Manifestation of dissimilar types of magnetism in iron- and chromium-substituted Mn2SnS4
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT02509K, PaperTuhin Subhra Dash, Subham Naik, Sheetal, Sachindra Nath Sarangi, Debakanta Samal, C. S. Yadav, S. D. Kaushik, Saroj L. Samal Variation of magnetic properties by changing the d-electrons of the substituent in Mn2 −xMxSnS4 (M = Fe, Cr). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 25, 2021 Category: Chemistry Authors: Tuhin Subhra Dash Source Type: research

A Protein Scaffold Enables Hydrogen Evolution for a Ni-bisdiphosphine Complex
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT03295J, PaperJoseph A Laureanti, Qiwen Su, Wendy Shaw An artificial metalloenzyme acting as a functional biomimic of hydrogenase enzymes was activated by assembly via covalent attachment of the molecular complex, [Ni(PNglycineP)2]2-, within a structured protein scaffold. Electrocatalytic H2... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 25, 2021 Category: Chemistry Authors: Joseph A Laureanti Source Type: research

Imidosulfonate scorpionate ligands in lanthanide single-molecule magnet design: slow magnetic relaxation and butterfly hysteresis in [ClDy{Ph2PCH2S(NtBu)3}2]
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Jochen Jung, Christina M. Legendre, Serhiy Demeshko, Regine Herbst-Irmer, Dietmar Stalke Single-molecule magnets (SMMs) harbour vast opportunities of potential pioneering applications upon optimization like big data storage and quantum computing. Lanthanides were found to be highly suitable candidates in the design... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 25, 2021 Category: Chemistry Authors: Jochen Jung Source Type: research

Synthesis of ZrO2:Pr3+,Gd3+ nanocrystals for optical thermometry with a thermal sensitivity above 2.32% K −1 over 270 K of sensing range
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT02070F, PaperMinghui Li, Jun Zhou, Ruoshan Lei, Huanping Wang, Feifei Huang, Shiqing Xu ZrO2:Pr3+/Gd3+ demonstrates outstanding optical thermometric performances, whose thermal quenching behaviors depend on non-radiative transition processes and trap energy levels. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 25, 2021 Category: Chemistry Authors: Minghui Li Source Type: research

Monitoring Spin-Crossover phenomena via Re(I) luminescence in hybrid Fe(II) silica coated nanoparticles
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Ismael Francisco D íaz-Ortega, Eva Luz Fernández-Barbosa, Silvia Titos, Simon Pope, Juan Ramón Jiménez, Enrique Colacio, Juan Manuel Herrera Bare (1) and silica coated (1@SiO2) spin crossover (SCO) nanoparticles based on the polymer {[Fe(NH2Trz)3](BF4)2}n have been prepared following a water-in-oil synthetic procedure. For 1, the critical temperatures of the... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 25, 2021 Category: Chemistry Authors: Ismael Francisco D íaz-Ortega Source Type: research

Rigid versions of PDTA4- incorporating a 1,3-diaminocyclobutyl spacer for Mn2+ complexation: stability, water exchange dynamics and relaxivity
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT02498A, PaperRoc ío Uzal-Varela, Daniela Lalli, Isabel Brandariz, Aurora Rodríguez-Rodríguez, Carlos Platas-Iglesias, Mauro Botta, David Esteban-Gómez Rigid derivatives of the acyclic ligand PDTA4 (H4PDTA = propylenediamine-N,N,N ′,N′-tetraacetic acid) were prepared by functionalization of a cis-1,3-cyclobutanediamine spacer. The new ligands contain either four acetate groups attached to the... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 25, 2021 Category: Chemistry Authors: Roc ío Uzal-Varela Source Type: research

