peptides containing separate cysteinyl residues
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03055G, PaperGy örgyi Szunyog, Aliz Laskai, Dóra Szűcs, Imre Sóvágó, Katalin Várnagy Nickel(II) complexes of peptides CSSACS-NH2, ACSSACS-NH2, SSCSSACS-NH2 and GACAAH-NH2 have been studied by potentiometric and various spectroscopic (UV-vis, CD, NMR, ESI-MS) techniques. All peptides have high nickel(II) binding ability in... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 16, 2019 Category: Chemistry Authors: Gy örgyi Szunyog Source Type: research

A porous and redox active ferrocenedicarboxylic acid based aluminium MOF with MIL-53-architecture
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03489G, PaperJannick Benecke, Sebastian Mangelsen, Tobias Engesser, Thomas Weyrich, Jannik Junge, Norbert Stock, Helge Reinsch The metallocene based linker 1,1 ’-ferrocenedicarboxylic acid (H2FcDC) was used to synthesise the first permanently porous ferrocenedicarboxylate, exhibiting a MIL-53 architecture. This compound Al MIL 53 FcDC [Al(OH)(FcDC)] is obtained in... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 16, 2019 Category: Chemistry Authors: Jannick Benecke Source Type: research

Correction: A comparative study of Ir(III) complexes with pyrazino[2,3-f][1,10]phenanthroline and pyrazino[2,3-f][4,7]phenanthroline ligands in light-emitting electrochemical cells (LECs)
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Iv án González, Paulina Dreyse, Diego Cortés-Arriagada, Mahesh Sundararajan, Claudio Morgado, Iván Brito, Cristina Roldán-Carmona, Henk J. Bolink, Bárbara Loeb To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 16, 2019 Category: Chemistry Authors: Iv án González Source Type: research

C –H and C–F bond activation reactions of pentafluorostyrene at rhodium complexes
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT03371H, PaperConghui Xu, Maria Talavera, Stefan Sander, Thomas Braun Reactions of various Rh(I) complexes towards penta-fluorostyrene or its borylated derivative afforded coordination and C –F bond or C–H bond activation reactions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 16, 2019 Category: Chemistry Authors: Conghui Xu Source Type: research

CuI incorporated cobalt ferrite nanoparticles as a magnetically separable catalyst for oxidative amidation reaction
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT03440D, PaperMintu Maan Dutta, Hrishikesh Talukdar, Prodeep Phukan A Cu-incorporated magnetic nanocatalyst has been developed for oxidative amidation of aryl aldehydes with 2-aminopyridine in the presence of TBHP. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 16, 2019 Category: Chemistry Authors: Mintu Maan Dutta Source Type: research

Up-conversion luminescence lifetime thermometry based on the 1G4 state of Tm3+ modulated by cross relaxation processes
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT03452H, PaperYuting Fu, Lijuan Zhao, Yuao Guo, Hua Yu The first study on the up-conversion luminescence lifetime thermometry based on the1G4 state of Tm3+ modulated by cross relaxation processes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 16, 2019 Category: Chemistry Authors: Yuting Fu Source Type: research

Direct synthesis of an anionic 13-vertex closo-cobaltacarborane cluster
Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT03111A, CommunicationThomas M. Maier, Peter Coburger, Nicolaas P. van Leest, Evamarie Hey-Hawkins, Robert Wolf Reaction of 1,2-bis(diphenylphosphino)-ortho-carborane (L) with [K(thf){(MesBIAN)Co( η4-cod)}] (1,MesBIAN = bis(mesityliminoacenaphthene)diimine, cod = 1,5-cyclooctadiene) affords an anionic 13-vertexcloso-cobaltacarborane cluster (2) in one step. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 16, 2019 Category: Chemistry Authors: Thomas M. Maier Source Type: research

