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A multi-functional nano-platform based on LiGa4.99O8:Cr0.01/IrO2 with near infrared –persistent luminescence, “afterglow” photodynamic and photo–thermal functions
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00240G, PaperXiangyu Liu, Rujie Xi, Yanfang Hu, Yong Wang, Abdukader Abdukayum Multi-functionalised nano-platforms based on persistent-luminescence nanoparticles (PLNPs) have attracted considerable attention for biomedical applications owing to their absence of background noise and in vivo imaging without the need for in... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 14, 2024 Category: Chemistry Authors: Xiangyu Liu Source Type: research

Optimising the acid –base ratio of Mg–Al layered double oxides to enhance CO2 capture performance: the critical role of calcination conditions
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.D. W. Justin Leung, Katherine R. Laney, Philip Kenyon, Nicholas H. Rees, Jean-Charles Buffet, Chunping Chen, Dermot O'Hare We investigated the impact of calcination conditions of layered double hydroxide on the formation of layered double oxides and its relationship with CO2 capture. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 14, 2024 Category: Chemistry Authors: D. W. Justin Leung Source Type: research

Thermodynamics of the Eu(III) –Mg–SO4–H2O and Eu(III)–Na–SO4–H2O systems. Part I: solubility experiments and the full dissociation Pitzer model
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.P. F. dos Santos, A. Lassin, X. Gaona, K. Garbev, M. Altmaier, B. Mad é A thermodynamic description of complex sulfate systems of relevance for nuclear waste disposal is provided. A full dissociation Pitzer model is derived for the system Eu(III) –Mg/Na–SO4–H2O based on solubility experiments and comprehensive solid phase characterization. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 14, 2024 Category: Chemistry Authors: P. F. dos Santos Source Type: research

Emerging Lead-Free All Inorganic Perovskite Single Crystals K7Bi3X16 (X=Cl, Br) toward Photodetector Application
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D3DT03872F, PaperWenjian Yang, Jingshen Zhang, Hui Xiong, Jing Lan, Songyang Yuan, Mengdi Zhan, Ziyu Tan, Wenzhe Li, Jiandong Fan Lead-free inorganic perovskites have attracted intensive attention in the field of photodetectors owing to their high stability, non-toxicity, and remarkable photoelectric characteristics. Herein, we designed and developed a series of... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 14, 2024 Category: Chemistry Authors: Wenjian Yang Source Type: research

A series of Isostructural Metal-Organic Frameworks for Enhanced Electro-catalytic Oxygen Evolution Reaction
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00210E, PaperPampa Jhariat, Abdul Kareem, Priyanka Kumari, Shafeeq Sarfudeen, Premchand Panda, Senthilkumar Sellappan, Tamas Panda Three new isostructural MOFs (ZnTIA, CoTIA and CdTIA) were synthesized by the solvothermal synthesis of organic linker 5-triazole isophthalic acid (5-TIA) with the transition metals Zn(II), Co(II) and Cd(II) salts... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 13, 2024 Category: Chemistry Authors: Pampa Jhariat Source Type: research

Reversible open-close conformational switching of a nano-size metalloporphyrin dimers triggered by light and temperature
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00223G, PaperSyed Jehanger Shah, Ajitesh Singh, Debabrata Goswami, Masatoshi Ishida , Sankar Prasad Rath The current work demonstrates the reversible control of substantial molecular motion in 'nano-sized' molecules, where two structural isomers can 'open' and 'close' their cavities using light or heat. The isomers... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 13, 2024 Category: Chemistry Authors: Syed Jehanger Shah Source Type: research

Hybridization of layered double hydroxides with functional particles
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00292J, PerspectiveRattanawadee Ploy Wijitwongwan, Soontaree Grace Intasa-ard, Makoto Ogawa The preparation, heterostructure and application of hybrids containing layered double hydroxides as the main component are overviewed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 13, 2024 Category: Chemistry Authors: Rattanawadee Ploy Wijitwongwan Source Type: research

Crucial size effect on dicarbonylation of acetylene over Pd/CsHPMo heterogeneous catalysts
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D3DT03663D, PaperXuemei Wei, Kai Wang, Guofeng Wu, Guoqi Yu, hualiang shen, Tao Cai, Yanjuan Luo, Tianbo Shang, Xinzhi Chen, Run-pu Shen, Bin Hu Structure-sensitive activity of Pd catalyst in carbonylation reaction is an urgent problem to be explored. Herein, Pd nanocrystals with uniform particle size (2.3 nm, 3.4 nm, 5.0 nm and 6.7... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 13, 2024 Category: Chemistry Authors: Xuemei Wei Source Type: research

