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Heterometallic MIL-125(Ti –Al) frameworks for electrochemical determination of ascorbic acid, dopamine and uric acid
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00021H, PaperAi-Xuan Yu, Xiao-Huan Liang, Cun-Di Hao, Xian-Zheng Hu, Jia-Jia Li, Xiang-Jie Bo, Dong-Ying Du, Zhong-Min Su The detection of ascorbic acid (AA), dopamine (DA), and uric acid (UA) is not only of great significance in the areas of biomedicine and neurochemistry but also helpful in disease diagnosis and pathology research. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 20, 2024 Category: Chemistry Authors: Ai-Xuan Yu Source Type: research

In-situ electrochemically activated V2O3@MXene cathode for super high-rate and long-life Zn-ion battery
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00488D, PaperYunlong Duan, Zhi Geng, Daohong Zhang, Qiufan Wang The development of a high specific capacity and stable vanadium based cathode material is very attractive for aqueous zinc-ion batteries (ZIBs). Herein, an in-situ electrochemically oxidated cathode has been fabricated... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 20, 2024 Category: Chemistry Authors: Yunlong Duan Source Type: research

From Alkaline Earth to Coinage Metal Carboranyls
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Michael Hill, Kyle G. Pearce, Louis Morris, Thomas Robinson, Andrew Lee Johnson, Mary F Mahon The β-diketiminato calcium and magnesium complexes, [(BDI)MgnBu] and [(BDI)CaH] (BDI = HC{C(Me)NDipp}2; Dipp = 2,6-di-isopropylphenyl), react with ortho-carborane (o-C2B10H12¬) to provide the respective [(BDI)Ae(o-C2B10H11)] (Ae = Mg or Ca) complexes.... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 20, 2024 Category: Chemistry Authors: Michael Hill Source Type: research

The luminescent semiconductor Pb7I6(CN2)4
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Albert T. Schwarz, Markus Str öbele, Carl P. Romao, David Enseling, Thomas Jüstel, H.-Jürgen Meyer The compound Pb7I6(CN2)4 was obtained from a solid-state reaction of PbI2 and PbCN2. Experimental studies and calculations feature this material as a semiconducting luminophore. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 20, 2024 Category: Chemistry Authors: Albert T. Schwarz Source Type: research

Unusual nucleophilic reactivity of a dithiolene-based N-heterocyclic silane
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Phuong M. Tran, Yuzhong Wang, Mitchell E. Lahm, Pingrong Wei, Henry F. Schaefer, Gregory H. Robinson Dithiolene-based N-heterocyclic silane demonstrates unusual dual nucleophilic reactivity toward boron halides. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 20, 2024 Category: Chemistry Authors: Phuong M. Tran Source Type: research

Designing a hybrid nanomaterial based on Cr-containing polyoxometalate and graphene oxide as an electrocatalyst for the hydrogen evolution reaction
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00320A, PaperMaryam Khalaji-Verjani, Majid Masteri-Farahani A new polyoxometalate (POM)-based hybrid nanomaterial (denoted as PMo11-Cr-mGO) was designed via covalent interaction between Cr(acac)3 complex and [PMo11O39]7- followed by immobilization on the surface of modified graphene oxide (mGO).... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 20, 2024 Category: Chemistry Authors: Maryam Khalaji-Verjani Source Type: research

Effect of Porphyrin Ligands on the Catalytic CH4 Oxidation Activity of Monocationic μ-Nitrido-Bridged Iron Porphyrinoid Dimers by Using H2O2 as An Oxidant
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Yasuyuki Yamada, Yusuke Miwa, Yuka Toyoda, Yoshiki Uno, Quan Manh Phung, Kentaro Tanaka The μ-nitrido-bridged iron phthalocyanine homodimer is a potent molecule-based CH4 oxidation catalyst that can effectively oxidize chemically stable CH4 under mild reaction conditions in an acidic aqueous solution including an... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 20, 2024 Category: Chemistry Authors: Yasuyuki Yamada Source Type: research

Fe3O4 Nanoparticles entrapped in the inner Surfaces of N-doped Carbon microtubes with enhanced biomimetic activity
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D3DT04310J, PaperHuanhuan Li, Ziqi Jin, Na Lu, Jianmin Pan, Jingli Xu, Xue-Bo Yin, Min Zhang Tubular structured composites have attracted great interest in catalysis research owing to their void-confinement effects. In this work, we synthesized a pair of hollow N-doped carbon microtubes (NCMTs) with Fe3O4... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 20, 2024 Category: Chemistry Authors: Huanhuan Li Source Type: research

