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Dinuclear NHC –gold(I)–thiolato and –alkynyl complexes: synthesis, anticancer activity, and catalytic activity in lactonization reactions
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Xinyuan Ma, Yuan Zhao, Isabella Caligiuri, Flavio Rizzolio, Nestor Bracho Pozsoni, Kristof Van Hecke, Thomas Scattolin, Steven P. Nolan A series of novel dinuclear NHC –gold–thiolato and –alkynyl complexes bearing aromatic linkers were successfully synthesized by an efficient and simple synthetic route. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 22, 2024 Category: Chemistry Authors: Xinyuan Ma Source Type: research

Newly synthesized palladium(II) complexes with dialkyl esters of (S,S)-propylenediamine-N,N ′-di-(2,2′-di-(4-hydroxy-benzil))acetic acid: in vitro investigation of biological activities and HSA/DNA binding
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Kemal Ćorović, Danijela Lj. Stojković, Đorđe S. Petrović, Sandra S. Jovičić Milić, Maja B. Đukić, Ivana D. Radojević, Ivana Raković, Milena Jurišević, Nevena Gajović, Marina Jovanović, Jovana Marinković, Ivan Jovanović, Bojan Stojanović The four new ligands, dialkyl esters type of ligands (R2-S,S-pddtyr ·2HCl) and corresponding palladium(II) complexes have been synthesized, characterized, and their biological activities were investigated. To cite this article before page numbers are assigned, use the DOI for...
Source: RSC - Dalton Trans. latest articles - April 22, 2024 Category: Chemistry Authors: Kemal Ćorović Source Type: research

Homoleptic Hexa and Penta Coordinated Gallium(I) Amide Complexes of Ruthenium and Molybdenum
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Raphael B ühler, Richard Johannes Josef Weininger, Johannes Stephan, Maximilian Muhr, Balasai Marie-Teres Bock, Christian Gemel, Roland A. Fischer Reaction of neutral olefin complexes of ruthenium and molybdenum with GaTMP (TMP = 2,2,6,6-tetramethylpiperidinyl) by substitution leads to the formation of respective five and six coordinated homoleptic products. [Ru(GaTMP)5] (1)... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 21, 2024 Category: Chemistry Authors: Raphael B ühler Source Type: research

Comparative outcomes of the voltage-dependent current density, charge transportation and rectification ratio of electronic devices fabricated using mechanically flexible supramolecular networks
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00383G, PaperBaishakhi Pal, Santanu Majumdar, Indrajit Pal, Gerald Lepcha, Amiya Dey, Partha Pratim Ray, Biswajit Dey Flexible supramolecular material-based metal –semiconductor junction-type Schottky barrier diodes with high rectification ratios and excellent charge transport properties have been achieved. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 19, 2024 Category: Chemistry Authors: Baishakhi Pal Source Type: research

Tuning the slow magnetic relaxation with the substituents in anilate bridged bis(dysprosium) complexes
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00175C, PaperFabio Manna, Mariangela Oggianu, Jose Galan-Mascaros, Flavia Pop, Boris Le Guennic, Maria Laura Mercuri, Narcis Avarvari Dinuclear lanthanide complexes [((HB(pz)3)2Dy)2( μ-Th2An)] (1Dy) and [((HB(pz)3)2Dy)2(μ-ClCNAn)] (2Dy), based on the hydrotris(pyrazol-1-yl)borate (HBpz3-) scorpionate capping ligand and anilate (An2-) bridging linkers, namely homosubstituted dithiophene- and heterosubstituted chlorocyanoanilate, bearing electron-donating and... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 19, 2024 Category: Chemistry Authors: Fabio Manna Source Type: research

Layered rare-earth hydroxides as multi-modal medical imaging probes: particle size optimisation and compositional exploration
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Margarita Strimaite, Connor J. R. Wells, Timothy J. Prior, Daniel James Stuckey, Jack Wells, Gemma-Louise Davies, Gareth R Williams Recently, layered rare-earth hydroxides (LRHs) have received growing attention in the field of theranostics. We have previously reported the hydrothermal synthesis of layered terbium hydroxide (LTbH), which exhibited high biocompatibility,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 19, 2024 Category: Chemistry Authors: Margarita Strimaite Source Type: research

An innovative synthesis of carbon-coated TiO2 nanoparticles as host for Na+ intercalation for sodium-ion batteries
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Tanguy SOUDANT, Solenne Fleutot, St éphanie Bruyère, Lucie Speyer, Sébastien Hupont, Mickaël Bolmont, Thomas Girardet, Loris Raspado, Claire Hérold, Sébastien Cahen In this work, an innovative route to synthesize anatase TiO2@C composite is presented. The synthesis was conducted by a soft chemistry microwave-assisted method using titanium(IV) butoxide as titanium precursor. The... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 19, 2024 Category: Chemistry Authors: Tanguy SOUDANT Source Type: research

