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New iodate fluoride Rb2Ce(IO3)5F with nonlinear optical properties
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00431K, PaperOksana Grigoreva, Tatiana Shatalova, Alexey N. Kuznetsov, Peter S Berdonosov, Sergey Stefanovich, Konstantin Lyssenko, Valery Dolgikh New noncentrosymmetric cerium (IV) iodate fluoride Rb2Ce(IO3)5F was prepared employing hydrothermal technique. The compound crystallizes in Cmc21 space group (#36) with cell parameters a = 11.1518(6) Å, b = 8.1187(4)... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 1, 2024 Category: Chemistry Authors: Oksana Grigoreva Source Type: research

Field induced slow magnetic relaxation in linear homotrinuclear manganese heterospin coordination compound with S = 7/2 ground state and intriguing spin density distribution
We report a first example of field-induced (HDC = 2500 Oe) slow magnetic relaxation in the homotrinuclear linear heterospin manganese coordination compound with S = 7/2 ground state, based on... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 1, 2024 Category: Chemistry Authors: Igor N Shcherbakov Source Type: research

Spin crossover in {Fe(pyrazine)[M(CN)4]} (M = Ni, Pt) thin films assembled on fused silica substrates
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Fayan Lai, G ábor Molnár, Saioa Cobo, Azzedine Bousseksou Thin films with thicknesses in the range between ca. 10 - 50 nm of the spin crossover (SCO) compound {Fe(pyrazine)[ µ4-M(CN)4]} (M=Ni, Pt) have been deposited on fused silica substrates using... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 1, 2024 Category: Chemistry Authors: Fayan Lai Source Type: research

Frustrated Lewis pair adducts of alkynyl-capped tetrelenes
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00795F, PaperAbhishek V Muralidharan, Brandon L. Frenette, Julius Wicke, Alvaro A. Oma ña, Michael J Ferguson, Eric Rivard The frustrated Lewis pair (FLP) adducts PB{ECl2} (PB =iPr2P(C6H4)BCy2; Cy = cyclohexyl; E = Si, Ge) were used to access a bis(alkynyl)-functionalized silylene and a germylene; the goal behind... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 1, 2024 Category: Chemistry Authors: Abhishek V Muralidharan Source Type: research

Crystal structure and properties of perovskite-type rubidium niobate, a high-pressure phase of RbNbO3
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Ayako Yamamoto, Kimitoshi Murase, Takeru Sato, Kazumasa Sugiyama, Toru Kawamata, Yoshiyuki Inaguma, Jun-ichi Yamaura, Kazuki Shitara, Rie Yokoi, Hiroki Moriwake We synthesized a perovskite-type RbNbO3 at 4 GPa and 1,173 K from non-perovskite RbNbO3 and investigated its crystal structure and properties to offer ferroelectric material design. Single-crystal X-ray diffraction analysis... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 1, 2024 Category: Chemistry Authors: Ayako Yamamoto Source Type: research

Stable N-doped NiMoO4/NiO2 electrocatalyst for efficient oxygen evolution reaction
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D3DT04034H, PaperZhengfang Hou, fangyuan Fan, Zhe Wang, Yeshuang Du Recently, there has been a significant increasing interest in the research of highly active and stable transition metal-based electrocatalysts for oxygen evolution reaction (OER). Non-noble metals nanocatalysts with excellent inherent... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 29, 2024 Category: Chemistry Authors: Zhengfang Hou Source Type: research

1,1 ′-Bis-(diphenylphosphino)ferrocene appended d8- and d10-configuration based thiosquarates: the molecular and electronic configurational insights into their sensitization and co-sensitization properties for dye sensitized solar cells
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00151F, PaperAparna Kushwaha, Devyani Srivastava, Om Prakash, Gabriele Kociok-K öhn, Suresh W. Gosavi, Ratna Chauhan, Mohd. Muddassir, Abhinav Kumar New dppf appended d8- and d10-configuration based thiosquarates synthesized and used as sensitizers and co-sensitizers with N719 dye in dye sensitized solar cells. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 29, 2024 Category: Chemistry Authors: Aparna Kushwaha Source Type: research

