Photocatalytic conversion of aryl diazonium salts to sulfonyl fluorides
We present the optimization of this mild method for the synthesis of sulfonyl fluorides, the scope of the transformation with a series of functionalized diazonium salts, and we discuss photophysical measurements that provide detailed information about the mechanism of the photochemical process.PMID:38404686 | PMC:PMC10887421 | DOI:10.1016/j.tet.2023.133364 (Source: Tetrahedron)
Source: Tetrahedron - February 26, 2024 Category: Chemistry Authors: Cooper A Vincent Alexia Ripak Ludovic Troian-Gautier Uttam K Tambar Source Type: research
Photocatalytic conversion of aryl diazonium salts to sulfonyl fluorides
We present the optimization of this mild method for the synthesis of sulfonyl fluorides, the scope of the transformation with a series of functionalized diazonium salts, and we discuss photophysical measurements that provide detailed information about the mechanism of the photochemical process.PMID:38404686 | PMC:PMC10887421 | DOI:10.1016/j.tet.2023.133364 (Source: Tetrahedron)
Source: Tetrahedron - February 26, 2024 Category: Chemistry Authors: Cooper A Vincent Alexia Ripak Ludovic Troian-Gautier Uttam K Tambar Source Type: research
Photocatalytic conversion of aryl diazonium salts to sulfonyl fluorides
We present the optimization of this mild method for the synthesis of sulfonyl fluorides, the scope of the transformation with a series of functionalized diazonium salts, and we discuss photophysical measurements that provide detailed information about the mechanism of the photochemical process.PMID:38404686 | PMC:PMC10887421 | DOI:10.1016/j.tet.2023.133364 (Source: Tetrahedron)
Source: Tetrahedron - February 26, 2024 Category: Chemistry Authors: Cooper A Vincent Alexia Ripak Ludovic Troian-Gautier Uttam K Tambar Source Type: research
Photocatalytic conversion of aryl diazonium salts to sulfonyl fluorides
We present the optimization of this mild method for the synthesis of sulfonyl fluorides, the scope of the transformation with a series of functionalized diazonium salts, and we discuss photophysical measurements that provide detailed information about the mechanism of the photochemical process.PMID:38404686 | PMC:PMC10887421 | DOI:10.1016/j.tet.2023.133364 (Source: Tetrahedron)
Source: Tetrahedron - February 26, 2024 Category: Chemistry Authors: Cooper A Vincent Alexia Ripak Ludovic Troian-Gautier Uttam K Tambar Source Type: research
Photocatalytic conversion of aryl diazonium salts to sulfonyl fluorides
We present the optimization of this mild method for the synthesis of sulfonyl fluorides, the scope of the transformation with a series of functionalized diazonium salts, and we discuss photophysical measurements that provide detailed information about the mechanism of the photochemical process.PMID:38404686 | PMC:PMC10887421 | DOI:10.1016/j.tet.2023.133364 (Source: Tetrahedron)
Source: Tetrahedron - February 26, 2024 Category: Chemistry Authors: Cooper A Vincent Alexia Ripak Ludovic Troian-Gautier Uttam K Tambar Source Type: research
Photocatalytic conversion of aryl diazonium salts to sulfonyl fluorides
We present the optimization of this mild method for the synthesis of sulfonyl fluorides, the scope of the transformation with a series of functionalized diazonium salts, and we discuss photophysical measurements that provide detailed information about the mechanism of the photochemical process.PMID:38404686 | PMC:PMC10887421 | DOI:10.1016/j.tet.2023.133364 (Source: Tetrahedron)
Source: Tetrahedron - February 26, 2024 Category: Chemistry Authors: Cooper A Vincent Alexia Ripak Ludovic Troian-Gautier Uttam K Tambar Source Type: research
Photocatalytic conversion of aryl diazonium salts to sulfonyl fluorides
We present the optimization of this mild method for the synthesis of sulfonyl fluorides, the scope of the transformation with a series of functionalized diazonium salts, and we discuss photophysical measurements that provide detailed information about the mechanism of the photochemical process.PMID:38404686 | PMC:PMC10887421 | DOI:10.1016/j.tet.2023.133364 (Source: Tetrahedron)
Source: Tetrahedron - February 26, 2024 Category: Chemistry Authors: Cooper A Vincent Alexia Ripak Ludovic Troian-Gautier Uttam K Tambar Source Type: research