Using molten salts to probe outer-coordination sphere effects on lanthanide(III)/(II) electron-transfer reactions
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT02708E, PaperMolly M. MacInnes, Zachary R. Jones, Bo Li, Nickolas H. Anderson, Enrique R. Batista, Ida M. DiMucci, Cecilia Eiroa-Lledo, Karah E. Knope, Maksim Y. Livshits, Stosh A. Kozimor, Veronika Mocko, Kristen A. Pace, Francisca R. Rocha, Benjamin W. Stein, Jennifer N. Wacker, Ping Yang Molten salt matrices were used to evaluate outer-coordination sphere effects on lanthanide redox chemistry. Results were rationalized by correlating the polarization power of the outer-sphere cation with shifts in the Ln3+/Ln2+ reduction potentials. To cite this article before page n...
Source: RSC - Dalton Trans. latest articles - October 25, 2021 Category: Chemistry Authors: Molly M. MacInnes Source Type: research

Luminescence and photoionization of X-ray generated Sm2+ in Coprecipitated CaF2 Nanocrystals
We report photoluminescence and photoionization properties of Sm2+ ions generated by X-irradiation of nanocrystalline CaF2:Sm3+ prepared by coprecipitation. The nanocrystals were of 46 nm average crystallite size with a distribution... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 23, 2021 Category: Chemistry Authors: Z. Siti Rozaila Source Type: research

Phosphorous-substituted redox-active ligands in base metal hydrosilylation catalysis
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT02879K, FrontierAnuja Sharma, Ryan J. Trovitch The preparation of redox-active ligand supported manganese, iron, cobalt, and nickel compounds that feature hemilabile phosphine moieties has allowed for highly efficient hydrosilylation catalysis. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 23, 2021 Category: Chemistry Authors: Anuja Sharma Source Type: research

Coupling external and internal pressure for the structural transition of MIL-53(Cr)
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT02538D, PaperBin Zheng, Jinlei Wang, Li Zhang, Lianli Wang Flexible metal –organic framework materials have the ability to perform stimulated sudden volume contractions and thus attract increasing attention for potential applications as actuators or sensors. Here, we investigated the structural... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 23, 2021 Category: Chemistry Authors: Bin Zheng Source Type: research

Tetragonal CoMn2O4 nanocrystals on electrospun carbon fibers as high-performance battery-type supercapacitor electrode materials
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT02829D, PaperDaniel M. Mijailovi ć, Vuk V. Radmilović, Uroš Č. Lačnjevac, Dušica B. Stojanović, Karen C. Bustillo, Vladimir D. Jović, Velimir R. Radmilović, Petar S. Uskoković A novel C@CoMn2O4 composite material was fabricated, having improved performance as a battery-type electrode for supercapacitor applications. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 22, 2021 Category: Chemistry Authors: Daniel M. Mijailovi ć Source Type: research

A 2D/2D NiCo-MOF/Ti3C2 heterostructure for simultaneous detection of acetaminophen, dopamine and uric acid by differential pulse voltammetry
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT03208A, PaperXing Lu, Feng Zhang, Yimeng Sun, Kai Yu, Guo Wei, Fengyu Qu A 2D-2D NiCo-MOF/Ti3C2 heterojunction is constructed as a non-enzymatic biosensor for the simultaneous electrochemical detection of acetaminophen (AP), dopamine (DA) and uric acid (UA) by differential pulse voltammetry. Benefiting from... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 22, 2021 Category: Chemistry Authors: Xing Lu Source Type: research

Post-synthetically modified metal-organic frameworks for sensing and capture of water pollutants
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT02862F, PerspectiveSoumya Mukherjee, Subhajit Dutta, Yogeshwar D. More, Sahel Fajal, Sujit K. Ghosh Thanks to a bottom-up Lego ® design of metals and organic ligands, the library of metal-organic frameworks (MOFs) have seen a conspicuous growth. Post-synthetically modified MOFs comprise a relatively smaller subset... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 22, 2021 Category: Chemistry Authors: Soumya Mukherjee Source Type: research

C –O and C–C bond cleavage of α,β-unsaturated esters with the assistance of a gallane(pyridyl)iron complex
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT03286K, PaperTakako Muraoka, Nursaliha Siti, Keiji Ueno C –O and C–C bonds in α,β-unsaturated esters were selectively cleaved with the assistance of a gallane(pyridyl)iron complex. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 22, 2021 Category: Chemistry Authors: Takako Muraoka Source Type: research