Room temperature spin crossover properties in a series of mixed-anion Fe(NH2trz)3(BF4)2 −x(SiF6)x/2 complexes
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Xinyu Yang, Alejandro Enriquez-Cabrera, Kane Jacob, Yannick Coppel, Lionel Salmon, Azzedine Bousseksou A series of mixed-anion Fe(NH2trz)3(BF4)2 −x(SiF6)x/2 complexes presenting abrupt spin crossover behaviour with a narrow hysteresis loop just above room temperature is obtained by coordination reaction or solid –liquid post synthetic modification. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 29, 2024 Category: Chemistry Authors: Xinyu Yang Source Type: research

Interfacial engineering of a multijunctional In2O3/WO3@Ti4N3Tx S-scheme photocatalyst with enhanced photoelectrochemical properties
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Antony Okinyi Onjwaya, Majahekupheleni Malati, Jane Catherine Ngila, Langelihle Nsikayezwe Dlamini Achieving high photoelectrochemical conversion efficiency requires the logical layout of a composite photocatalyst with optimal charge separation and transfer with ideal light harvesting capabilities to enhance the photocatalytic performance, and... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 29, 2024 Category: Chemistry Authors: Antony Okinyi Onjwaya Source Type: research

Defluorination of HFCs by a Magnesium Reagent
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Daniel James Sheldon, Joseph Parr, Mark Richard Crimmin Reaction of a series of HFCs with a main group reagent containing a Mg –Mg bond results in defluorination to form the corresponding magnesium fluoride complex. In the case of 1,1,1,2-tetrafluoroethane... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 29, 2024 Category: Chemistry Authors: Daniel James Sheldon Source Type: research

Insertion of fluorine in LiFePO4 electrode material by gas-solid fluorination
In this study, the insertion of fluorine in LiFePO4 was carried under molecular fluorine F2 at different temperatures. The reactivity strongly depends on the applied fluorination temperature leading to very... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 29, 2024 Category: Chemistry Authors: Kevin Lemoine Source Type: research

Synthesis, polymorphism, and shape complementarity-induced co-crystallization of hexanuclear Co(II) clusters capped by a flexible heteroligand shell
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Micha ł Terlecki, Arkadiusz Kornowicz, Kornel Sacharczuk, Iwona Justyniak, Janusz Lewinski Polymorphism and co-crystallization have gradually gained attention as new tools in the development of modern crystalline functional materials. However, the study on the selective self-assembly of metal clusters into multicomponent... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 29, 2024 Category: Chemistry Authors: Micha ł Terlecki Source Type: research

New Type of Tin(IV) complex based Turn-on Fluorescent Chemosensor for Fluoride ion Recognition: Elucidating the Effect of Molecular Structure on Sensing Property
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00461B, PaperAndrew Wu, Patrick C. Hillesheim, Peter N Nelson, Matthias Zeller, Gia M Carignan, Jing Li, Daniel Wooseok Ki A novel type of chemosensor based on tin(IV) complexes incorporating hydroxyquinoline derivatives has been designed and investigated for selectively detecting fluoride ions. Sn(meq)2Cl2 (meq = 2-methyl-8-quinolinol) (complex 1) exhibits a... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 29, 2024 Category: Chemistry Authors: Andrew Wu Source Type: research

N –C QDs coated with a molecularly imprinted polymer as a fluorescent probe for detection of penicillin
Dalton Trans., 2024, Advance Article DOI: 10.1039/D3DT04297A, PaperShan Wang, Zhihui Sun, Xuyang Zhao, Kunhua Li, Yafei Wang, Xijing Zhang The N –C QDs@MIP from wheat straw was synthesized by a gel-sol method and it could be used as a sensor for penicillin. The study paves an avenue to develop highly efficient sensor for the detection of antibiotics. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 29, 2024 Category: Chemistry Authors: Shan Wang Source Type: research

Towards Structurally Versatile Mesoionic N-Heterocyclic Olefin Ligands and their Coordination to Palladium, Gold, and Boron Hydride
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Tisa Ževart, Balazs Pinter, Matic Lozinšek, Damijana Urankar, Ross D Jansen-van Vuuren, Janez Kosmrlj We have developed an efficient and versatile approach to the synthesis of a family of 1,2,3-triazole-based mesoionic N-heterocyclic olefin (mNHO) ligands and investigated their coordination to palladium, gold, and boron... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 29, 2024 Category: Chemistry Authors: Tisa Ževart Source Type: research