Photocatalytic removal of 17 β-estradiol from water using a novel bimetallic NiCu/Nb < sub > 2 < /sub > O < sub > 5 < /sub > catalyst

In this study, a novel photocatalyst based on niobium pentoxide (Nb2O5) functionalized with nickel (Ni) and copper (Cu) was synthesized for E2 removal. The NiCu/Nb2O5 photocatalyst was prepared using a facile wet impregnation method and characterized by various techniques. The incorporation of Ni and Cu into Nb2O5 reduced the band gap energy from 3.3 to 2.8 eV, enabling efficient utilization of visible light. Moreover, NiCu/Nb2O5 exhibited the highest E2 removal efficiency (82%) under UV-A-assisted conditions at a concentration of 1.5 g L-1. The reaction kinetics were found to follow a second-order model with a rate constant of k = 0.0020 L g-1 min-1, and a plausible reaction mechanism was proposed. Through the study of radical elimination, it was proven that the radical oxidation reaction mechanism predominated in the reaction. The results of the toxicity assays, combined with the TOC parameter, demonstrated the efficacy of photocatalytic degradation in reducing E2. These findings demonstrate the great potential of the NiCu/Nb2O5 photocatalyst for removing persistent pollutants.PMID:37688700 | DOI:10.1007/s11356-023-29727-8
Source: Environmental Science and Pollution Research International - Category: Environmental Health Authors: Source Type: research