On the origin of the electronic and magnetic circular dichroism of naphthyl C-glycosides: Anomeric configuration

In conclusion, reliable ECD patterns cannot be calculated by separating the naphthyl rotation from other conformational motions. MCD patterns have been similar for all the naphthyl C-glycosides studied. No clear diagnostic features have been found for either the pseudoanomeric configuration or the preferred hydroxymethyl rotamer. Nevertheless, the work has demonstrated the potential of MCD for the study of aryl glycosides interacting with proteins.PMID:38171193 | DOI:10.1016/j.carres.2023.109021
Source: Carbohydrate Research - Category: Genetics & Stem Cells Authors: Source Type: research