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Design and Characterization of Fe(II) Complexes with Tetradentate Ligands Exhibiting Spin-Crossover Near Room Temperature
This study focuses on the design of Fe(II) complexes usingN,N'-Bis(2-pyridinylmethyl)-1,2-ethanediamine-based ligands with... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 23, 2024 Category: Chemistry Authors: Diyu Dou Source Type: research

The cubic structure of Li3As stabilized by substitution – Li8TtAs4 (Tt = Si, Ge) and Li14TtAs6 (Tt = Si, Ge, Sn) and their lithium ion conductivity
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00664J, PaperMartin Schmid, Florian Wegner, Claudia De Giorgi, Florian Pielnhofer, Arno Pfitzner The new lithium arsenidotetrelates Li8SiAs4, Li8GeAs4, Li14SiAs6, Li14GeAs6 and Li14SnAs6 were synthesized via ball milling and structurally characterized by Rietveld analysis of X-ray powder diffraction data. The aliovalent substitution of... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 23, 2024 Category: Chemistry Authors: Martin Schmid Source Type: research

Design and performance analysis of mid-infrared broadband thermally tunable metamaterial absorption device based on the phase-change effect
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00657G, PaperTianquan Feng, Chenyu Gong, Shiri Liang, Zao Yi, Yuxuan Yi, Can Ma We propose a structurally simple, innovative, and multifunctional mid-infrared broadband thermally tunable metamaterial absorption device. The absorption device consists of a three-layer structure, from bottom to top: Ti substrate, SiO2... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 23, 2024 Category: Chemistry Authors: Tianquan Feng Source Type: research

ALP-Responsive, Anionic Iridium complex for Specific Recognition of Osteosarcoma Cells
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00568F, PaperShuang Shen, Shu Nong, Xianpeng Zhang, Jiaqi Song, Caiting Meng, Xinling Liu, Liang Shao, Guanying Li, Li Xu Poor cellular permeability greatly hampers the utilization of anionic Ir(III) complexes, though efficiently emissive and remarkably stable, in cell-based diagnosis. To overcome this barrier, we present the development of an... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 23, 2024 Category: Chemistry Authors: Shuang Shen Source Type: research

Synthesis of NiMn2O4/PANI Nanosized Composite with Increased Specific Capacitance for Energy Storage Application
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00722K, PaperMuhammad Abdullah, Syed Imran Abbas Shah, Karam Jabbour, Peter John, Muhammad Fahad Ehsan, Abdulnasser M. Karami, Muhammad Naeem Ashiq, Suleyman I. Allakhverdiev Polyaniline (PANI) stands out as a highly promising conducting polymer with potential for advanced utilization in high-performance pseudocapacitors. Therefore, there exists a pressing need to bolster structural durability of PANI,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 23, 2024 Category: Chemistry Authors: Muhammad Abdullah Source Type: research

What triggers the coupling of proton transfer and electron transfer at the active site of nitrogenase?
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00474D, PaperIan Dance In nitrogenase electron transfer triggers proton transfer to the active site by increasing the negative charge on S atoms. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 23, 2024 Category: Chemistry Authors: Ian Dance Source Type: research

Interfacial charge transfer in sheet Ni2P-FePx heterojunction to promote the study of electrocatalytic oxygen evolution
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00054D, PaperQiangqiang Wang, Xuejing Liu, Xiang Ren, Xu Sun, Xuan Kuang, Dan Wu, Qin Wei The substantial expense associated with catalysts significantly hampers the progress of electrolytic water-based hydrogen production technology. There is an urgent need to find non-precious metal catalysts that are both cost-effective... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 23, 2024 Category: Chemistry Authors: Qiangqiang Wang Source Type: research

Dual emitting CsPbBr3/Eu-BDC composite as a ratiometric photoluminescent turn on probe for aliphatic amine sensing
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00222A, PaperShahnaz Ahmed, Swapan Kumar Dolui The impressive photoluminescence properties of all inorganic cesium lead halide perovskite quantum dots (PeQDs) make them highly intriguing for fluorescence chemosensor applications. Herein, a ratiometric dual emitting perovskite based sensor... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 23, 2024 Category: Chemistry Authors: Shahnaz Ahmed Source Type: research