Bi3+ photoluminescence in Y1-xBixCa3(GaO)3(BO3)4 and the energy transfer to Eu3+ and Tb3+ in co-doped phosphors
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT03100G, PaperYan Gao, Huayu Qian, Pengfei Jiang, Rihong Cong, Tao Yang Bi3+ possesses the outer shell lone pair electrons, and, thus the so-involved photoluminescence (PL) is sensitive to the surrounding coordination, . in additionBesides, the similarity in structural chemistry between Bi3+... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 22, 2021 Category: Chemistry Authors: Yan Gao Source Type: research

Iron Oxidation to Amplify the Na and Li Storage Capacities of Nano-sized Maricite NaFePO4
This study reports an effective approach to improve dramatically the electrochemical performance of nanosized NaFePO4 with a maricite structure, which is commonly considered as electrochemically inactive due to the absence... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 22, 2021 Category: Chemistry Authors: Tanya Boyadzhieva Source Type: research

Eight coordinated mononuclear dysprosium complexes of heptadentate aminophenol ligands: the influence of the phenol substituents and the ancillary donors on the magnetic relaxation
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT02756E, PaperMatilde Fondo, Julio Corredoira-V ázquez, Ana M. Garcia-Deibe, Jesus Sanmartin Matalobos, Daniel Reta Mañeru, Enrique Colacio The mononuclear complexes [Dy(3Br,5Cl-H3L1,1,4)(D)] ·solvate (D = H2O, solvate = 0.25MeOH, 1W·0.25MeOH; D = Py without solvate, 1Py), and [Dy(3NO2,5Br-H3L1,1,4)(H2O)] (2W) were isolated. The crystal structures of 1W·0.25MeOH, 1Py and 2W·2CH3C6H5... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 22, 2021 Category: Chemistry Authors: Matilde Fondo Source Type: research

Gold(I) 1,2,3-Triazolylidene Complex Featuring the Interaction Between Gold and Methine Hydrogen
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT02827H, CommunicationAdi Narayana Mannem, Moulali Vaddamanu, Arruri Sathyanarayana , Kumar Siddhant, Shohei Sugiyama, Kazuhisa Ozaki, Aravind Kumar Rengan, Kavitha Velappan, Kyohei Hisano, Osamu Tsutsumi, Prabusankar Ganesan Mesoionic N-heterocyclic carbene-gold(I) complex with a unique Au ····H–C(methine) intramolecular hydrogen bonding interaction has been investigated in the solid-state. The structure of this new neutral gold(I)-carbene was characterized by FT-IR, NMR... The content of this RSS Feed (c) The Royal Society of Chemi...
Source: RSC - Dalton Trans. latest articles - October 22, 2021 Category: Chemistry Authors: Adi Narayana Mannem Source Type: research

Robust ionic liquid@MOF composite as a versatile superprotonic conductor
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT02877D, PaperTaksande Kiran, Effrosyni Gkaniatsou, Corine Simonnet-J égat, Carine Livage, Guillaume Maurin, Nathalie Steunou, Sabine Devautour-Vinot A highly performing proton conducting composite was prepared through the impregnation of EMIMCl ionic liquid in the mesoporous MIL-101(Cr)-SO3H MOF. The resulting EMIMCl@MIL-101(Cr)-SO3H composite displays high thermal and chemical stability,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 22, 2021 Category: Chemistry Authors: Taksande Kiran Source Type: research

Role of the (Pseudo)Halido Ligand in Ruthenium(II) p-Cymene α-Amino Acid Complexes on Speciation, Protein Reactivity and Cytotoxicity
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT03274G, PaperLorenzo Biancalana, Emanuele Zanda, Mouna Hadiji, Stefano Zacchini, Alessandro Pratesi, Guido Pampaloni, Paul Joseph Dyson, Fabio Marchetti The reactions of the dimeric complexes [RuX2( η6-p-cymene)]2 (X = Br, I, SCN) with ʟ-proline (ProH) and trans-4-hydroxy-ʟ-proline (HypH), in methanol in the presence of NaOH, afforded [RuX(κ2N,O-Pro)(η6-p-cymene)] (X = Br,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 22, 2021 Category: Chemistry Authors: Lorenzo Biancalana Source Type: research

