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Lithium polyacrylate as lithium and carbon source in the synthesis of Li3VO4for high-rate and long-life Li-ion batteries
ChemSusChem. 2023 Aug 9:e202300979. doi: 10.1002/cssc.202300979. Online ahead of print.ABSTRACTLi3VO4 is a promising anode material for use in lithium-ion batteries, however, the conventional synthesis methods for Li3VO4 anodes involve the separate use of lithium and carbon sources, resulting in inefficient contact and low crystalline quality. Herein, we utilized lithium polyacrylate (LiPAA) as a dual-functional source and employed an in-situ polymerization followed by a spray-drying method to synthesize Li3VO4. LiPAA serves a dual purpose, acting as both a lithium source to improve the crystal process and a carbon source ...
Source: ChemSusChem - August 9, 2023 Category: Chemistry Authors: Haokun Yan Cunyuan Pei Yan Zhang Yiwei Zhao Xun Chen Zongping Zhang Dongmei Zhang Bing Sun Huijuan Ma Shibing Ni Source Type: research
Sulfur-Decorated Ti < sub > 3 < /sub > C < sub > 2 < /sub > T < sub > X < /sub > MXene for High-Performance Sodium/Potassium-Ion Batteries
Chem Asian J. 2023 Aug 9:e202300336. doi: 10.1002/asia.202300336. Online ahead of print.ABSTRACTAs post-lithium ion batteries, both sodium-ion batteries (SIBs) and potassium ion batteries (PIBs) possess great potential for large scale energy storage. However, the application of both SIBs and PIBs are hindered by the lack of suitable electrode materials. Here, we synthesized the sulfur decorated Ti3 C2 Tx (S-T3 C2 Tx ) MXene as electrode material for SIBs and PIBs. Thanks to the sulfur functional group and the formation of Ti-S bond, which facilitates the sodium in-/desertion and strengthens the potassium ion adsorption abi...
Source: Chemistry, an Asian Journal - August 9, 2023 Category: Chemistry Authors: Zhendong Guo Guangsheng Dong Man Zhang Musen Gao Leijun Shao Meng Chen Hongli Liu Mingchen Ni Dianxue Cao Kai Zhu Source Type: research
A high-performance TPGDA/PETEA composite gel polymer electrolyte for lithium metal batteries
Chem Commun (Camb). 2023 Aug 9. doi: 10.1039/d3cc02598e. Online ahead of print.ABSTRACTA gel polymer electrolyte (GPE) supported by a polyimide (PI) nanofiber membrane with Li6.5La3Zr1.5Ta0.5O12 (LLZTO) nanoparticles (PI/LLZTO/GPE) shows excellent flexibility and electrochemical properties, the ionic conductivity is 1.87 mS cm-1 and the Li+ transfer number is 0.64 at room temperature. The assembled Li metal battery with a LiFePO4 (LFP) cathode retains a 56.4 mA h g-1 discharge capacity at 10C.PMID:37554079 | DOI:10.1039/d3cc02598e
Source: Chemical Communications - August 9, 2023 Category: Chemistry Authors: Zhifu Chen Quan Pei Zhitao An Yiting Tong Qingfeng Zhang Shuhong Xie Source Type: research
An Increase in Peroxiredoxin 6 Expression Induces Neurotoxic A1 Astrocytes in the Lumbar Spinal Cord of Amyotrophic Lateral Sclerosis Mice Model
In this study, we observed that the expression of peroxiredoxin 6 (PRDX6), a member of the peroxiredoxin family, was markedly upregulated in astrocytes of the lumbar spinal cord of SOD1G93A mice model for ALS. Additionally, when PRDX6 was transiently transfected into the mouse astrocyte cell line C8-D1A and human astrocytoma cell line U-251 MG, the mRNA expression of complement C3 (a marker for A1 astrocyte phenotype) and inflammatory cytokines was increased. Furthermore, the mRNA expression of C3 and inflammatory cytokine was increased in C8-D1A and U-251 MG cells stably expressing PRDX6, and the increased mRNA expression...
