Ni0(cod)(dq) (COD: 1,5-cycloctadiene; DQ: duroquinone) complex as a catalyst precursor for oligothiophene and polythiophene synthesis
Org. Biomol. Chem., 2024, Accepted Manuscript DOI: 10.1039/D4OB00210E, PaperAtsunori Mori, Naoki Noda, Seiha Yamaoka, Ukyo Ogi, Masaki Horie, Kentaro Okano Nickel-catalyzed syntheses of oligothiophene and polythiophene were carried out with Ni(cod)(dq) (COD: 1,5-cycloctadiene; DQ: duroquinone) as a catalyst precursor. Studies on ligand exchange of Ni(cod)(dq) revealed that a high temperature... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Organic and Biomolecular Chemistry)
Source: RSC - Organic and Biomolecular Chemistry - March 6, 2024 Category: Molecular Biology Authors: Atsunori Mori Source Type: research

Rhodium-catalysed additive-free carbonylation of benzamides with diethyl dicarbonate as a carbonyl source
Org. Biomol. Chem., 2024, Accepted Manuscript DOI: 10.1039/D4OB00059E, CommunicationHirotsugu Suzuki, Seigo Kiyobe, Takanori Matsuda Phthalimides are prevalent in numerous pharmaceuticals, prompting various phthalimide syntheses through C –H activation. Nevertheless, the necessity for stoichiometric additives limits their practicality and versatility. Herein, we introduced diethyl dicarbonate as... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Organic and Biomolecular Chemistry)
Source: RSC - Organic and Biomolecular Chemistry - March 6, 2024 Category: Molecular Biology Authors: Hirotsugu Suzuki Source Type: research

Construction of indolizine scaffolds from α,ω-alkynoic acids and α,ω-vinylamines via sequential-relay catalysis in “one pot”
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Jiami Liu, Yi Lu, Lingxuan Zhu, Xinsheng Lei A simple and efficient method for the synthesis of indolizin-3-ones through sequential Au(I)-catalyzed hydrocarboxylation, aminolysis, and cyclization, followed by ruthenium-catalyzed ring-closing metathesis. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Organic and Biomolecular Chemistry)
Source: RSC - Organic and Biomolecular Chemistry - March 6, 2024 Category: Molecular Biology Authors: Jiami Liu Source Type: research

Recent advances in the synthesis and applications of fluoranthenes
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Yunus Emre T ürkmen As an important subclass of polycyclic aromatic hydrocarbons (PAHs), fluoranthenes continue to attract significant attention in synthetic organic chemistry and materials science. In this article, an overview of recent advances... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Organic and Biomolecular Chemistry)
Source: RSC - Organic and Biomolecular Chemistry - March 6, 2024 Category: Molecular Biology Authors: Yunus Emre T ürkmen Source Type: research

A Visible light-induced photosensitizer-free decarbonylative Minisci-type reaction
This study presents a green and practical visible-light-induced photosensitizer-free decarbonylative Minisci-type reaction using aldehydes as alkyl radical precursors. Mechanism experiments revealed that TFA could absorb light and activate N-heteroarenes, promoting... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Organic and Biomolecular Chemistry)
Source: RSC - Organic and Biomolecular Chemistry - March 6, 2024 Category: Molecular Biology Authors: Ming Qi Source Type: research

Catalyst-free visible light-promoted defunctionalization of alkyl isocyanides with a hydrosilane through C-N bond cleavage
Org. Biomol. Chem., 2024, Accepted Manuscript DOI: 10.1039/D4OB00173G, CommunicationYu-Qing Ma, Shi-Kai Tian A radical initiator-free defunctionalization reaction of alkyl isocyanides with a hydrosilane has been established through C-N bond cleavage under catalyst-free visible light irradiation. Various alkyl isocyanides participated in the defunctionalization... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Organic and Biomolecular Chemistry)
Source: RSC - Organic and Biomolecular Chemistry - March 4, 2024 Category: Molecular Biology Authors: Yu-Qing Ma Source Type: research

Cobalt-catalyzed amination of aziridines and azetidines toward 1,2- and 1,3-diamines
Org. Biomol. Chem., 2024, Accepted Manuscript DOI: 10.1039/D4OB00168K, CommunicationLing-Chao Cheng, Zhihua Wang, Xinglei He, Wang-Fu Liang, Ke-Yin Ye Diamines play important roles in synthetic organic chemistry and thus facilitate life and materials science. Herein we report a cobalt-catalyzed ring opening, nucleophilic amination of aziridines and azetidines with N-fluorosulfonamides... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Organic and Biomolecular Chemistry)
Source: RSC - Organic and Biomolecular Chemistry - March 1, 2024 Category: Molecular Biology Authors: Ling-Chao Cheng Source Type: research

Application of the Intramolecular Diels –Alder Vinylarenе (IMDAV) Reaction for the Synthesis of Benzo-, Carbocyclo-, Thienothiopheneisoindolecarboxylic Acids and Its Limitations.
Org. Biomol. Chem., 2024, Accepted Manuscript DOI: 10.1039/D3OB01933K, PaperElizaveta Yakovleva, Evgeniya Shelukho, Maryana Nadirova, Pavel Erokhin, Daria Simakova, Victor N Khrustalev, Mikhail S. Grigoriev, Anton P. Novikov, Anna Romanycheva, Anton Shetnev, Olga Bychkova, Alexey Trenin, Fedor Ivanovich Zubkov, Vladimir P. Zaytsev Thienylallylamines, readily accessible from the corresponding thienyl aldehydes, interact with maleic and trifluoromethylmaleic anhydrides leading to the formation of acids with a thieno[2,3-f]isoindole core. The reaction sequence involves two successive... The content of this RSS Feed (c) The Ro...
Source: RSC - Organic and Biomolecular Chemistry - March 1, 2024 Category: Molecular Biology Authors: Elizaveta Yakovleva Source Type: research

