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Influence of the phonon-bottleneck effect and low-energy vibrational modes on the slow spin-phonon relaxation in Kramers-ions-based Cu(II) and Co(II) complexes with 4-amino-3,5-bis-(pyridin-2-yl)-1,2,4-triazole and dicyanamide
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00219A, PaperIvan Poto čňák, Oleksandr Bukrynov, Andrii Kliuikov, Mariia Holub, Svitlana Vitushkina, Erika Samoľová, Erik Čižmár, Lucia Váhovská Two new complexes, [Cu(abpt)2(dca)2] and [Co(abpt)2(dca)2] (abpt = 4-amino-3,5-bis-(pyridin-2-yl)-1,2,4-triazole; dca = dicyanamide), have been prepared and magneto-structurally characterised. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Ivan Poto čňák Source Type: research

Tunable Zinc Benzamidinate Complexes: Coordination Modes and Catalytic Activity in the Ring-Opening Polymerization of L-lactide
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00188E, PaperChen-Chieh Chang, Ming-Tsz Chen, Tzu-Lun Huang, Chi-Tien Chen Seven asymmetric zinc benzamidinate complexes featuring or lacking side-arm functionalities were synthesized. Using equimolar zinc reagent produced distinct dinuclear motifs [(C6H5-C{NR}=NC6H5)ZnEt]2 (R =tBu,1; (CH2)2OMe,2; (CH2)2NMe2,3). Half... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Chen-Chieh Chang Source Type: research

Probing the Influence of Strontium Doping and Annealing Temperature on Structure and Biocompatibility of Hydroxyapatite Nanorods
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D3DT04305C, PaperHarsha G. Patil, Archana Rajendran, Nibedita Lenka, Sachin Kumar Balakrishnamurthy, Selvakumar Murugesan, S. Anandhan Among numerous biologically important metal cations, strontium (Sr2+) has received much attention in bone tissue regeneration because of its osteoinductive property combined with its ability in inhibiting osteoclast activity. In... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Harsha G. Patil Source Type: research

Reactions of (mesityl)n(methyl)2 −nsilylene complexes with pyridine-N-oxide (n = 1 and 0): formation of silanone complexes and a disiloxanyloxy complex
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00631C, PaperTakako Muraoka, Taichi Ishita, Kosuke Kawachi, Takuya Nishio, Hiroto Ishihara, Keiji Ueno A silanone tungsten complex with Mes(Me) substituents (Mes: 2,4,6-Me3C6H2) was obtained. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Takako Muraoka Source Type: research

Unlocking single molecule magnetism: a supramolecular strategy for isolating neutral MnIII salen-type dimer in crystalline environments
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Yuri Kyoya, Kiyonori Takahashi, Wataru Kosaka, Rui-Kang Huang, Xue Chen, Jia-bing Wu, Hitoshi Miyasaka, Takayoshi Nakamura In [Mn(5-MeOsalen)(Cl)]2(dibenzo[24]crown-8), dibenzo[24]-crown-8 formed a supramolecule via multi-point interactions with the [Mn(5-MeOsalen)(Cl)] dimer. The dimer was magnetically isolated withST = 4 and weak interdimer magnetic interactions. The crystal exhibited... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Yuri Kyoya Source Type: research

Spectroscopic and Thermodynamic Characterization of a Cobalt-Verdazyl Valence Tautomeric System. Influence of Crystal Structure, Solvent and Counterion.
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.David James Rawsthorne Brook, Jeffrey DaRos, Aamani Ponnekanti, Stefano Agrestini, Eric Pellegrin Crystallization of the verdazyl-based valence tautomeric ion [Co(dipyvd)2]2+ (where dipyvd is the radical ligand 1-isopropyl-3,5-di(2 ’-pyridyl) -6-oxoverdazyl) with a variety of different counterions results in materials that show varying degrees of... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: David James Rawsthorne Brook Source Type: research

Bright white light emission from lanthanide oxide LaGdO3 for LED lighting by Bi3+ to Eu3+ energy transfer
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00532E, PaperZhangyan Yang, Zeyu Lyu, Dashuai Sun, Sida Shen, Shuai Wei, Zheng Lu, Mingrui He, Zhuihao Huang, Hongpeng You This work reports a novel white light emission phosphor LaGdO3:Bi3+,Eu3+. A single-phased WLED device with a color-rendering index of 92.4 was successfully prepared by employing a near-ultraviolet chip and the LaGdO3:Bi3+,Eu3+ phosphors. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Zhangyan Yang Source Type: research