N^N^C-Cyclometalated rhodium(III) complexes with isomeric pyrimidine-based ligands: unveiling the impact of isomerism on structural motifs, luminescence and cytotoxicity
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00824C, PaperSofia Vorobyeva, Sof ’ya Bautina, Nikita Shekhovtsov, Elena B Nikolaenkova, Taisiya Sergeevna Sukhikh, Yuliya Golubeva, Lyubov Klyushova, Viktor P Krivopalov, Marianna I Rakhmanova, Christophe Gourlaouen, Mark B Bushuev The impact of isomerism of pyrimidine-based ligands and their rhodium(III) complexes with regard to their structures and properties was investigated. Two isomeric ligands, 4-(3,5-dimethyl-1H-pyrazol-1-yl)-2,5-diphenylpyrimidine (HL2,5) and 4-(3,5-dimethyl-1H-pyrazol-1-yl)-2,6-diphenylpyrimidine (HL2,6), were synthesized.... The content...
Source: RSC - Dalton Trans. latest articles - April 23, 2024 Category: Chemistry Authors: Sofia Vorobyeva Source Type: research

Quantification of the thermodynamic effects of the low-spin – high-spin interaction in molecular crystals of a mononuclear iron(II) spin crossover complex
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00613E, PaperJuliusz Wolny, Konstantin Gr öpl, Jonathan Kiehl, Eva Rentschler, Volker Schünemann A method is proposed to estimate the energetic and entropic effects of spins of neighbouring molecules on the spin transition of a mononuclear spin crossover (SCO) complex in a molecular... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 23, 2024 Category: Chemistry Authors: Juliusz Wolny Source Type: research

Bidentate boron Lewis acids: synthesis by tin boron exchange reaction and host –guest complex formation
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.J. Louis Beckmann, Beate Neumann, Hans-Georg Stammler, Jan-Hendrik Lamm, Norbert W. Mitzel Three bidentate Lewis acids with different substituents were synthesized and their complexation with pyridine, pyrimidine and TMEDA as neutral guest molecules has been studied by NMR and XRD experiments. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 22, 2024 Category: Chemistry Authors: J. Louis Beckmann Source Type: research

Crystal structure of KMnPO4F with short and long range order inside the layered magnetic system
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00878B, PaperOlga Vsevolodovna Yakubovich, Larisa Victorovna Shvanskaya, Galina Kiriukhina, Sergey Vladimirovich Simonov, Anatoly Volkov, Olga Dimitrova, Vladimir V. Korolev, Yevgeny Ovchenkov, Alexander Vasiliev Potassium manganese fluoride phosphate, KMnPO4F, has been obtained through mild hydrothermal synthesis and characterized by scanning electron microscopy, microprobe analysis and X-ray diffraction. The compound possesses an orthorhombic symmetry and... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 22, 2024 Category: Chemistry Authors: Olga Vsevolodovna Yakubovich Source Type: research

Magneto-structural correlation in lanthanide luminescent [2.2]Paracyclophane-based Single-Molecule Magnets
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Hadrien Flichot, Annika Sickinger, Jules Brom, Bertrand Lefeuvre, Vincent Dorcet, Thierry Guizouarn, Olivier Cador, Boris Le Guennic, laurent.micouin@u-paris.fr laurent.micouin@u-paris.fr, Olivier Maury, erica.benedetti@u-paris.fr erica.benedetti@u-paris.fr, Fabrice Pointillart The association of lanthanide ions and paracyclophane derivatives is yet very scarce in the literature. Elaboration of five coordination lanthanide complexes involving the 1,4(1,4)-dibenzenacyclohexaphane-12,43-diylbis(diphenylphosphine oxide) ligand (L) ...
Source: RSC - Dalton Trans. latest articles - April 22, 2024 Category: Chemistry Authors: Hadrien Flichot Source Type: research

68 Ga labeled EphA2-targeted cyclic peptide: a novel positron imaging tracer for triple-negative breast cancer?
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00837E, PaperBin Qu, Xianjun Li, Yuze Ma, Yanzhi Wang, Yeming Han, Guihua Hou, Feng Gao The cyclic peptide SD01 was successfully prepared. Gallium-68 (68Ga) labeled-DOTA-SD01 could be used for micro PET/CT imaging of EphA2 positive TNBC tumors as a novel PET imaging agent. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 22, 2024 Category: Chemistry Authors: Bin Qu Source Type: research

Synthesis of tricyclic 1,4-dihydro-1,4-phosphagermines – trying to establish molecular fencing of reactive centers
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00895B, PaperMridhul. R. K. Ramachandran, Surendar Karwasara, Hui Zhu, Gregor Schnakenburg, Rainer Streubel Novel 1,4-dihydro-1,4-phosphagermines (A) have been synthesised bearing small N-alkyl substituents, but the N-Mes substituent led finally to a pentacyclic P,Ge-heterocycle (B); the latter was rationalized using DFT theoretical calculations. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 22, 2024 Category: Chemistry Authors: Mridhul. R. K. Ramachandran Source Type: research