Quantification of odorous and potentially harmful substances in acrylic paint

Ecotoxicol Environ Saf. 2023 Aug 8;262:115329. doi: 10.1016/j.ecoenv.2023.115329. Online ahead of print.ABSTRACTWithin this study sixteen odour active substances (1-butanol, butyl acetate, 3-methyl-4-heptanone, butyl acrylate, styrene, ethylbenzene, propylbenzene, cumene, sec-butylbenzene, benzaldehyde, 2-ethylhexyl acrylate, naphthalene, 1-methylnaphthalene, 2-methylnaphthalene, 1,2-dimethylnaphthalene, 1,7-dimethylnaphthalene), that have previously been identified in acryl paints were quantified in ten black acrylic paint samples using GC-GC-MS (heart-cut two-dimensional gas chromatography-mass spectrometry) after prior extraction and purification via solvent assisted flavour evaporation. In this case, the preceding analysis of the most abundant odour active volatiles via GC-O (gas chromatography-olfactometry) provided indications on which smell properties might be linked with elevated and concerning levels of possibly harmful substances. Based on that work, four samples raised attention due to their mainly repelling or unpleasant odour with mainly aromatic, solvent-like, mothball-like or geranium-like smell impressions. The remaining samples either showed fruity/fermented, fruity/apple juice-like, mushroom-like or cocoa-like/earthy odour qualities. The repelling and unpleasant odour was generally linked to naphthalene or benzene derivatives that are of concern with regard to being potential carcinogens. With concentrations ranging as high as from 3.75 mg/kg to 143.41 mg/kg...
Source: Ecotoxicology and Environmental Safety - Category: Environmental Health Authors: Source Type: research