ESI and tandem MS for mechanistic studies with high-valent transition metal species
Dalton Trans., 2022, Accepted Manuscript DOI: 10.1039/D2DT00809B, PaperKatharina Bleher, Peter Comba, J ürgen H. Gross, Thomas Josephy The analysis of high-valent metal species has been in the focus of research for over 20 years. Mass spectrometry (MS) represents a technique routinely used for their characterization, in particular... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 19, 2022 Category: Chemistry Authors: Katharina Bleher Source Type: research

Strong Magnetic Exchange Coupling in a Radical-Bridged Trinuclear Nickel Complex
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Luming Yang, Julius Oppenheim, Mircea Dinca Reaction of 2,3,6,7,10,11-hexaaminotriphenylene hexahydrochloride (HATP ·6HCl) and (TpPhNi)Cl (TpPh = tris(3,5-diphenyl-1-pyrazolyl)borate) produces the radical-bridged trinickel complex [(TpPhNi)3(HITP)] (HITP3 –• = 2,3,6,7,10,11-hexaiminotriphenylene). Magnetic measurements and broken-symmetry density functional theory calculations reveal strong exchange... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 19, 2022 Category: Chemistry Authors: Luming Yang Source Type: research

Copper(II) and Zinc(II) Complexation with N Ethylene hydroxycyclams and Consequences on the Macrocyclic Backbone Configuration
We report a series of four cyclams and cross-bridged cyclams, N-functionalized by one hydroxyethyl arm, which may incorporate additional methyl(s) group(s). The Cu(II) and Zn(II) complexes of these ligands were... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 19, 2022 Category: Chemistry Authors: Nancy AlHaddad Source Type: research

Highly emissive supramolecular gold(I) –BTD materials
Dalton Trans., 2022, Advance Article DOI: 10.1039/D2DT00950A, PaperAndrea Pinto, Marcelo Echeverri, Berta G ómez-Lor, Laura Rodríguez Herein we report the synthesis of three light emitting rod-shaped gold(I) complexes by combining ethynyl-functionalized 2,1,3-benzothiadiazole (BTD), with different N-heterocyclic (imidazole, benzimidazole and phenantroimidazole) carbene gold(I) complexes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 18, 2022 Category: Chemistry Authors: Andrea Pinto Source Type: research

The confinement effect of layered double hydroxides on intercalated pyromellitic acidic anions and highly selective uranium extraction from simulated seawater
Dalton Trans., 2022, Advance Article DOI: 10.1039/D2DT01278B, PaperLixiao Yang, Qian Wang, Huiqin Yao, Qishuo Yang, Xiao Lu, Zhenglong Wu, Rong Liu, Keren Shi, Shulan Ma Oxygen-rich pyromellitic acidic anions are intercalated into MgAl-layered double hydroxides to fabricate the MgAl –PMA–LDH composite exhibiting excellent adsorption performance toward uranium. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 18, 2022 Category: Chemistry Authors: Lixiao Yang Source Type: research

An α-diiminato germylene family: syntheses, structures, and reactivity towards C–C coupled digermylene and digermylene oxide
Dalton Trans., 2022, Advance Article DOI: 10.1039/D2DT00981A, PaperJingjing Liu, Jianxuan Shang, Jing Wei, Fangfang Gao, Lei Hou, Fanlong Zeng, Anyang Li, Wenyuan Wang The synthesis and reactivity of a germylene chloride2 stabilized by a rigid α-diiminate ligand was systematically explored to afford a new family of germylenes, which bonding nature was revealed by their XRD structures and DFT calculations. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 18, 2022 Category: Chemistry Authors: Jingjing Liu Source Type: research

Diruthenium and triruthenium compounds of the potential redox active non-chelated η1-N,η1-N-benzothiadiazole bridge
Dalton Trans., 2022, Advance Article DOI: 10.1039/D2DT00533F, PaperSanchaita Dey, Arijit Singha Hazari, Shaikh M. Mobin, Goutam Kumar Lahiri The redox non-innocent behaviour of non-chelated μ-bis-η1-N, η1-N BTD (2,1,3-benzothiadiazole)-bridged mixed valent diruthenium and triruthenium complexes is attributed to a moderately coupled delocalised electronic state withVab≈ 2640–2890 cm−1. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 18, 2022 Category: Chemistry Authors: Sanchaita Dey Source Type: research

Fluorinated 2,6-bis(arylimino)pyridyl iron complexes targeting bimodal dispersive polyethylenes: probing chain termination pathways via a combined experimental and DFT study
Dalton Trans., 2022, Advance Article DOI: 10.1039/D2DT00868H, PaperQiuyue Zhang, Zheng Zuo, Yanping Ma, Tongling Liang, Xinzheng Yang, Wen-Hua Sun Ortho-Fluorinated iron catalysts showed high activity in ethylene polymerization delivering two types of PEs with different end-groups. DFT studies on polymerization mechanism have explain the above-mentioned observations. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 18, 2022 Category: Chemistry Authors: Qiuyue Zhang Source Type: research

