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The effect of light irradiation on a nitro-ruthenium porphyrin complex in the induced death of lung cancer cells in two- and three-dimensional cultures: Insights into the effect of nitric oxide
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00381K, PaperAmanda Blanque Becceneri, Matheus Torelli Martin, Angelica Ellen Graminha, M árcia Regina Cominetti, Peter C. Ford, Roberto Santana da Silva The effects of the nitro-ruthenium porphyrin complex, RuNO2TPyP, in lung cells using 2D and 3D cell culture models. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 2, 2024 Category: Chemistry Authors: Amanda Blanque Becceneri Source Type: research

Insights into a surface-modified Li(Ni0.80Co0.15Al0.05)O2 cathode by atomic layer fluorination for improved cycling behaviour
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Youn Charles-Blin, Oumaima Hatim, M élissa Clarac, Anne-Marie Perbost, Solveine Liminana, Laura Lopez, Olinda Gimello, Katia Guérin, Marc Dubois, Michael Deschamps, Delphine Flahaut, Hervé Martinez, Laure Monconduit, Nicolas Louvain Atomic layer fluorination of Li(Ni0.80Co0.15Al0.05)O2 leads to improved charge/discharge cyclability in Li-ion cells and limited electrolyte decomposition. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society...
Source: RSC - Dalton Trans. latest articles - May 2, 2024 Category: Chemistry Authors: Youn Charles-Blin Source Type: research

DLPNO-CCSD(T) and DFT study of the acetate-assisted C –H activation of benzaldimine at [RuCl2(p-cymene)]2: the relevance of ligand exchange processes at ruthenium(II) complexes in polar protic media
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Vicente Ojea, Mar ía Ruiz For acetate-assisted cyclometallation of benzaldimine at [RuCl2(p-cymene)]2 in MeOH, anion dissociation is the rate-determining step. Subsequent C –H bond activation events and acetate/chloride exchange at cycloruthenate are reversible processes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 2, 2024 Category: Chemistry Authors: Vicente Ojea Source Type: research

Constructing novel hydrated metal molten salt with high self-heal as anode material for Lithium-Ion Batteries
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00696H, PaperYiting Wang, Yifei Li, Jiali Chai, Yichuan Rui, Lei Jiang, Bohejin Tang Lithium-ion batteries (LIBs) are greatly limited in its practical application because of its poor cycle performance, low conductivity and volume expansion. Herein, Molten salts (MSs) FeCl3.6H2O-NMP with low temperature via... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 2, 2024 Category: Chemistry Authors: Yiting Wang Source Type: research

Dibenzoazepine hydrazine is a building block for N-alkene hybrid ligands: exploratory syntheses of complexes of Cu, Fe, and Li
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Alexander Grasruck, Kristina Schall, Frank W. Heinemann, Jens Langer, Alberto Herrera, Sybille Frie ß, Günter Schmid, Romano Dorta A new Dibenzoazepine-hydrazine is a versatile building block for the synthesis of potentially hemilabile hydrazone N –alkene ligands for the formation of main group and transition metal complexes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 2, 2024 Category: Chemistry Authors: Alexander Grasruck Source Type: research

Comparison of the structural, electrochemical, and spectroscopic properties of two cryptates of trivalent uranium
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.D. Nuwangi Kulasekara, Matthew D. Bailey, Cassandra L. Ward, Matthew J. Allen Two cryptates of trivalent uranium are compared with respect to luminescence, solid-state structure, and electrochemistry. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 2, 2024 Category: Chemistry Authors: D. Nuwangi Kulasekara Source Type: research

Orthopalladated imidazolones and thiazolones: synthesis, photophysical properties and photochemical reactivity
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Darius Dumitra ș, David Dalmau, Pilar García-Orduña, Alexandra Pop, Anca Silvestru, Esteban Pablo Urriolabeitia The reaction of Pd(OAc)2 with (Z)-5-arylidene-4-(4H)-imidazolones (2a-e) and (Z)-4-arylidene-5(4H)-thiazolones (3a-e) in trifluoroacetic acid results in the corresponding orthopalladated dinuclear complexes (4a-e, imidazolones; 11a-d, thiazolones) with trifluoroacetate bridges through regioselective C-H... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 2, 2024 Category: Chemistry Authors: Darius Dumitra ș Source Type: research

An ALP-responsive, anionic iridium complex for specific recognition of osteosarcoma cells
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00568F, PaperShuang Shen, Shuli Nong, Xianpeng Zhang, Jiaqi Song, Caiting Meng, Xinling Liu, Liang Shao, Guanying Li, Li Xu Through the hydrolysis by alkaline phosphatase, an anionic Ir(III) complex is converted into cationic complex with increased lipophilicity, subsequently enhancing cell internalization and specifically staining osteosarcoma cells. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 2, 2024 Category: Chemistry Authors: Shuang Shen Source Type: research