Effect of chirality on the anticancer activity of Pt(II) and Pt(IV) complexes containing 1R,2R and 1S,2S enantiomers of the trans-1,2-diamino-4-cyclohexene ligand (DACHEX), an analogue of diaminocyclohexane used in oxaliplatin
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT02255E, PaperParide Papadia, Alessandra Barbanente, Nicoletta Ditaranto, James D. Hoeschele, Giovanni Natile, Cristina Marzano, Valentina Gandin, Nicola Margiotta Two Pt(II) and four Pt(IV) enantiomerically pure, oxaliplatin-like, compounds containing an unsaturated cyclic diamine as a substitute for thetrans-1,2-diaminocyclohexane used in oxaliplatin, were investigated. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 22, 2021 Category: Chemistry Authors: Paride Papadia Source Type: research

Redox induced oxidative C-C coupling of non-innocent bis(heterocyclo)methanides
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT03310G, PaperGoutam Kumar Lahiri, Sanjib Panda, Rupal Baliyan, Suman Dhara, Kuo-Wei Huang Redox driven C-C bond formation has gained recent attention over the traditional sequence of oxidative addition, insertion and reductive elimination. In this regard, transient radical mediated diverse reactivity profile of... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 22, 2021 Category: Chemistry Authors: Goutam Kumar Lahiri Source Type: research

One pot tandem dual C C and CO bond reductions in the β-alkylation of secondary alcohols with primary alcohols by ruthenium complexes of amido and picolyl functionalized N-heterocyclic carbenes
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT02849A, PaperA. P. Prakasham, Sabyasachi Ta, Shreyata Dey, Prasenjit Ghosh A neutral amido-functionalized ruthenium complex and a cationic picolyl-functionalized ruthenium complex of NHC ligands efficiently catalysed tandem β-alkylation reaction of alcohols, including the synthesis of various bioactive flavan derivatives. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 21, 2021 Category: Chemistry Authors: A. P. Prakasham Source Type: research

Micro-controlling of the grain boundaries in NiCo2O4/NiCo2S4 nanowires for enhanced charge storage
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT02941J, PaperMengqi Cui, Zining Wang, Hui Wang, Xuyun Wang, Jianwei Ren A NiCo2O4/NiCo2S4 material with rich grain boundaries has been grown on a nickel foam matrix by a vapor deposition method, and not only shows excellent specific capacitance performance, but also has high cycling stability. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 21, 2021 Category: Chemistry Authors: Mengqi Cui Source Type: research

Dihypoiodites stabilised by 4-ethylpyridine through O –I–N halogen bonds
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Eric Kramer, Shilin Yu, Jas S. Ward, Kari Rissanen Several neutralbis(O –I–N) compounds were synthesised incorporating various dihypoiodites and 4-ethylpyridine, which were characterised in both the solution and solid states. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 21, 2021 Category: Chemistry Authors: Eric Kramer Source Type: research

Pyridylpyrrolido ligand in Ge(II) and Sn(II) chemistry: Synthesis, reactivity and catalytic application
This study details the prepartion of a series of new germylenes and... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 21, 2021 Category: Chemistry Authors: Sanjukta Pahar Source Type: research

γ-CuI from Ionic Liquids/Poly(Ionic liquid)s Precursor with Controllable Morphologies and Improved Photocatalytic Performance
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT03124D, PaperSu-Yun Zhang, Fangchao Long, Chenxu Kang, Zhengyuan Jin, Ailun Zhao, Huawei Liang, Shuangchen Ruan, Yu-Jia Zeng γ-phase copper(I) iodide (abbreviated to CuI hereafter) with different morphologies is realized through one-step redox process from I-containing ionic liquid (IL) or poly(ionic liquid)s (PILs) precursors at room temperature. The... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 21, 2021 Category: Chemistry Authors: Su-Yun Zhang Source Type: research