Programming heterometallic 4f –4f′ helicates under thermodynamic control: the circle is complete
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Charlotte Egger, Laure Gu énée, Neel Deorukhkar, Claude Piguet The use of pair interactions and specific site affinities provides 63% of the heterotrimetallicHHH-[(L43Zn)LaEu]8+ helicate in solution where statistics predicts only 25% of this isomer under thermodynamic control for a stoichiometric ratio of 1  : 1 : 1. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 13, 2024 Category: Chemistry Authors: Charlotte Egger Source Type: research

Refined structural studies on the fluorite-related polymorphs of sol –gel undoped and Eu3+-doped yttrium tantalates
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00338A, PaperFernanda Hediger Borges, Maria Vit ória Guidorzi, Hayra do Prado Labaki, Rute A. S. Ferreira, Rogéria Rocha Gonçalves Undoped and Eu3+-doped yttrium tantalates were synthesizedvia sol –gel method. Refined X-ray diffraction, Raman spectroscopy, and low-temperature photoluminescence measurements were employed for conclusive RE3TaO7 crystalline phase asignment. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 13, 2024 Category: Chemistry Authors: Fernanda Hediger Borges Source Type: research

Exploring the Carbonic Anhydrase-Mimetic [(PMDTA)2ZnII2(OH –)2]2+ for Nitric Oxide Monooxygenation
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00407H, CommunicationSandip Das, Pankaj Kumar In biology, nitrite (NO2–) serves as a storage pool of nitric oxide (NO); however, the formation of NO2– from NO is still under investigation. Here, we report the NO monooxygenation... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 13, 2024 Category: Chemistry Authors: Sandip Das Source Type: research

Direct C-H electrophilic borylation with (C6F5)2B-NTf2 to generate B-N dibenzo[a,h]pyrenes
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00469H, PaperTony Nguyen, Jason Laurence Dutton, Chia Yun Chang, Wen Zhou, Warren Piers The borylation of aryl substituted pyridines is an effective way of preparing B-N doped conjugated organic frameworks. Trihaloborane Lewis acids are often employed for this protocol, and may require further... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 13, 2024 Category: Chemistry Authors: Tony Nguyen Source Type: research

Enabling a Bioinspired N,N,N- Copper Coordination Motif through Spatial Control in UiO-67: Synthesis and Reactivity
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Isabelle Gerz, Erlend Aunan, Valeria Finelli, MOUHAMMAD ABU RASHEED, Gabriele Deplano, Rafael Cortez S. Pupo, Inga Lena Schmidtke, David Wragg, Matteo Signorile, Knut Tormodss ønn Hylland, Elisa Borfecchia, Karl Petter Lillerud, Silvia Bordiga, Unni Olsbye, Mohamed Amedjkouh Metal-organic frameworks (MOFs) featuring zirconium-based clusters are widely used for the development of functionalized materials due to their exceptional stability. In this study, we report the synthesis of a novel... The content of this RSS Feed (c) The Royal Society ...
Source: RSC - Dalton Trans. latest articles - March 13, 2024 Category: Chemistry Authors: Isabelle Gerz Source Type: research

Third-order Nonlinear Optical Properties of Highly Electron Deficient, Nonplanar Push-Pull Porphyrins: β-Nitro-Hexa-Substituted Porphyrins Bearing Bromo, Phenyl, and Phenylethynyl groups
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00045E, PaperRenu K Rohal, Dipanjan Banerjee, Nivedita Rana, Venugopal Rao Soma, Sankar Muniappan β-Heptasubstituted porphyrins [MTPP(NO2)X6; M = 2H, Ni(II), Cu(II), and ZnII; X = Br, Ph, and PE] were synthesized and explored their third-order nonlinear optical (NLO) properties using single-beam Z-scan technique... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 12, 2024 Category: Chemistry Authors: Renu K Rohal Source Type: research

Re(I)[2-aryl-1H-imidazo[4,5-f][1,10]phenanthroline] tricarbonyl chloride complexes for selective cancer therapy via a potential DNA damage mechanism
Dalton Trans., 2024, Advance Article DOI: 10.1039/D3DT04383E, PaperLavanya Thilak Babu, Utpal Das, Rishav Das, Binoy Kar, Priyankar Paira Rhenium (I)-based 2-arylimidazopenantroline tricarbonyl complexes show potential for cancer treatmentvia G2/M phase cell-cycle arrest in association with the generation of reactive oxygen species (ROS). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - March 12, 2024 Category: Chemistry Authors: Lavanya Thilak Babu Source Type: research