Effect of Distal Metal Species on Lewis Basicity of a μ3-Oxo Ligand in Doubly Oxo-bridged (μ3-O)[Rh(COD)]3(μ4-O)M Core
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00932K, CommunicationHayato Tsurugi, Hiroki Mori, Haruna Mori, Masami Nakamoto, Shinji Tanaka, Kazushi Mashima The Lewis basicity of a μ3-oxo ligand for ( μ3-O)[Rh(COD)]3( μ4-O)M complexes was controllable by metal species on the μ4-oxo ligand locating at the opposite site of the μ3-oxo ligand. Coordination of... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 2, 2024 Category: Chemistry Authors: Hayato Tsurugi Source Type: research

Fluorescence properties of novel deep-red phosphor LiMg4SbO7:Mn4+ with excellent quantum efficiency and color purity for warm white LEDs
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00868E, PaperFei Wang, Huihui Chen, Zhang Shiwei, Jin Huiqing Red fluorescent materials have important application value in the background light and LED lighting fields of displays. In this work, a novel type of rare earth free deep-red phosphor LiMg4SbO7:Mn4+... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 2, 2024 Category: Chemistry Authors: Fei Wang Source Type: research

Correction: Synthetic routes to carbon substituted cobalt bis(dicarbollide) alkyl halides and aromatic amines along with closely related irregular pathways
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Jan Nekvinda, Dmytro Bavol, Miroslava Liteck á, Ece Zeynep Tüzün, Michal Dušek, Bohumír Grüner To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 2, 2024 Category: Chemistry Authors: Jan Nekvinda Source Type: research

Ni(2,2 ’:6’,2’’-terpyridine)2: A high-spin octahedral formal Ni(0) complex
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Natalia Cabrera-Lobera, Estefania del Horno, M. Teresa Quiros, Elena Bu ñuel, Magali Gimeno, William W. Brennessel, Michael L. Neidig, Jose Luis Priego, Diego J Cardenas We have synthesised and characterised the complex Ni(tpy)2 (tpy = 2,2 ’:6’,2’’-terpyridine). This formally Ni(0) complex is paramagnetic both in the solid state and in solution (S = 2). The crystal... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 2, 2024 Category: Chemistry Authors: Natalia Cabrera-Lobera Source Type: research

Dinuclear ytterbium(III) benzamidinate complexes with bridging S32 −, Se22− and Te22− ligands: synthesis, structure and magnetic properties
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00724G, CommunicationYing-Zhao Ma, Lian Yu, Qi Zhou, Wensheng Fu The reduction of S8, Se or Te by an Yb(II) benzamidinate complex afforded a series of dinuclear Yb(III) chalcogenides and the Te22 − bridging one is a rare ytterbium telluride single molecule magnet. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 1, 2024 Category: Chemistry Authors: Ying-Zhao Ma Source Type: research

Cu(II)-Ln(III) (Ln = Gd, Tb and Dy) complexes of an unsymmetrical N2O3 donor ligand: Field induced SMM behaviour for Cu(II)-Tb(III) complex
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00304G, PaperPradip Bhunia, Souvik Maity, Tanmoy Kumar Ghosh, Arpan Mondal, Julia Mayans, Ashutosh Ghosh Three new hetero-metallic CuII ─LnIII complexes [(CuL)Gd(NO3)3(CH3OH)]n (1), [(CuL)Tb(NO3)3(H2O)]∙[CuL] (2) and [(CuL)Dy(NO3)3(H2O)]∙[CuL] (3) have been synthesized using a mono-nuclear Cu(II) complex, [CuL] of an unsymmetrically di-condensed N2O3 donor Schiff base ligand,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 1, 2024 Category: Chemistry Authors: Pradip Bhunia Source Type: research

Synthesis and catalytic properties of palladium(II) complexes with P, π-chelating ferrocene phosphinoallyl ligands and their non tethered analogues
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Karel Skoch, Jakub Antala, Ivana Cisarova, Petr Štěpnička Hybrid phosphines usually combine a phosphine moiety with another heteroatom secondary donor group in their structures while compounds equipped with hydrocarbyl π-donor moieties remain still uncommon. This contribution reports the... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Dalton Trans. latest articles)
Source: RSC - Dalton Trans. latest articles - May 1, 2024 Category: Chemistry Authors: Karel Skoch Source Type: research