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Probing structural and dynamic properties of MAPbCl3 hybrid perovskite using Mn2+ EPR
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Gediminas Usevicius, Justinas Turcak, Yuxuan Zhang, Andrea Eggeling, Zyginta Einoryte, Michael A. Hope, Sarunas Svirskas, Daniel Klose, Vidmantas Kalendra, K ęstutis Aidas, Gunnar Jeschke, Juras Banys, Mantas Simenas Hybrid methylammonium (MA) lead halide perovskites have emerged as materials exhibiting excellent photovoltaic performance related to their rich structural and dynamic properties. Here, we use multifrequency (X-, Q-, and W-band)... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Gediminas Usevicius Source Type: research

Modulated Spin Dynamics of [Co2] Coordination Helicates via Differential Strand Composition
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Guillem Aromi, LEONI ALEJANDRA ALEJANDRA BARRIOS MORENO, Nuria Cap ó, Hanae Boulehjour, Daniel Reta, Ines Tejedor, Olivier Roubeau Coordination supramolecular chemistry provides a versatile entry into materials with functionalitites of technological relevance at the nanoscale. Here, we describe how two different bis-pyrazolylpyridine ligands (L1 and L2) assemble with... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Guillem Aromi Source Type: research

Exploring spin states and ligand field splitting in metal complexes: a theoretical analysis of spin-orbital interactions and magnetic properties
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00329B, PaperTomohiko Ishii, Kazuyoshi Ogasawara, Genta Sakane Metal complexes are pivotal in diverse fields due to their wide array of functionalities, including magnetism, conductivity, and photoresponsiveness. These functionalities are intricately linked to the phenomenon of ligand field... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Tomohiko Ishii Source Type: research

Theoretical Insights into Selective Extraction of Am(III) from Cm(III) and Eu(III) with Asymmetric N-heterocyclic Ligands
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D3DT03965J, PaperYan-Mei Chen, Congzhi Wang, Lei Zhang, Qun-Yan Wu, Jianhui Lan, Zhifang Chai, Weiqun Shi Separation of lanthanide (Ln) and minor actinide (MA) elements and mutual separation between minor actinide elements (e.g. Am(III), Cm(III)) represent a crucial undertaking. However, separating these elements poses a significant... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Yan-Mei Chen Source Type: research

Effect of diamagnetic Zn(II) ions on the SMM properties of a series of trinuclear ZnDy2 and tetranuclear Zn2Dy2 (LnIII = Dy, Tb, Gd) complexes: combined experimental and theoretical studies
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00417E, PaperPooja Shukla, Ibtesham Tarannum, Soumalya Roy, Amit Rajput, Prem Lama, Saurabh Kumar Singh, Julia K łak, Junseong Lee, Sourav Das Two distinct series of ZnII–LnIII complexes have been synthesized and characterized. Both experimental and theoretical magnetic studies have been conducted to examine the influence of diamagnetic ions on magnetic interactions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 2, 2024 Category: Chemistry Authors: Pooja Shukla Source Type: research

In situ electrochemically activated V2O3@MXene cathode for a super high-rate and long-life Zn-ion battery
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00488D, PaperYunlong Duan, Zhi Geng, Daohong Zhang, Qiufan Wang An  in situ electrochemically oxidized cathode is fabricated based on a V2O3@MXene cathode for Zn-ion storage, which delivered a high capacity of 450 mA h g−1 at 0.2 A g−1 as well as ultra-high-rate performance and cycling stability. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 2, 2024 Category: Chemistry Authors: Yunlong Duan Source Type: research

A carbon quantum dot-decorated g-C3N4 composite as a sulfur hosting material for lithium –sulfur batteries
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00511B, PaperYang Liu, Dandan Cai, Feng Zheng, Ziwei Qin, Ying Li, Wenxian Li, Aijun Li, Yufeng Zhao, Jiujun Zhang Graphitic C3N4 (g-C3N4) assembled with highly-dispersed carbon quantum dots is designed as a cooperative catalyst to accelerate the reaction kinetics of lithium polysulfide conversion. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 2, 2024 Category: Chemistry Authors: Yang Liu Source Type: research