Source: Neurochemical Research - August 9, 2023 Category: Neuroscience Authors: Akiko Yamamuro-Tanabe Yurika Mukai Wataru Kojima Siyuan Zheng Naoko Matsumoto Shoho Takada Mao Mizuhara Yasuhiro Kosuge Yuki Ishimaru Yasuhiro Yoshioka Source Type: research
Sulfur-Decorated Ti < sub > 3 < /sub > C < sub > 2 < /sub > T < sub > X < /sub > MXene for High-Performance Sodium/Potassium-Ion Batteries
Chem Asian J. 2023 Aug 9:e202300336. doi: 10.1002/asia.202300336. Online ahead of print.ABSTRACTAs post-lithium ion batteries, both sodium-ion batteries (SIBs) and potassium ion batteries (PIBs) possess great potential for large scale energy storage. However, the application of both SIBs and PIBs are hindered by the lack of suitable electrode materials. Here, we synthesized the sulfur decorated Ti3 C2 Tx (S-T3 C2 Tx ) MXene as electrode material for SIBs and PIBs. Thanks to the sulfur functional group and the formation of Ti-S bond, which facilitates the sodium in-/desertion and strengthens the potassium ion adsorption abi...
Source: Chemistry, an Asian Journal - August 9, 2023 Category: Chemistry Authors: Zhendong Guo Guangsheng Dong Man Zhang Musen Gao Leijun Shao Meng Chen Hongli Liu Mingchen Ni Dianxue Cao Kai Zhu Source Type: research
Hybrid Sub-1 nm Nanosheets of Co-assembled MnZnCuOx and Polyoxometalate Clusters as Anodes for Li-ion Batteries
Angew Chem Int Ed Engl. 2023 Aug 8:e202309934. doi: 10.1002/anie.202309934. Online ahead of print.ABSTRACTHybrid Sub-1 nm Nanosheets of Co-assembled MnZnCuOx and Polyoxometalate Clusters as Anodes for Li-ion BatteriesTransition metal oxide (TMO) anode materials in lithium-ion batteries (LIBs) usually suffer from serious volume expansion leading to the pulverization of structures, further giving rise to lower specific capacity and worse cycling stability. Herein, by introducing polyoxometalate (POM) clusters into TMOs and precisely controlling the amount of POMs, the MnZnCuOx-phosphomolybdic acid hybrid sub-1 nm nanosheets ...
Source: Angewandte Chemie - August 8, 2023 Category: Chemistry Authors: Guobao Yuan Huaiyun Ge Wenxiong Shi Junli Liu Yu Zhang Xun Wang Source Type: research
Ammonium fluoride induced barrier-free and oxygen vacancies enhanced LLZO powder for fast interfacial lithium-ion transport in composite solid electrolytes
J. Mater. Chem. A, 2023, Accepted Manuscript DOI: 10.1039/D3TA03195K, PaperZiwen Pan, Shiyu Cao, Xinqi Lu, Gang Zhang, Qiang Shen, Chong Mao, Xiaobing Dai, Fei Chen The interphase structure and Li-ion transport across interface are essential for high-performance composite solid electrolytes (CPEs). Tailoring the interface between rigid inorganic solid electrolyte fillers and polymer electrolyte matrix is... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - J. Mater. Chem. latest articles - August 7, 2023 Category: Chemistry Authors: Ziwen Pan Source Type: research
Lithium isotope tracing in silicon based electrodes using solid-state MAS NMR: a powerful comprehensive tool for the characterization of lithium battery
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Manon Berthault, Anton Buzlukov, Lionel Dubois, Pierre-Alain Bayle, Willy Porcher, Thibaut Gutel, Eric De Vito, Michel Bardet The introduction of lithiated components with different 7Li/6Li isotopic ratio, also called isotopic tracing, can give access to better understanding of the lithium transport and lithiation processes in lithium-ion batteries.... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Phys. Chem. Chem. Phys. latest articles - August 7, 2023 Category: Chemistry Authors: Manon Berthault Source Type: research