Organometallics in Molecular Junctions: Conductance, Functions, and Reactions
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00668B, PerspectiveYuya Tanaka Molecular junctions, which involve sandwiching molecular structures between electrodes, play a crucial role in molecular electronics. Recent advances in this field have revealed the vital role of organometallic chemistry in... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 19, 2024 Category: Chemistry Authors: Yuya Tanaka Source Type: research

Highly Cytotoxic Cu(II) Terpyridine Complexes as Chemotherapeutic Agents
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Kaixin Ni, Nicol ás Montesdeoca, Johannes Karges Cancer is considered as the biggest medicinal challenge worldwide. During a typical treatment, the tumorous tissue is removed in a surgical procedure and the patient further treated by chemotherapy. One... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 19, 2024 Category: Chemistry Authors: Kaixin Ni Source Type: research

Reactivity of Schiff base-[C,N,S] pincer palladacycles: hydrolysis renders singular trinuclear, tetranuclear, and heteropentanuclear Pd3W2 coordinated complexes
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Jose M. Vila, Francisco Reigosa, M. Teresa Pereira, Paula M. Polo Treatment of the Schiff base ligands a-f with Li2[PdCl4] / NaAcO in methanol under reflux gave the single nuclear palladacycles 1a-1f, with the metal atom bonded to a terdentate monoanionic... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 19, 2024 Category: Chemistry Authors: Jose M. Vila Source Type: research

Coinage metal-ethylene complexes of sterically demanding 1,10-phenanthroline ligands
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00822G, PaperDeepika V. Karade, Vo Quang Huy Phan, Rasika Dias Phenanthroline-based ligands with bulky aryl groups flanking the metal binding pocket enabled the synthesis and detailed investigation of ethylene complexes of copper(I), silver(I), and gold(I), including structural data of [{2,9-bis(2,4,6-triisopropylphenyl)-1,10-phenanthroline}M(C2H4)][SbF6]... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 19, 2024 Category: Chemistry Authors: Deepika V. Karade Source Type: research

Enhanced white rot control in garlic bulbil using organic –inorganic hybrid materials as coating membranes
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00301B, PaperLorena Alves de Melo Bessa, Mariane Lu ísa Ferreira Nazário, Celly Mieko Shinohara Izumi, Vera Regina Leopoldo Constantino, Valdir Lourenço, Everaldo Antônio Lopes, Eduardo Seiti Gomide Mizubuti, Jairo Tronto Organic –inorganic hybrid materials have a range of applications due to their unique properties. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 18, 2024 Category: Chemistry Authors: Lorena Alves de Melo Bessa Source Type: research

Discovery of two predictable (3,18)-connected topologies based on Wells –Dawson type cages for the design of porous metal phosphonocarboxylate frameworks
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00590B, PaperWenyan Dan, Zhenxia Chen, Yun Ling, Yu Jia, Yongtai Yang, Xiaofeng Liu, Mingli Deng Four porous metal phosphonocarboxylate frameworks (MPCFs) were constructed using a Wells –Dawson-like molecular building unit and 4′-phosphonobiphenyl-3,5-dicarboxylic acid, exhibiting rare (3,18)-connected topologies ofgez andgea, respectively. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 18, 2024 Category: Chemistry Authors: Wenyan Dan Source Type: research

Computational design of cooperatively acting molecular catalyst systems: carbene based tungsten- or molybdenum-catalysts with rhodium- or iridium-complexes for the ionic hydrogenation of N2 to NH3
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Totan Mondal, Walter Leitner, Markus H ölscher Low activation barriers allow for NH3 synthesis from N2/H2 using cooperatively acting catalysts based on carbene pincer complexes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - April 18, 2024 Category: Chemistry Authors: Totan Mondal Source Type: research

Investigation of Ln3+ complexation by a DOTA derivative substituted by an imidazothiadiazole: synthesis, solution structure, luminescence and relaxation properties
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00533C, PaperEmma Caillet, L éa Nunes, Svetlana Valer'evna Eliseeva, Modou Ndiaye, Manon Isaac, Agnes Pallier, Jean-François Morfin, Hervé Meudal, Stephane Petoud, Sylvain Routier, Carlos Platas-Iglesias, Frédéric Buron, Célia S. Bonnet We investigated the coordination properties of original macrocyclic Ln3+ complexes comprising an imidazothiadiazole heterocycle. The thermodynamic stability of the Gd3+ complex was determined by a combination of potentiometric and photophysical... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Da...
Source: RSC - Dalton Trans. latest articles - April 18, 2024 Category: Chemistry Authors: Emma Caillet Source Type: research