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Reduced Polyoxometalate-Encapsulated Organo Cobalt modified phosphate Framework for improving photocatalytic reduction CO2
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00812J, CommunicationYinhua Zhu, Pinfang Yan, Ling Tong Xu, Zeyu Du, Hua Mei, Yan Xu The photoconversion of CO2 into energy carriers by visible light is critical for preserving the natural carbon balance and fostering sustainability. Exploring high-performance and low-cost photocatalysts is an important key... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 11, 2024 Category: Chemistry Authors: Yinhua Zhu Source Type: research

Boron bis-(4-methylbenzoxazol-2-yl)-methanide complexes
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Xiaobai Wang, Franziska R üttger, Johannes Kretsch, Anne Kreyenschmidt, Regine Herbst-Irmer, Dietmar Stalke Boron compounds attract the attention of chemists because of their unique catalytic properties and their potential wider materials applications. Although the Group 13 metal compounds, which are based on bis-(benzoxazol-2-yl)-methane... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 11, 2024 Category: Chemistry Authors: Xiaobai Wang Source Type: research

M –Ge–Si thermolytic molecular precursors and models for germanium-doped transition metal sites on silica
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00644E, PaperJames P. Dombrowski, Vidmantas Kalendra, Micah S. Ziegler, K. V. Lakshmi, Alexis T. Bell, T. Don Tilley The new siloxy-germoxy ligand HOGe[OSi(OtBu)3]3 generates Mn-, Fe-, and Cr-containing precursors suitable forthermolytic molecular precursor routes to quaternary oxides. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 11, 2024 Category: Chemistry Authors: James P. Dombrowski Source Type: research

Exploring the impact of various reducing agents on Cu nanocluster synthesis
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Sourav Biswas, Yuichi Negishi The synthesis of copper (Cu) nanoclusters (NCs) has experienced significant advancements in recent years. Despite the exploration of metal NCs dating back almost two decades, challenges specific to Cu NC... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 11, 2024 Category: Chemistry Authors: Sourav Biswas Source Type: research

Antiferromagnetism and insulator-metal transition of alkali metal-loaded sodalite
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00562G, PaperTakehito Nakano, Kunihiro Watanabe, Atsufumi Hanazawa, Yuko Ishida, Kenji Tanibe, Ryosuke Sakon Alkali metal clusters with a single unpaired s-electron can be arranged three-dimensionally in a sodalite crystal by loading the guest alkali atoms. Na, K, and K-Rb alloy clusters are known... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 11, 2024 Category: Chemistry Authors: Takehito Nakano Source Type: research

Discovery of two predictable (3, 18)-connected topologies based on Wells-Dawson type cage for the design of porous metal phosphonocarboxylate frameworks
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00590B, PaperWenyan Dan, Zhenxia Chen, Yun Ling, Yu Jia, Yongtai Yang, Xiaofeng Liu, Mingli Deng Highly connected molecular building blocks (MBBs) have been demonstrated to play a crucial role in reticular chemistry, particularly in predicting the topologies of metal-organic frameworks. Metal phosphonate clusters exhibit considerable... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 11, 2024 Category: Chemistry Authors: Wenyan Dan Source Type: research

Self-reducing Precursors for Aluminium Metal Thin Films: Evaluation of Stable Aluminium Hydrides for Vapor Phase Aluminium Deposition
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Niklas Huster, Rita Mullins, Michael Nolan, Anjana Devi Thin films of Al as interconnect materials and those of AlN as wide bandgap semiconductor and piezoelectric material are of great interest for microelectronic applications. For the fabrication of these... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 11, 2024 Category: Chemistry Authors: Niklas Huster Source Type: research

Facile synthesis of a three-dimensional Ln-MOF@FCNT composite for the fabrication of a symmetric supercapacitor device with ultra-high energy density: overcoming the energy storage barrier
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00136B, PaperMohammad Yasir Khan, Ahmad Husain, Dhiraj K. Mahajan, Mohammad Muaz, M. Shahid, Mohd Zeeshan, Farasha Sama, Sharique Ahmad A novel lanthanide MOF-FCNT composite is fabricated and employed as a symmetric supercapacitor (SSC) device with the highest energy density reported so far. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 10, 2024 Category: Chemistry Authors: Mohammad Yasir Khan Source Type: research

