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Drug: Lithium

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Common changes in rat cortical gene expression after valproate or lithium treatment particularly affect pre- and post-synaptic pathways that regulate four neurotransmitters systems
CONCLUSIONS: Our study suggests that treating with mood stabilisers cause many common changes in levels of RNA which will impact on CNS function, particularly affecting post-synaptic muscarinic receptor functioning and the release of multiple neurotransmitters.PMID:37722808 | DOI:10.1080/15622975.2023.2258972
Source: The World Journal of Biological Psychiatry - September 18, 2023 Category: Psychiatry Authors: Brian Dean Elizabeth Scarr Source Type: research

Boosting the Cell Performance of the SiO/Cu and SiO/PPy Anodes via In-Situ Reduction/Oxidation Coating Strategies
Chemistry. 2023 Sep 18:e202302369. doi: 10.1002/chem.202302369. Online ahead of print.ABSTRACTSilicon monoxide (SiO) has attracted great attention due to its high theoretical specific capacity as an alternative material for conventional graphite anode, but its poor electrical conductivity and irreversible side reactions at the SiO/electrolyte interface seriously reduce its cycling stability. Here, to overcome the drawbacks, the dicharged SiO anode coated with Cu coating layer is elaborately designed by in-situ reduction method. Compared with the pristine SiO anode of lithium-ion battery (293 mAh g-1 at 0.5 A g-1 after 200 ...
Source: Chemistry - September 18, 2023 Category: Chemistry Authors: Tan Luo Yanyun Che Xingjie Lu Guifang Wang Jinming Cai Jianchen Lu Jianhong Yi Dong Fang Source Type: research

Partial and Complete Replacement of the Phenyl Group(s)  of 1,1,3,3-Tetraphenyl-2,2,4,4-tetrakis(trimethylsilyl)cyclotetrasilane by Chlorine Atom(s)
Chemistry. 2023 Sep 18:e202302479. doi: 10.1002/chem.202302479. Online ahead of print.ABSTRACTThe four phenyl groups of 1,1,3,3-tetraphenyl-2,2,4,4-tetrakis(trimethylsilyl)cyclotetrasilane were partially replaced by chlorine atom(s) by successive treatment with trifluoromethanesulfonic acid and lithium chloride. The replacement of all phenyl groups was carried out with hydrogen chloride in the presence of aluminum chloride. The structural features of the resulting mono-, di-, and tetrachlorocyclotetrasilanes were compared by X-ray crystallography.PMID:37720978 | DOI:10.1002/chem.202302479
Source: Chemistry - September 18, 2023 Category: Chemistry Authors: Shintaro Ishida Yosuke Ishii Tetsuya Fukasawa Soichiro Kyushin Source Type: research

Intrinsic Stress-strain in Barium Titanate Piezocatalysts Enabling Lithium-Oxygen Batteries with Low Overpotential and Long Life
Angew Chem Int Ed Engl. 2023 Sep 18:e202311739. doi: 10.1002/anie.202311739. Online ahead of print.ABSTRACTRechargeable lithium-oxygen (Li-O2) batteries with high theoretical energy density are considered as promising candidates for portable electronic devices and electric vehicles, whereas their commercial application is hindered due to poor cyclic stability caused by the sluggish kinetics and cathode passivation. Herein, the intrinsic stress originated from the growth and decomposition of the discharge product (lithium peroxide, Li2O2) is employed as a microscopic pressure resource to induce the built-in electric field, ...
Source: Angewandte Chemie - September 18, 2023 Category: Chemistry Authors: Li-Jun Zheng Li-Na Song Xiao-Xue Wang Shuang Liang Huan-Feng Wang Xing-Yuan Du Ji-Jing Xu Source Type: research

Common changes in rat cortical gene expression after valproate or lithium treatment particularly affect pre- and post-synaptic pathways that regulate four neurotransmitters systems
CONCLUSIONS: Our study suggests that treating with mood stabilisers cause many common changes in levels of RNA which will impact on CNS function, particularly affecting post-synaptic muscarinic receptor functioning and the release of multiple neurotransmitters.PMID:37722808 | DOI:10.1080/15622975.2023.2258972
Source: The World Journal of Biological Psychiatry - September 18, 2023 Category: Psychiatry Authors: Brian Dean Elizabeth Scarr Source Type: research

A phthalocyanine-based porous organic polymer for a lithium-ion battery anode
Dalton Trans., 2023, Advance Article DOI: 10.1039/D3DT02548A, PaperLihua Guo, Chunhua Li, Yougui Zhou, Xinmeng Hao, Huipeng Li, Hong Shang, Bing Sun A phthalocyanine-based porous organic polymer was constructedin situ on copper foil directly used as an anode without any binder or conductive additives, exhibiting great potential for high-energy density lithium-ion batteries. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Dalton Trans. latest articles - September 18, 2023 Category: Chemistry Authors: Lihua Guo Source Type: research