Photoinduced Jahn –Teller switch in Mn(III) terpyridine complexes
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Kyle Barlow, Julien Eng, Iona Ivalo, Marco Coletta, Euan K. Brechin, Thomas J. Penfold, J. Olof Johansson Ultrafast transient absorption spectra were recorded for [Mn(terpy)X3], where X = Cl, F, and N3, to explore photoinduced switching from axial to equatorial Jahn –Teller (JT) distortion. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 18, 2022 Category: Chemistry Authors: Kyle Barlow Source Type: research

Preparation, characterization and DFT+U study of the polar Fe3+-based phase Ba5Fe2ZnIn4S15 containing S= 5/2 zigzag chains
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Batoul Almoussawi, Victor Duffort, Angel M. Arevalo-Lopez, Maxime Braun, Nora Djelal, Houria Kabbour The polar magnetic chalcogenide phase Ba5Fe2ZnIn4S15 was synthesized and its structure solved from single crystal XRD. It is the first member with a 3d magnetic metal (Fe3+) in the Pb5ZnGa6S15-type... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 18, 2022 Category: Chemistry Authors: Batoul Almoussawi Source Type: research

An [FeIII8] molecular oxyhydroxide
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Euan K Brechin, Daniel J. Cutler, Marco Coletta, Mukesh Singh, Angelos B. Tsanai, Laura J. McCormick McPherson, Simon Coles, J ürgen Schnack An [FeIII8] hexagonal bipyramid displays antiferromagnetic exchange between the two capping tetrahedral ions and the six ring octahedral ions resulting in a spin ground state, S = 10. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 18, 2022 Category: Chemistry Authors: Euan K Brechin Source Type: research

MOF nanoparticles as heterogeneous catalysts for direct amide bond formations
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Isabel Ab ánades Lázaro, Ross S. Forgan, Francisco. G. Cirujano Ultra-small isoreticular UiO-type metal –organic frameworks (MOFs) with different functionalized and extended linkers are evaluated for catalytic direct amide bond formation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 18, 2022 Category: Chemistry Authors: Isabel Ab ánades Lázaro Source Type: research

Benchmarking the dynamic luminescent properties and UV stability of B18H22-based materials
Dalton Trans., 2022, Accepted Manuscript DOI: 10.1039/D2DT01225A, CommunicationKierstyn P Anderson, Ash Sueh Hua, John B Plumley, Austin D Ready, Arnold L Rheingold, Thomas L Peng, Peter Ivan Djurovich, Christopher Kerestes, Neil A Snyder, Andrew Andrews, Justin R Caram, Alex Spokoyny The dynamic photoluminescent properties, and potential quenching mechanisms, of anti-B18H22, 4,4 ’-Br2-anti-B18H20, and 4,4’-I2-anti-B18H20 are investigated in solution and polymer films. UV stability studies of the neat powders show no decomposition... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton ...
Source: RSC - Dalton Trans. latest articles - May 18, 2022 Category: Chemistry Authors: Kierstyn P Anderson Source Type: research

Coupled Nickel-Cobalt Nanoparticles/N,P,S-co-doped Carbon Hybrid Nanocages with High Performance for Catalysis and Protein Adsorption
Dalton Trans., 2022, Accepted Manuscript DOI: 10.1039/D2DT01130A, PaperYanchun Xie, Jing Zheng, Suping Han, Jingli Xu, Xue-Bo Yin, Min Zhang Carbon-supported bimetallic NiCo nanoparticles(NPs) have emerged as attractive catalysts and adsorbent for the reduction of 4-nitrophenol(4-NP) and separation of histidine-rich(His-rich) protein recently due to its low cost, high catalytic activity... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 18, 2022 Category: Chemistry Authors: Yanchun Xie Source Type: research

Preparation of Bi/BiOBr sensitized titania nanorod arrays via a one-pot solvothermal method and construction of kanamycin photoelectrochemical aptasensors
Dalton Trans., 2022, Advance Article DOI: 10.1039/D2DT00618A, PaperMin Wu, Mengyao Dong, Zeinhom M. El-Bahy, Tao Jing, Gaber A. M. Mersal, Jingzhi Tian, Haiyan Qi, Danni Shi, Nithesh Naik, Vignesh Murugadoss, Mohamed M. Ibrahim, Mina Huang, Zhanhu Guo Photoactive Bi/BiOBr/TiO2 NRA composites displayed an efficient visible light response and fast charge transport rate and were used to construct sensitive kanamycin photoelectrochemical aptasensors. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Tr...
Source: RSC - Dalton Trans. latest articles - May 17, 2022 Category: Chemistry Authors: Min Wu Source Type: research