Exploring the electronic and steric effects on the dimerization of intramolecular Frustrated Lewis Pairs: A comparison between aminoboranes and aminoalanes
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D3DT04274J, PaperC ésar Barrales-Martínez, Claudio Illanes-Solis, Rocío Durán, Julio Caballero The dimerization of intramolecular aminoborane and aminoalane Frustrated Lewis Pairs was investigated using Density Functional Theory. We systematically varied the substituents to gradually increase their bulkiness, including H, CH3,t-Bu,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 19, 2024 Category: Chemistry Authors: C ésar Barrales-Martínez Source Type: research

Exploring the carbonic anhydrase-mimetic [(PMDTA)2ZnII2(OH −)2]2+ for nitric oxide monooxygenation
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00407H, CommunicationSandip Das, Pankaj Kumar The reaction of ZnII-hydroxide (1) with NO showed the generation ZnII–nitrito complex (3) with H2 gas evolutionvia a proposed ZnII-nitrous acid intermediate. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 19, 2024 Category: Chemistry Authors: Sandip Das Source Type: research

Mononuclear Fe(III) complexes with 2,4-dichloro-6-((quinoline-8-ylimino)methyl)phenolate: synthesis, structure, and magnetic behavior
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Ah Rim Jeong, Si Ra Park, Jong Won Shin, Jihyun Kim, Ryuya Tokunaga, Shinya Hayami, Kil Sik Min Three Fe(III)-based coordination complexes [Fe(dqmp)2](NO3) •H2O (1), [Fe(dqmp)2](BF4)•2CH3COCH3 (2), and [Fe(dqmp)2](ClO4) (3) were synthesized from Fe(NO3)3·9H2O/Fe(ClO4)3·xH2O, NaBF4, and 2,4-dichloro-6-((quinoline-8-ylimino)methyl)phenol (Hdqmp) in methanol/acetone and characterized. The structures of complexes 1–3 were determined... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 19, 2024 Category: Chemistry Authors: Ah Rim Jeong Source Type: research

A microporous Bismuth-based MOF for efficient separation of acetylene from carbon dioxide
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00246F, PaperTong-Liang Hu, Bo Xing, Shan-Qing Yang, Qiang Zhang Separation of acetylene from carbon dioxide is challenging due to almost identical molecular sizes and volatilities. Metal-organic frameworks (MOFs) in general are strong candidates for the separation of gases owing... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 19, 2024 Category: Chemistry Authors: Tong-Liang Hu Source Type: research

White light-emitting ZnO:Dy3+ nanophosphors: delving into the spectroscopic parameters via Judd –Ofelt analysis
Dalton Trans., 2024, Advance Article DOI: 10.1039/D3DT04070D, PaperRajendran Raji, Gopalakrishnan Jyothi, Sajesh Sasidharan, Kunnel Gopalan Gopchandran The synthesis of ribbon-shaped cool white-emitting ZnO:xDy3+ nanophosphors and the quantitative evaluation of their radiative parameters using Judd –Ofelt analysis. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 18, 2024 Category: Chemistry Authors: Rajendran Raji Source Type: research

Controlling the europium oxidation state in diopside through flux concentration
Dalton Trans., 2024, Advance Article DOI: 10.1039/D3DT04160C, PaperN. G órecka, T. Leśniewski, S. Mahlik, M. Łapiński, Y.-T. Tsai, A. Bielicka-Giełdoń, K. Szczodrowski The reduction of lanthanides (Ln3+) incorporated into alkali earth sites in a matrix,, requires the creation of electron donating defects,e.g., and elimination of charge compensation defects,e.g. V ′′Me, from the vicinity of the. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 18, 2024 Category: Chemistry Authors: N. G órecka Source Type: research

Luminescence properties and Judd –Ofelt analysis of Tb3+ doped Sr2YTaO6 double perovskite phosphors for white LED applications
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00302K, PaperLi Wang, Yuhang Zhang, Duan Gao, Xuezhu Sha, Xin Chen, Yanqiu Zhang, Jinsu Zhang, Xizhen Zhang, Yongze Cao, Yichao Wang, Xiangping Li, Sai Xu, Hongquan Yu, Baojiu Chen A WLED prototype was assembled using a 310 nm LED chip combined with a prepared green SYT: Tb3+ phosphor and the other two commercial blue and red phosphors. The obtained warm white light exhibits good chromaticity coordinates and high color rendering index. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal So...
Source: RSC - Dalton Trans. latest articles - March 18, 2024 Category: Chemistry Authors: Li Wang Source Type: research