Metal ions determined geometrical configurations of metallo-cages with different emission properties
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00178H, PaperZirui Zhai, Qixia Bai, Yuming Guan, He Zhao, Tun Wu, Jingxian Pang, Haoxuan Xu, Tingzheng Xie, Zhe Zhang, Pingshan Wang The formation of metallo-cages is affected by a variety of factors such as ligands, metals, and anions, among which the impact of metals with different binding capacities is particularly important,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 2, 2024 Category: Chemistry Authors: Zirui Zhai Source Type: research

Memory effect in ferroelectric polyvinylidene fluoride (PVDF) films via spin crossover probes
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00220B, PaperYongsung Koo, Jose Galan-Mascaros Ferroelectric polymers are of great interest due to their intrinsic processing capabilities, superior to classic inorganic ferroelectric materials. For example, polyvinylidene fluoride (PVDF) and derivatives have been incorporated into multiple... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 2, 2024 Category: Chemistry Authors: Yongsung Koo Source Type: research

A Density Functional Theory Analysis of the C-H Activation Reactivity of Iron(IV)-Oxo complexes with 'O' Substituted Tetramethyl-cyclam Macrocycle
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00063C, PaperDebasish Mandal, Lovleen Kaur In this article, we present a meticulous computational study to foresee the effect of an oxygen-rich macrocycle on the reactivity of C-H activation. For this study, a widely studied nonheme... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 2, 2024 Category: Chemistry Authors: Debasish Mandal Source Type: research

Revisiting a (001)-oriented layered lead chloride templated by 1,2,4-triazolium: structural phase transitions, lattice dynamics and broadband photoluminescence
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00406J, PaperMiros ław Mączka, Szymon Sobczak, Maciej Ptak, Szymon Smółka, Katarzyna Fedoruk, Filip Dybała, Artur P. Herman, Waldeci Paraguassu, Jan K. Zaręba, Robert Kudrawiec, Adam Sieradzki, Andrzej Katrusiak Layered 1,2,4-triazolium lead chloride undergoes three phase transitions. It also exhibits narrow and broad emissions, which exhibit different temperature dependence. We correlated this behaviour with the change of the octahedral distortion. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS F...
Source: RSC - Dalton Trans. latest articles - April 2, 2024 Category: Chemistry Authors: Miros ław Mączka Source Type: research

Phenoxazinyl Zn(II) diradical complex formed via redox-driven cyclization of a 2-aminophenol-based N3O ligand. Isolation of the modified N3 ligand radical and its Ni(II) complex
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00374H, CommunicationNarottam Mukhopadhyay, Arunava Sengupta, Francesc Lloret, Rabindranath Mukherjee Intramolecular cyclization of an N3O ligand in air affording a phenoxazinyl Zn(II) diradical complex and isolation of the modified N3 ligand-radical. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 2, 2024 Category: Chemistry Authors: Narottam Mukhopadhyay Source Type: research

Impact on metal coordination and pH on the antimicrobial activity of histatin 5 and the products of its hydrolysis
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00565A, PaperEmilia Dzie ń, Joanna Wątły, Arian Kola, Aleksandra Mikolajczyk, Adriana Miller, Agnieszka Matera-Witkiewicz, Daniela Valensin, Magdalena Rowinska-Zyrek The work focuses on the relationship between the coordination chemistry and antimicrobial activity of Zn(II) and Cu(II) complexes of histatin 5 and the products of its hydrolysis: its N-terminal fragment... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 2, 2024 Category: Chemistry Authors: Emilia Dzie ń Source Type: research

Preparation of Monodisperse Cerium Oxide Particle Suspensions from a Tetravalent Precursor
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Ashley M. Hastings, Susana Herrera, Sharee Harris, Tashi Parsons-Davis, Andrew J. Pascall, Jennifer Shusterman Cerium oxide particles are a unique material that enables studying the intersection of metal oxides,f-elements, and nanomaterials. Distinct from diverse applications in catalysis, energy, and medicine, cerium possesses additional... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 2, 2024 Category: Chemistry Authors: Ashley M. Hastings Source Type: research

From Ln2O2S to Ln10OS14: Exploring the sulphur spectrum of trivalent lanthanoid oxysulphides
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00294F, FrontierBrian Alan Wuille Bille, Jes ús M. Velázquez While Ln2O2S oxysulphides have increasingly gained attention for their structural and optoelectronic properties, an expansive compositional space lies beyond as the sulphur-to-oxygen ratio increases. In these oxysulphides, the compounded effect... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 1, 2024 Category: Chemistry Authors: Brian Alan Wuille Bille Source Type: research