N^N^C-Cyclometalated rhodium(III) complexes with isomeric pyrimidine-based ligands: unveiling the impact of isomerism on structural motifs, luminescence and cytotoxicity

Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00824C, PaperSofia Vorobyeva, Sof ’ya Bautina, Nikita Shekhovtsov, Elena B Nikolaenkova, Taisiya Sergeevna Sukhikh, Yuliya Golubeva, Lyubov Klyushova, Viktor P Krivopalov, Marianna I Rakhmanova, Christophe Gourlaouen, Mark B Bushuev The impact of isomerism of pyrimidine-based ligands and their rhodium(III) complexes with regard to their structures and properties was investigated. Two isomeric ligands, 4-(3,5-dimethyl-1H-pyrazol-1-yl)-2,5-diphenylpyrimidine (HL2,5) and 4-(3,5-dimethyl-1H-pyrazol-1-yl)-2,6-diphenylpyrimidine (HL2,6), were synthesized.... The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Dalton Trans. latest articles - April 23, 2024 Category: Chemistry Authors: Sofia Vorobyeva Source Type: research