Functional Polymers as Artificial Solid Electrolyte Interface for Stabilizing Lithium Metal Anode
ChemSusChem. 2023 Sep 17:e202301228. doi: 10.1002/cssc.202301228. Online ahead of print.ABSTRACTThe practical implementation of the lithium metal anode (LMA) has long been pursued due to its extremely high specific capacity and low electrochemical equilibrium potential. However, the unstable interfaces resulting from lithium ultrahigh reactivity have significantly hindered the use of LMA. This instability directly leads to dendrite growth behavior, dead lithium, low Coulombic efficiency, and even safety concerns. Therefore, artificial solid electrolyte interfaces (ASEI) with enhanced physicochemical and electrochemistry pr...
Source: ChemSusChem - September 17, 2023 Category: Chemistry Authors: Tuoya Naren Ruheng Jiang Guichao Kuang Liangjun Zhou Libao Chen Source Type: research

Research progress on bioleaching recovery technology of spent lithium-ion batteries
Environ Res. 2023 Sep 14:117145. doi: 10.1016/j.envres.2023.117145. Online ahead of print.ABSTRACTBioleaching of lithium-ion batteries is a microbially catalyzed process. Under the action of redox, acid leaching and complexation in the presence of microorganisms, the valuable metals in the cathode material enter the liquid phase as ions and are subsequently recovered from the succeeding process. This technique has the advantages of being inexpensive, environmentally friendly and having simple needs. However, it is still in development and has not yet commercialized. In this paper, the technology is fully discussed based on...
Source: Environmental Research - September 16, 2023 Category: Environmental Health Authors: Jiafeng Li Haijun Zhang Haifeng Wang Baojing Zhang Source Type: research

Graphene/C2N lateral heterostructures as promising anode materials in lithium-ion batteries
In this study, we employ first-principles calculations to... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Phys. Chem. Chem. Phys. latest articles - September 15, 2023 Category: Chemistry Authors: Yawen Chen Source Type: research

Tailoring the growth route of lithium peroxide through the rational design of a sodium-doped nickel phosphate catalyst for lithium –oxygen batteries
Chem. Commun., 2023, Advance Article DOI: 10.1039/D3CC03323F, CommunicationSe-Si Li, Xing-He Zhao, Kai-Xue Wang, Jie-Sheng Chen Sodium-doped nickel phosphate nanorods with optimized electronic structure facilitate the uniform growth of sea cucumber-like Li2O2 with large reaction area. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - September 15, 2023 Category: Chemistry Authors: Se-Si Li Source Type: research

Tailoring the growth route of lithium peroxide through the rational design of a sodium-doped nickel phosphate catalyst for lithium-oxygen batteries
Chem Commun (Camb). 2023 Sep 15. doi: 10.1039/d3cc03323f. Online ahead of print.ABSTRACTTailoring the morphology and structure of Li2O2, the discharge product of lithium-oxygen batteries (LOBs), through the rational design of cathode catalysts is an efficient strategy to promote the electrochemical performance of LOBs. In this work, sodium-doped nickel phosphate nanorods (Na-NiPO NRs) grown on Ni foam (NF) were prepared by the hydrothermal method and subsequent calcination. For the Na-NiPO NRs, the electronic structure could be optimized and abundant void space among the nanorods would provide abundant transport channels. ...
Source: Chemical Communications - September 15, 2023 Category: Chemistry Authors: Se-Si Li Xing-He Zhao Kai-Xue Wang Jie-Sheng Chen Source Type: research

Work-Function-Induced Interfacial Electron/Ion Transport in Carbon Hosts toward Dendrite-Free Lithium Metal Anodes
Angew Chem Int Ed Engl. 2023 Sep 15:e202310132. doi: 10.1002/anie.202310132. Online ahead of print.ABSTRACTCoupled electron/ion transport is a decisive feature of Li plating/stripping, wherein the compatibility of electron/ion transport rates determines the morphology of deposited Li. Local Li+ hotspots form due to inhomogeneous interfacial charge transfer and lead to uncontrolled Li deposition, which decreases the Li utilization rate and safety of Li metal anodes. Herein, we report a method to obtain dendrite-free Li metal anodes by driving electron pumping and accumulating and boosting Li ion diffusion by tuning the work...
Source: Angewandte Chemie - September 15, 2023 Category: Chemistry Authors: Yu-Shuai Feng Yun-Nuo Li Pei Wang Zaiping Guo Fei-Fei Cao Huan Ye Source Type: research