Comparative studies on the VOCs sorption performances over hierarchical and conventional ZSM-5 zeolites
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT02869C, PaperQianxi Tang, Wei Deng, Donghang Chen, Dongqi Liu, Limin Guo The sorption behaviors of hexane, toluene and mesitylene as the probe volatile organic compounds (VOCs) over hierarchical and conventional zeolite ZSM-5 were investigated by a series of experiments, such as... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 21, 2021 Category: Chemistry Authors: Qianxi Tang Source Type: research

A New Broad-Band Infrared Window Material CdPbOCl2 with Excellent Comprehensive Properties
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT03215A, PaperChen Bai, Bingliang Cheng, Kewang Zhang, Min Zhang, Shilie Pan, Junjie Li Herein, a new IR window material CdPbOCl2 was rationally designed and fabricated by an heavy-metal oxide and halide combined strategy. The millimeter-scale CdPbOCl2 single crystal exhibits a wide IR transparent... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 21, 2021 Category: Chemistry Authors: Chen Bai Source Type: research

Novel polynitro azoxypyrazole-based energetic materials with high performance
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT03357C, CommunicationPengju Yang, Hongwei Yang, Ying Zhao , Jie Tang, Guangbin Cheng Novel polynitro azoxypyrazole-based energetic compounds 1,2-bis (4-nitro-1H-pyrazol-5-yl) diazene 1-oxide (3) and 1,2-bis (1,4-dinitro-1H-pyrazol-3-yl) diazene 1-oxide (4) were synthesized from 5-aminopyrazole-4-carbonitrile by the optimized reactions. Their structures are characterized by elemental... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 21, 2021 Category: Chemistry Authors: Pengju Yang Source Type: research

Three types of charged ligands based neutral phosphorescent iridium(III) complexes featuring nido-carborane: synthesis, structures, and solution processed organic light-emitting diode application
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT02990H, PaperQiuxia Li, Chao Shi, Manli Huang, Xinghua Zhang, Fangxiang Sun, Ying Zheng, Hong Yan, Chuluo Yang, Aihua Yuan In view of the fact that coordination configuration and special functional groups are both important for the optical properties of phosphorescent iridium complexes materials, we have prepared a novel family... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 21, 2021 Category: Chemistry Authors: Qiuxia Li Source Type: research

Pincer-Supported Metal/Main-Group Bonds as Platforms for Cooperative Transformations
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT02739E, PerspectiveMatthew Whited Electron-rich late metals and electropositive main-group elements (metals and metalloids) can be combined to provide an ambiphilic fa çade for exploring metal–ligand cooperation, yet the instability of the metal/main-group bond frequently... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 21, 2021 Category: Chemistry Authors: Matthew Whited Source Type: research

Macrocycle- and metal-centered reduction of metal tetraphenylporphyrins where the metal is copper(II), nickel(II) and iron(II)
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT02573B, PaperDmitry I. Nazarov, Mikhail G. Andronov, Aleksey V. Kuzmin, Salavat S. Khasanov, Evgeniya I. Yudanova, Alexander F. Shestakov, Akihiro Otsuka, Hideki Yamochi, Hiroshi Kitagawa, Dmitri V. Konarev Crystalline salts of metal tetraphenylporphyrins (M = Ni, Cu and Fe) are obtained in crystalline state and studied. Possibility of the doublet-quartet transition from {NiI(TPP2 −)}− to {NiII(TPP·3−)}−is shown. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The ...
Source: RSC - Dalton Trans. latest articles - October 20, 2021 Category: Chemistry Authors: Dmitry I. Nazarov Source Type: research

A hydrostable Zn2+ coordination polymer for multifunctional detection of inorganic and organic contaminants in water
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT03022A, PaperHao Cheng, Fu-Qiang Song, Na-Na Zhao, Xue-Qin Song A water-stable and highly emissive Zn2+ coordination polymer together with its PMMA films was developed for sensing of Fe3+ and picric acid (PA) in water. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 20, 2021 Category: Chemistry Authors: Hao Cheng Source Type: research

