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Chromium Iodate: Structure and Origin of Optical Second Harmonic Generation
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00470A, PaperYang Chi, Mei-Ling Xin Iodate crystal materials are one of the important candidates for mid-infrared nonlinear optical (NLO) crystals. Almost all the structures and NLO properties of monometallic iodates have been studied, except for... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 22, 2024 Category: Chemistry Authors: Yang Chi Source Type: research

A multi-functional nano-platform based on LiGa4.99O8:Cr0.01/IrO2 with near infrared-persistent luminescence, “afterglow” photodynamic and photo-thermal functions
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00240G, PaperXiangyu Liu, Rujie Xi, Yanfang Hu, Yong Wang, Abdukader Abdukayum LGO:Cr/IrO2 shows NIR-persistent luminescence, a PTT effect under NIR irradiation, and a continuous “afterglow” PDT effect without the need forin situ excitation owing to persistent energy transfer from LGO:Cr to the IrO2, in turn generating ROS. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 22, 2024 Category: Chemistry Authors: Xiangyu Liu Source Type: research

Coordination of Copper within a Crystalline Carbon Nitride and its Catalytic Reduction of CO2
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Magnus Pauly, Ethan White, Mawuli Deegbey, Emmanuel Adu Fosu, Landon Keller, Scott McGuigan, Golnaz Dianat, Eric Gabilondo, Jian Cheng Wong, Corban G. E. Murphey, Bo Shang, Hailiang Wang, James F. Cahoon, Renato Neiva Sampaio, Yosuke Kanai, Gregory N. Parsons, Elena Jakubikova, Paul Maggard Inherently disordered structures of carbon nitrides have hindered an atomic level tunability and understanding of their catalytic reactivity. Starting from a crystalline carbon nitride, poly(triazine imide) or PTI, the coordination... The con...
Source: RSC - Dalton Trans. latest articles - March 22, 2024 Category: Chemistry Authors: Magnus Pauly Source Type: research

Exploring the phototoxicity of GSH-resistant 2-(5,6-dichloro-1H-benzo[d]imidazol-2-yl)quinoline-based Ir(III)-PTA complexes in MDA-MB-231 cancer cells
Dalton Trans., 2024, Advance Article DOI: 10.1039/D3DT04361D, PaperUtpal Das, Priyankar Paira A GSH-resistant 2-(5,6-dichloro-1H-benzo[d]imidazol-2-yl)quinoline-based Ir(III)-PTA complex has been developed for selective phototherapy against TNBC cells. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 21, 2024 Category: Chemistry Authors: Utpal Das Source Type: research

Barium phosphidoboranes and related calcium complexes
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Gabriel Dunes, Peter M. Chapple, Samia Kahlal, Thierry Roisnel, Jean-Francois Carpentier, Jean-Yves Saillard , Yann Sarazin The attempted synthesis of [{Carb}BaPPh2] (1) showed this barium-phosphide and its thf adducts1.thf and1.(thf)2 to be unstable in solution. Our strategy to circumvent the fragility of these compounds... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 21, 2024 Category: Chemistry Authors: Gabriel Dunes Source Type: research

Expanding dimensionality of bis(tetrazolyl)alkane-based Fe(II) coordination polymers by an application of dinitrile coligands
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00462K, PaperAleksandra To łoczko, Marcin Kaźmierczak, Maria Książek, Marek Damian Weselski, Joachim Kusz, Robert Bronisz Reactions between 1,2-di(tetrazol-2-yl)ethane (ebtz), 1,6-di(tetrazol-2-yl)hexane (hbtz) or 1,1 ’-di(tetrazol-1-yl)methane (1ditz) and Fe(BF4)2 in presence of adiponitrile (AND), glutaronitrile (GLN) or suberonitrile (SUN) resulted in formation of coordination polymers [Fe( μ-ebtz)2( μ-ADN)](BF4)2 (1), [Fe( μ-hbtz)2( μ-ADN)](BF4)2... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 21, 2024 Category: Chemistry Authors: Aleksandra To łoczko Source Type: research

Efficient electrochemical reduction of CO2 to CO in flow cell device by a pristine Cu5tz6-cluster-based metal-organic framework
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00189C, PaperZijing Li, Yingtong Lv, Haoliang Huang, Zi-Jian Li, Tao Li, Linjuan Zhang, Jian-Qiang Wang The electrochemical reduction of CO2 to CO is a powerful approach to achieve carbon neutrality. Herein, we report a five-nuclear copper cluster-based metal –azolate framework CuTz-1 as an electrocatalyst for the... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 21, 2024 Category: Chemistry Authors: Zijing Li Source Type: research