Identification and Quantification of N6-Methyladenosine by Chemical Derivatization Coupled with 19F NMR Spectroscopy
Org. Biomol. Chem., 2024, Accepted Manuscript DOI: 10.1039/D4OB00169A, PaperTing Jiang, Qian Zhou, Kang-Kang Yu, Shan-Yong Chen, Kun Li N6-methyladenosine (6mA) is a well-known prokaryotic DNA modification that has been shown to play epigenetic roles in eukaryotic DNA. Accurate detection and quantification of 6mA are prerequisites for molecular understanding... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Organic and Biomolecular Chemistry)
Source: RSC - Organic and Biomolecular Chemistry - March 1, 2024 Category: Molecular Biology Authors: Ting Jiang Source Type: research

Visible light-induced organo-photocatalyzed route to synthesize substituted pyrazoles
Org. Biomol. Chem., 2024, Accepted Manuscript DOI: 10.1039/D4OB00248B, CommunicationKoustav Pal, Vinjamuri Srinivasu, Sourabh Biswas, Sureshkumar Devarajulu The synthesis of tetra-substituted pyrazoles holds significant synthetic value and has been accomplished through an organo-photocatalyzed decarboxylative intramolecular cyclization using readily available 1,2-diaza-1,3-dienes and α-ketoacids. This method allows for the... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Organic and Biomolecular Chemistry)
Source: RSC - Organic and Biomolecular Chemistry - March 1, 2024 Category: Molecular Biology Authors: Koustav Pal Source Type: research

A visible-light-catalyzed sulfonylation reaction of an aryl selenonium salt via an electron donor –acceptor complex
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Yuqing Wang, Liang Zhao, Xinyu Hao, Kun Jin, Rong Zhang, Chunying Duan, Yaming Li An efficient synthesis of sulfone structures through selenonium salts and sodium sulfinates was developed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Organic and Biomolecular Chemistry)
Source: RSC - Organic and Biomolecular Chemistry - February 29, 2024 Category: Molecular Biology Authors: Yuqing Wang Source Type: research

Electro-oxidative intermolecular CSP2-H amination of heteroarenes via proton-coupled electron transfer
Org. Biomol. Chem., 2024, Accepted Manuscript DOI: 10.1039/D4OB00164H, Communicationshuai liu, Xin Liu, Tian-Shu Zhang, Xiaoyu Bao, Xiaoyu Sheng, Zhenjie Qi, Dongfang Jiang A new electrochemical proton-coupled electron transfer method for the intermolecular CSP2-H amination of heteroarenes without oxidants, metal-catalysts and external electrotyles has been developed. Various new N-containing heteroarenes were prepared with... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Organic and Biomolecular Chemistry)
Source: RSC - Organic and Biomolecular Chemistry - February 29, 2024 Category: Molecular Biology Authors: shuai liu Source Type: research

Synthesis of bioactive evodiamine and rutaecarpine analogues under a ball milling condition
Org. Biomol. Chem., 2024, Accepted Manuscript DOI: 10.1039/D4OB00056K, PaperHao-Chun Hu, Szu-Yin Yu, Yi-Hong Tsi, Pei-Wen Hsieh, Hui-Chun Wang, Yan-Ning Chen, Ya-Ting Chuang , Min-Yu Lee, Hsueh-Wei Chang, Hao-Chun Hu, Yang-Chang Wu, Fang-Rong Chang, Istv án Szatmári, Ferenc Fulop Mechanochemical reactions achieved by processes such as milling and grinding offer a promising alternative to traditional solution-based chemistry. This approach not only eliminates the need for large quantities of solvents,... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Organic and Biomolecular Chemistry)
Source: RSC - Organic and Biomolecular Chemistry - February 29, 2024 Category: Molecular Biology Authors: Hao-Chun Hu Source Type: research

Small-Molecule Fluorogenic Probes Based on Indole Scaffold
Org. Biomol. Chem., 2024, Accepted Manuscript DOI: 10.1039/D3OB02057F, Review ArticleAjit Kumar Mahapatra, Pintu Ghosh, Anirban Karak Indoles are the most versatile organic N-heterocyclic compounds widely present in bioactive natural products and used in different fields such as coordination chemistry, pharmacy, dyes, and medicine, as well as... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Organic and Biomolecular Chemistry)
Source: RSC - Organic and Biomolecular Chemistry - February 29, 2024 Category: Molecular Biology Authors: Ajit Kumar Mahapatra Source Type: research

Additive-assisted synthesis of α-Kdo glycosides with peracetylated glycosyl ynenoate as a donor
Org. Biomol. Chem., 2024, Advance Article DOI: 10.1039/D4OB00182F, CommunicationHe Miao, Siqian Lu, Hongyu Chen, Jintao Shang, Jibin Zheng, You Yang Additive-assisted α-selective Kdo glycosylation using a peracetylated Kdo ynenoate is described for stereoselective synthesis of the protected trisaccharide variant relevant to the lipopolysaccharide ofCoxiella burnetii strain Nine Mile. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Organic and Biomolecular Chemistry)
Source: RSC - Organic and Biomolecular Chemistry - February 28, 2024 Category: Molecular Biology Authors: He Miao Source Type: research