All-solid-state Z-scheme Ag3PO4/CSs/AgBr heterostructures for efficient visible-light photocatalysis and the photocatalytic mechanism
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT02937A, PaperNan Li, Guodong Fan, Miaomiao Fan, Fan Wu, Guoxian Zhang, Di Fan Using CSs as a charge carrier transfer bridge for constructing Z-scheme Ag3PO4/CSs/AgBr photocatalysts has high-efficiency catalytic ability. The Ag3PO4-CSs interface and the CSs-AgBr interface are ohmic contact and Schottky contact, respectively. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 20, 2021 Category: Chemistry Authors: Nan Li Source Type: research

Remote control: stereoselective coordination of electron-deficient 2,2 ′-bipyridine ligands to Re(I) and Ir(III) cores
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Kimberley Jerwood, Phoebe Lowy, Laura Deeming, Benson M. Kariuki, Paul D. Newman Configurational diastereoselectivity is observed upon coordination of a mono-substituted bipy ligand with an asymmetric amidinium group at the 4-position while no selectivity occurs with the analogous 5-derivative. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 20, 2021 Category: Chemistry Authors: Kimberley Jerwood Source Type: research

K3Na(TaF7)(SiF6): A Mixed-anion Pentanary Fluoride with Zero Dimensional Anions Exhibiting Large Band Gap
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT03320D, PaperRu-Ling Tang, Xin Lian, Wen-Dong Yao, Wen-Long Liu, Sheng-Ping Guo Metal halides have potential applications in many optics-related fields, such as birefringence materials. Here, a pentanary fluoride K3Na(TaF7)(SiF6), has been obtained through a facile hydrothermal route. It crystallizes in the... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 20, 2021 Category: Chemistry Authors: Ru-Ling Tang Source Type: research

The influence of alkyl chains on the performance of DSCs employing iron(II) N-heterocyclic carbene sensitizers
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Catherine E. Housecroft, Edwin C Constable, Mariia Karpacheva, Vanessa Wyss The photovoltaic performances of DSCs employing two new iron(II) N heterocyclic carbene (NHC) sensitizers are presented. The presence of n butyl side chains had a significant impact of DSCs performace.... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 20, 2021 Category: Chemistry Authors: Catherine E. Housecroft Source Type: research

Multiple phenyl ring appended Re-based complexes for strong visible light absorption and DNA binding
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT02216D, PaperBholey Singh, Balaram Pani, Deepak Gupta A series offacial-Re(CO)3-based acyclic complexes possessing N ∩O bis-chelating ligands and triphenylphosphine-oxide donors displayed strong absorption in the visible region (ε = 40  000 M−1 cm−1) and satisfactory DNA binding ability. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 20, 2021 Category: Chemistry Authors: Bholey Singh Source Type: research

Theoretical insights into the possible applications of amidoxime-based adsorbents in neptunium and plutonium separation
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT01900G, PaperYan-Mei Chen, Cong-Zhi Wang, Qun-Yan Wu, Jian-Hui Lan, Zhi-Fang Chai, Wei-Qun Shi Quantum chemical calculations demonstrated the potential applications of amidoxime-based adsorbents in neptunium and plutonium separation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 20, 2021 Category: Chemistry Authors: Yan-Mei Chen Source Type: research

Fluorescence and electrochemical detection of iodine vapor in the presence of high humidity using Ln-based MOFs
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT02839A, PaperXiuting Dong, Qing He, Menglin Li, Xinpeng Wang, Yuxin Wang, Wen Zhang Ln-based MOFs with BTC linkers could provide dual fluorescence and electrochemical response of iodine vapor in the presence of humidity with high sensitivity. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 20, 2021 Category: Chemistry Authors: Xiuting Dong Source Type: research

Design, synthesis, structural, spectral, redox properties and phenoxazinone synthase activity of tripodal pentacoordinate Mn(II) complexes with impressive turnover numbers
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT01925B, PaperSadananda Kumbhakar, Bishnubasu Giri, Arabinda Muley, Kalai Selvan Karumban, Somnath Maji Catechol oxidase (CO) and phenoxazinone synthase (PHS) are two enzymes of immense significance for their capability to oxidize catechols and o-aminophenols to o-quinones and phenoxazinones respectively. In this connection two... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 20, 2021 Category: Chemistry Authors: Sadananda Kumbhakar Source Type: research