Modelling Electro-Chemically Induced Stresses in All-Solid-State Batteries: Screening Electrolyte and Cathode Materials in Composite Cathodes
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Robert M ücke, Najma Yaqoob, Martin Finsterbusch, Fadi Al-Jaljouli, Payam Kaghazchi, Dina Fattakhova-Rohlfing, Olivier Guillon All-solid-state lithium batteries (ASSBs) are gaining significant attention worldwide as one of the most promising alternatives to lithium-ion batteries due to their superior safety and potentially higher energy density. However,... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - J. Mater. Chem. latest articles - August 7, 2023 Category: Chemistry Authors: Robert M ücke Source Type: research
Continuous Wet Chemical Synthesis of Mo(C,N,O)x as Anode Materials for Li-Ion Batteries
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Mana Abdirahman Mohamed, Stefanie Arnold, Oliver Janka, Antje Quade, J örg Schmauch, Volker Presser, Guido Kickelbick Molybdenum carbides, oxides, and mixed anionic carbide-nitride-oxides Mo(C,N,O)x are potential anode materials for lithium-ion batteries. Here we present the preparation of hybrid inorganic-organic precursors by a precipitation reaction of ammonium... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - J. Mater. Chem. latest articles - August 7, 2023 Category: Chemistry Authors: Mana Abdirahman Mohamed Source Type: research
Combined pyro-hydrometallurgical technology for recovering valuable metal elements from spent lithium-ion batteries: a review of recent developments
Green Chem., 2023, Advance Article DOI: 10.1039/D3GC01077E, Tutorial ReviewMinyu He, Xi Jin, Xiaogang Zhang, Xinxi Duan, Pengyang Zhang, Liumei Teng, Qingcai Liu, Weizao Liu A combined pyro-metallurgical process with green chemistry principles for the recycling of valuable metals from spent lithium-ion batteries is reviewed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Green Chem. latest articles - August 7, 2023 Category: Chemistry Authors: Minyu He Source Type: research
Stepwise recycling of valuable metals from spent lithium-ion batteries based on in situ thermal reduction and ultrasonic-assisted water leaching
Green Chem., 2023, Advance Article DOI: 10.1039/D3GC01673K, PaperWei Ding, Shenxu Bao, Yimin Zhang, Liuyi Ren, Chunfu Xin, Bo Chen, Bo Liu, Junhui Xiao, Xiaochuan Hou A breakthrough method is proposed for stepwise recovering valuable metals from spent entire lithium-ion batteries.In-situ thermal reduction combined with ultrasonic-assisted water leaching can be used to efficiently and selectively recover lithium. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Green Chem. latest articles - August 7, 2023 Category: Chemistry Authors: Wei Ding Source Type: research
Anion-tethered Single Lithium-ion Conducting Polyelectrolytes through UV-induced Free Radical Polymerization for Improved Morphological Stability of Lithium Metal Anodes
In this study, we fabricated a SIC electrolyte using a single-step UV polymerization approach. The resulting electrolyte exhibited a high Li+ transference number (t+) of 0.85 and demonstrated good Li+ conductivity (6.3×10-5 S/cm at room temperature), which is comparable to that of a benchmark dual ion conductor (DIC, 9.1×10-5 S/cm). Benefitting from the high transference number of SIC, it displayed a three-fold higher critical current density (2.4 mA/cm2) compared to DIC (0.8 mA/cm2) by successfully suppressing concentration polarization-induced short-circuiting. Additionally, the t+ significantly influenced the depositi...
Source: Angewandte Chemie - August 7, 2023 Category: Chemistry Authors: Yubin He Chunyang Wang Peichao Zou Ruoqian Lin Enyuan Hu Huolin L Xin Source Type: research