Structural insight and in silico prediction of the pharmacokinetic parameters and toxicity of alkaline earth metal compounds strontium and barium with the non-steroidal anti-inflammatory drug nimesulide
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00446A, CommunicationMa łgorzata Rybczyńska, Artur Sikorski In the crystals of alkaline earth metal compounds strontium and barium with the non-steroidal anti-inflammatory drug nimesulide, the metal ions have different coordination spheres, TCTPR-9 and TCTPR-10, respectively. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 21, 2024 Category: Chemistry Authors: Ma łgorzata Rybczyńska Source Type: research

Selective fluoride sensing by a novel series of lanthanide-based one-dimensional coordination polymers through intramolecular proton transfer
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Arun Kumar Bar, Vaibhav Singh, Lakshmi Thachanadan Suresh, Jean-Pascal Sutter A novel series of one-dimensional coordination polymers (CPs) is achieved via a facile one-pot synthetic strategy employing the nitrate salts of trivalent lanthanides, a pentadentate chelating ligand, and triphenylphosphine oxide... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 21, 2024 Category: Chemistry Authors: Arun Kumar Bar Source Type: research

Construction of zirconium/hafnium-oxo clusters based on a new protection-calix[8]arene
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00169A, CommunicationFei-Fei Wang, Baoshan Hou A new series of zirconium/hafnium-oxo clusters based on protection-calix[8]arene were successfully synthesized and have been used as an example to study the effect of different metal centers on iodine adsorption. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 21, 2024 Category: Chemistry Authors: Fei-Fei Wang Source Type: research

Bright white light emission from lanthanide oxide LaGdO3 for LED lighting by the Bi3+ to Eu3+ energy transfer
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00532E, PaperZhangyan Yang, Zeyu Lyu, Dashuai Sun, Sida Shen, Shuai Wei, Zheng Lu, Zhuihao Huang, Mingrui He, Hongpeng You Phosphors with intrinsic white light emission is of great potential in constructing high-quality white LED (WLED). In this work, we propose to achieve white light emission by utilizing the energy... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 21, 2024 Category: Chemistry Authors: Zhangyan Yang Source Type: research

Circularly polarized blue fluorescence based on chiral heteroleptic six-coordinate bis-pyrazolonate-Zn2+ complexes
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00086B, PaperJiaxiang Liu, Yuzhen Zhao, Zhe Zhang, Manni Li, Wenqi Song, Wentao Li, Zongcheng Miao Applying molecular design to chiral organo-Zn2+ complexes, a new pair of chiral heterolepticbis-pyrazolonate-Zn2+ enantiomers [Zn(PMBP)2(1R,2R-Chxn)] (R,R-Zn2+;HPMBP = 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone and1R,2R-Chxn = (1R,2R)-cyclohexane-1,2-diamine) and [Zn(PMBP)2(1S,2S-Chxn)] (S,S-Zn2+;1S,2S-Chxn = (1S,2S)-cyclohexane-1,2-diamine)... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 21, 2024 Category: Chemistry Authors: Jiaxiang Liu Source Type: research

Resilience of the Aurivillius structure upon La and Cr doping in a Bi5Ti3FeO15 multiferroic
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00159A, PaperOmar Alejandro Salas, Yohannes W. Getahun, H. Cein Mandujano, Felicia Manciu, Mariana Castellanos, Jorge Lopez, Raquel Garza Hern ández, Volodymir B. Buturlim, Krzysztof Gofryk, Dhanpal Bairwa, Suja Elizabeth, Harikrishnan S. Nair We have studied the influence of La and Cr doping on the crystal structure and magnetism of Aurivillius multiferroic Bi5Ti3FeO15 and demonstrated the resilience of this structure type. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of C...
Source: RSC - Dalton Trans. latest articles - March 20, 2024 Category: Chemistry Authors: Omar Alejandro Salas Source Type: research

Third-order nonlinear optical properties of highly electron deficient, nonplanar push –pull porphyrins: β-nitro-hexa-substituted porphyrins bearing bromo, phenyl, and phenylethynyl groups
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00045E, PaperRenu K. Rohal, Dipanjan Banerjee, Nivedita Rana, Venugopal Rao Soma, Muniappan Sankar β-Heptasubstituted porphyrins were synthesized and their third-order nonlinear optical (NLO) properties were explored. The existence of enhanced polarization and intramolecular charge transfer are held responsible for the observed strong NLO responses. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 20, 2024 Category: Chemistry Authors: Renu K. Rohal Source Type: research

Heterometallic MIL-125(Ti –Al) frameworks for electrochemical determination of ascorbic acid, dopamine and uric acid
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00021H, PaperAi-Xuan Yu, Xiao-Huan Liang, Cun-Di Hao, Xian-Zheng Hu, Jia-Jia Li, Xiang-Jie Bo, Dong-Ying Du, Zhong-Min Su The detection of ascorbic acid (AA), dopamine (DA), and uric acid (UA) is not only of great significance in the areas of biomedicine and neurochemistry but also helpful in disease diagnosis and pathology research. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 20, 2024 Category: Chemistry Authors: Ai-Xuan Yu Source Type: research