Correction: Multi-color electrochromism from coordination nanosheets based on a terpyridine-Fe(II) complex
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Yu Kuai, Weijun Li, Yujie Dong, Wai-Yeung Wong, Shuanma Yan, Yuyu Dai, Cheng Zhang To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 16, 2019 Category: Chemistry Authors: Yu Kuai Source Type: research

Adducts of Triangular Silver(I) 3,5-Bis(trifluoromethyl)pyrazolate with Thiophene-Derivatives: A Weak Interaction Model of Desulfurization
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03344K, CommunicationRongrong Liu, Wen-Hua Zhang, Donghui Wei, Jing-Huo Chen, Guang Yang The π-acidic triangular silver(I) 3,5-bis(trifluoromethyl)pyrazolate (Ag3pz3) has been employed to form air-stable 1:1 adducts with the so-called heterocyclic aromatic sulfur compounds (HASC), such as dibenzothiophene (DBT), 4,6-dimethyldibenzothiophene (DMDBT), benzothiophene (BT)... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 16, 2019 Category: Chemistry Authors: Rongrong Liu Source Type: research

Direct comparison of dithienosilole and dithienogermole as π-conjugated linkers in photosensitizers for dye-sensitized solar cells
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT02600B, PaperYohei Adachi, Taishi Nabeya, Takanori Nomura, Keisuke Kondo, Keigo Kawakami, Yousuke Ooyama, Joji Ohshita Dithienosilole (DTS) and dithienogermole (DTG) are useful building units of π-conjugated organic materials. In the present work, donor–π–acceptor (D–π–A) dyes with bis(dihexyloxyphenyl)aminophenyl, DTS or DTG, and pyridine or cyanoacrylic acid... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 15, 2019 Category: Chemistry Authors: Yohei Adachi Source Type: research

A Water-Stable Zinc(II)-Organic Framework as a Multiresponsive Luminescent Sensor for Toxic Heavy Metal Cations, Oxyanions and Organochlorine Pesticides in Aqueous Solution
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03195B, PaperXiaoqing Wang, Dou-Dou Feng, Jing Tang, Yu-Di Zhao, Jun Li, Jie Yang, Chan Kyung Kim, Feng Su A novel metal-organic framework with formula [Zn3(DDB)(DPE)] •H2O (1) (H5DDB=3,5-di(2’,4’-dicarboxylphenyl)benozoic acid and DPE=1,2-di(4-pyridyl)ethylene), has been solvothermal synthesized by employing a rigid carboxylate ligand H5DDB to assemble with Zn(II) ions in the... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 15, 2019 Category: Chemistry Authors: Xiaoqing Wang Source Type: research

Isomeric Ir(III) complexes for tracking mitochondrial pH fluctuation and inducing mitochondria disfunction during photodynamic therapy
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03453F, PaperHaijie Chen, Ge Chen, Huiqun Cao, Xuepeng Zhang, Ling Zhang, Linhai Jiang, Pingyu Zhang, Qianling Zhang Mitochondrial pH is known to be alkaline (near 8.0) and has emerged as a potential factor for mitochondrial function and disorder. Here we investigate two pairs of isomeric phosphorescent Ir(III)... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 15, 2019 Category: Chemistry Authors: Haijie Chen Source Type: research

Linear-shaped LnIII4 and LnIII6 clusters constructed by polydentate Schiff base ligand and β-diketone co-ligand: structures, fluorescent properties, magnetic refrigeration and single-molecule magnet behavior
Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT03478A, PaperWen-Min Wang, Li-Yuan He, Xin-Xin Wang, Ying Shi, Zhilei Wu, Jian-zhong Cui Ten new linear-shaped LnIII4 and LnIII6 clusters, with the formula of [Ln4(acac)6L2(CH3O)2(CH3OH)4] ·xCH3OH (Ln = Nd (1), Sm (2), Eu (3), Gd (4), Tb (5), Dy (6), and Tm (8), Hacac... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 15, 2019 Category: Chemistry Authors: Wen-Min Wang Source Type: research