DLPNO-CCSD(T) and DFT study of the acetate-assisted C –H activation of benzaldimine at [RuCl2(p-cymene)]2: the relevance of ligand exchange processes at ruthenium(II) complexes in polar protic media

This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Vicente Ojea, Mar ía Ruiz For acetate-assisted cyclometallation of benzaldimine at [RuCl2(p-cymene)]2 in MeOH, anion dissociation is the rate-determining step. Subsequent C –H bond activation events and acetate/chloride exchange at cycloruthenate are reversible processes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Dalton Trans. latest articles - May 2, 2024 Category: Chemistry Authors: Vicente Ojea Source Type: research