Simple electrodeposition to synthesize a NiFeSx –modified Ti-Fe2O3 photoanode: an effective strategy to improve the photoelectrochemical water oxidation reaction
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT02303A, PaperHaoyu Wang, Rui Zhang, Yin Yin Li, Dejun Wang, Yanhong Lin, Tengfeng Xie The photocurrent density of a NiFeSx–Ti-Fe2O3 photoanode rises to 3 mA cm−2 at 1.23 Vvs. RHE and the onset potential of NiFeSx–Ti-Fe2O3 shifts negatively by 170 mV compared with Ti-Fe2O3. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 20, 2021 Category: Chemistry Authors: Haoyu Wang Source Type: research

Assessing the Lewis Acidity and Catalytic Activity of Bis(catecholato)germanes
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT03180E, PaperAndrew Timothy Henry, Taylor P. L. Cosby, Paul D Boyle, Kim M Baines The synthesis of a variety of bis(catecholato)germanes is reported. The Lewis acidity of the bis(catecholato)germanes was assessed using the experimental Gutmann-Beckett method and computational FIA and GEI methods. The oligomerization... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 20, 2021 Category: Chemistry Authors: Andrew Timothy Henry Source Type: research

Phosphorus mediated imidazolinium to oxazolium ring rearrangement
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT03363H, CommunicationDeependra Bawari, Solomon Volodarsky , Yael Ginzburg, Kuldeep Jaiswal, Pooja Joshi, Roman Dobrovetsky An unexpected rearrangement occured when an imidazolinium based OCO pincer-type ligand (1) was reacted with PCl3 producing a chlorophosphine with a pendant oxazolium "arm" (3). The mechanism of this rearrangement... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 20, 2021 Category: Chemistry Authors: Deependra Bawari Source Type: research

Alkali/alkaline earth-based metal –organic frameworks on biomedical applications
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT02814F, PerspectiveJian-Qiang Liu, Gaomin Ye, Chen Chen, Jingzhe Lin, Xinsheng Peng, Abhinav Kumar, Dong Liu With steady development of metal-organic framework (MOF) materials, this peculiar class of three-dimensional materials finds application prospects in myriad of areas. The integration of different metals with varied categories of... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 20, 2021 Category: Chemistry Authors: Jian-Qiang Liu Source Type: research

A selective fluorescent probe for gadoliniumIII in water based on a PdII-preorganized chromone-receptor
Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT01753E, PaperDaniele Paderni, Luca Giorgi, Eleonora Macedi, Mauro Formica, Paola Paoli, Patrizia Rossi, Vieri Fusi A preorganized PdII complex able to sense GdIII ions in real aqueous samplesvia an OFF –ON fluorescence signal. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 19, 2021 Category: Chemistry Authors: Daniele Paderni Source Type: research

BiOBr/Bi4MoO9 edge-on heterostructure with fast electron transport for efficient photocatalytic activity
This study demonstrates the rational design and construction of BiOBr/Bi4MoO9 edge-on heterostructure by growing fish scale-like BiOBr nanosheets on the surfaces of Bi4MoO9. Such structural and compositional merits expedite electron... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 19, 2021 Category: Chemistry Authors: Gui Yang Source Type: research

Direct Detection of Iron Clusters in L Ferritins through ESI MS Experiments
Dalton Trans., 2021, Accepted Manuscript DOI: 10.1039/D1DT03106F, CommunicationLara Massai, Silvia Ciambellotti, Lucrezia Cosottini, Luigi Messori, Paola Turano, Alessandro Pratesi Human cytoplasmic ferritins are heteropolymers of H and L subunits containing a catalytic ferroxidase center and a nucleation site for iron biomineralization, respectively. Here, ESI-MS successfully detected labile metal-protein interactions... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 19, 2021 Category: Chemistry Authors: Lara Massai Source Type: research

Correction: Graphene oxide encapsulated by mesoporous silica for intelligent anticorrosive coating: studies on release models and self-healing ability
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Peng Du, Juan Wang, Haichao Zhao, Guangzhou Liu, Liping Wang To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - October 19, 2021 Category: Chemistry Authors: Peng Du Source Type: research