Efficient electrochemical reduction of CO2 to CO in a flow cell device by a pristine Cu5tz6-cluster-based metal –organic framework
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00189C, PaperZijing Li, Yingtong Lv, Haoliang Huang, Zi-Jian Li, Tao Li, Linjuan Zhang, Jian-Qiang Wang A Cu5tz6 cluster-based metal –organic framework results in efficient electrochemical reduction of CO2 to CO, in which the copper site was fully characterized by X-ray absorption spectroscopy and other techniques. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Zijing Li Source Type: research

Chromium iodate: the structure and origin of optical second harmonic generation
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00470A, PaperYang Chi, Mei-Ling Xin The transition metal cation centered groups of Cr(IO3)3 play a key role in its large second-harmonic generation effect. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Yang Chi Source Type: research

Azidomethyl-bisoxadiazol-linked-1,2,3-triazole-(ABT)-based potential liquid propellant and energetic plasticizer
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Sohan Lal, Richard J. Staples, Jean'ne M. Shreeve A scalable and facile synthesis of a novel next-generation liquid rocket propellant and a potential energetic plasticizer has been reported with balanced energetic performance. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Sohan Lal Source Type: research

Linker-dependent control of the chiroptical properties of polymethylene-vaulted trans-bis[( β-iminomethyl)naphthoxy]platinum(II) complexes
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00273C, PaperMasahiro Ikeshita, Shing Cho Ma, Gilles Muller, Takeshi Naota The effects of polymethylene bridges on the chiroptical properties oftrans-bis[( β-iminomethyl)naphthoxy]platinum(II) platforms were examined both experimentally and theoretically using newly-designed planar chiral Pt analogues (1) bearing three-dimensional superstructures. A series... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Masahiro Ikeshita Source Type: research

Guest water-induced structural transformation and spin-crossover variation of a two-dimensional Hofmann-type compound
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00435C, PaperZhi-Kun Liu, Ke Sun, Jin-Peng Xue, Zi-Shuo Yao, Jun Tao In this paper, we report a two-dimensional (2D) Hofmann-type spin-crossover coordination polymer [FeII(o-NTrz)2PtII(CN)4] ∙H2O (o-NTrz = 4-(o-nitrobenzyl)imino-1,2,4-triazole). Due to the remarkable configurational flexibility of triazole-based ligand, the porous structure of this... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Zhi-Kun Liu Source Type: research

Synthesis and catalytic activity of single-site group V alkoxide complexes for the ring-opening polymerization of ε-caprolactone
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00422A, PaperFrank Peprah, Grace E. Tarantola, Alyson S. Plaman, Emily L. Vu, Alyssa B. Huynh, Christopher B. Durr The synthesis, characterization, and ring-opening polymerization (ROP) activity of a family of niobium and tantalum alkoxide catalysts was studied. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Frank Peprah Source Type: research

Strong thickness dependence in thin film photocatalytic heterojunctions: the ZnO –Bi2O3 case study
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00697F, PaperAlberto Bernal-D íaz, Agileo Hernández-Gordillo, Juan Carlos Alonso, Sandra E. Rodil, Monserrat Bizarro In thin film heterojunctions, the photocatalytic activity is strongly influenced by the deposition order and the thickness of each layer as different reactive species can be formed. Under certain conditions a synergistic effect can be achieved even under visible light. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Alberto Bernal-D íaz Source Type: research

Effective photosensitized emission of a Tb(III) complex using a β-diketonate photosensitizer and an oxygen barrier system in a thermally populated triplet state
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Kota Inage, Mengfei Wang, Yasuchika Hasegawa, Yuichi Kitagawa A Tb(III) complex with a β-diketonate photosensitizer and bulky ancillary ligands exhibits strong photosensitized emission. The bulky ancillary ligand plays a crucial role in shielding from oxygen, resulting in effective photosensitized emission. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 3, 2024 Category: Chemistry Authors: Kota Inage Source Type: research