Two-dimensional spin-crossover coordination polymers based on the 1,1,2,2-tetra(pyridin-4-yl)ethene ligand
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00204K, PaperMeng-Ling Wu, Yan-Cong Chen, Ze-Yu Ruan, Zhao-Ping Ni, Si-Guo Wu, Ming-Liang Tong Spin-crossover behaviors and guest effects were investigated in three Fe(II) two-dimensional coordination polymers based on the 1,1,2,2-tetra(pyridin-4-yl)ethene ligand. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 10, 2024 Category: Chemistry Authors: Meng-Ling Wu Source Type: research

A density functional theory analysis of the C –H activation reactivity of iron(IV)-oxo complexes with an ‘O’ substituted tetramethylcyclam macrocycle
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00063C, PaperLovleen Kaur, Debasish Mandal As equatorial nitrogen atoms are replaced by oxygen atoms, [Fe(IV)OTMC] complexes become more reactive in C –H activation. The reaction follows exchange-enhanced mediated two-state reactivity patterns. Reactivity is dominated by electron acceptor orbital energy, which decreases with O-enrichment. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 10, 2024 Category: Chemistry Authors: Lovleen Kaur Source Type: research

Protic- or anionic-NHCs with a classical-NHC in a single [Ru(CNC)(PPh3)2Cl]Cl pincer complex: direct comparison of structure & electronic properties and heterolytic H2 splitting
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00623B, CommunicationNavdeep Srivastava, Amrendra K. Singh A set of pincer complexes1,2 and2 ’ having a protic- or anionic-NHC and a classical-NHC in the same molecule are reported. Cooperation between metal and ligand in2' is indicated by the heterolytic splitting of H2 to give the Ru-hydride complex3. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 10, 2024 Category: Chemistry Authors: Navdeep Srivastava Source Type: research

Ionic conduction in ammonia functionalised closo-dodecaborates MB12H11NH3 (M = Li and Na)
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00801D, PaperSteffen R. H. Jensen, Mathias J ørgensen, Thi Phuong Thao Nguyen, Greg Nolan, Craig Buckley, Torben Rene Jensen, Mark Paskevicius Metal hydroborates and their derivatives have been receiving attention as potential solid-state ion conductors for battery applications owing to their impressive electrochemical and mechanical characteristics. However, to date only a... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 10, 2024 Category: Chemistry Authors: Steffen R. H. Jensen Source Type: research

Exploring the Effect of Pendent Amine Group Poised Over the Secondary Coordination Sphere of a Cobalt Complex on the Electrocatalytic Hydrogen Evolution Reaction
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00009A, PaperAfsar Ali, Rajaneesh Kumar Verma, Avijit Das, Sayantan Paria A CoIII complex (2) of a bispyridine-dioxime ligand (H2LNMe2) containing a tertiary amine group at the proximity of the Co center has been synthesized and characterized. One of the oxime... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 10, 2024 Category: Chemistry Authors: Afsar Ali Source Type: research

Multifunctional Chemical Anchor Achieves Boosted Fill Factor and Mitigated Ion Migration of High-Stability Perovskite Solar Cells
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00076E, PaperYiqing Chen, Jun Han, Wei Huang, Dandan Luo, Fei Wang, Chong Jia, Xinhua Li To date, it is urgent to produce perovskite films with comparative or even better morphologies in an open-air environment. Unfortunately, a substantial number of trap state on the grain surface,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 10, 2024 Category: Chemistry Authors: Yiqing Chen Source Type: research

Effective oxygen activation on polyoxometalate-based hybrids for epoxidation of alkenes
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00530A, CommunicationXue Bai, Maochun Zhu, Yifei Liu, Min Xing, Xiaoying Ji, Ange Zhang, Yanli Yang, Ying Lu, Shuxia Liu The synergistic effect of transition metal (TM) centers and POMs anions in the title compound promotes its catalytic performance in the oxidation of styrene with O2 as the oxidant. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 10, 2024 Category: Chemistry Authors: Xue Bai Source Type: research