Photocatalytic conversion of aryl diazonium salts to sulfonyl fluorides
We present the optimization of this mild method for the synthesis of sulfonyl fluorides, the scope of the transformation with a series of functionalized diazonium salts, and we discuss photophysical measurements that provide detailed information about the mechanism of the photochemical process.PMID:38404686 | PMC:PMC10887421 | DOI:10.1016/j.tet.2023.133364 (Source: Tetrahedron)
Source: Tetrahedron - February 26, 2024 Category: Chemistry Authors: Cooper A Vincent Alexia Ripak Ludovic Troian-Gautier Uttam K Tambar Source Type: research
Photocatalytic conversion of aryl diazonium salts to sulfonyl fluorides
We present the optimization of this mild method for the synthesis of sulfonyl fluorides, the scope of the transformation with a series of functionalized diazonium salts, and we discuss photophysical measurements that provide detailed information about the mechanism of the photochemical process.PMID:38404686 | PMC:PMC10887421 | DOI:10.1016/j.tet.2023.133364 (Source: Tetrahedron)
Source: Tetrahedron - February 26, 2024 Category: Chemistry Authors: Cooper A Vincent Alexia Ripak Ludovic Troian-Gautier Uttam K Tambar Source Type: research
Photocatalytic conversion of aryl diazonium salts to sulfonyl fluorides
We present the optimization of this mild method for the synthesis of sulfonyl fluorides, the scope of the transformation with a series of functionalized diazonium salts, and we discuss photophysical measurements that provide detailed information about the mechanism of the photochemical process.PMID:38404686 | PMC:PMC10887421 | DOI:10.1016/j.tet.2023.133364 (Source: Tetrahedron)
Source: Tetrahedron - February 26, 2024 Category: Chemistry Authors: Cooper A Vincent Alexia Ripak Ludovic Troian-Gautier Uttam K Tambar Source Type: research
Photocatalytic conversion of aryl diazonium salts to sulfonyl fluorides
We present the optimization of this mild method for the synthesis of sulfonyl fluorides, the scope of the transformation with a series of functionalized diazonium salts, and we discuss photophysical measurements that provide detailed information about the mechanism of the photochemical process.PMID:38404686 | PMC:PMC10887421 | DOI:10.1016/j.tet.2023.133364 (Source: Tetrahedron)
Source: Tetrahedron - February 26, 2024 Category: Chemistry Authors: Cooper A Vincent Alexia Ripak Ludovic Troian-Gautier Uttam K Tambar Source Type: research
Synthesis of L-cyclic tetrapeptides by backbone amide activation CyClick strategy
Tetrahedron. 2022 Nov 5;126:133071. doi: 10.1016/j.tet.2022.133071. Epub 2022 Oct 5.ABSTRACTCyclic tetrapeptides exhibit high cellular permeability and a wide range of biological properties and thus have gained great interest in the field of medicinal chemistry. We synthesized highly strained 12-membered head to tail cyclic peptides with varying reactive amino acids, without oligomerization using the exclusively intramolecular CyClick chemistry. This occurs by a two-step process involving the low-energy formation of a 15 atom-containing cyclic imine, followed by a chemoselective ring contraction of the peptide backbone gen...
Source: Tetrahedron - November 23, 2023 Category: Chemistry Authors: Rachel Wills Victor Adebomi Caroline Spancake Ryan D Cohen Monika Raj Source Type: research
Synthesis of L-cyclic tetrapeptides by backbone amide activation CyClick strategy
Tetrahedron. 2022 Nov 5;126:133071. doi: 10.1016/j.tet.2022.133071. Epub 2022 Oct 5.ABSTRACTCyclic tetrapeptides exhibit high cellular permeability and a wide range of biological properties and thus have gained great interest in the field of medicinal chemistry. We synthesized highly strained 12-membered head to tail cyclic peptides with varying reactive amino acids, without oligomerization using the exclusively intramolecular CyClick chemistry. This occurs by a two-step process involving the low-energy formation of a 15 atom-containing cyclic imine, followed by a chemoselective ring contraction of the peptide backbone gen...
Source: Tetrahedron - November 23, 2023 Category: Chemistry Authors: Rachel Wills Victor Adebomi Caroline Spancake Ryan D Cohen Monika Raj Source Type: research
Synthesis of L-cyclic tetrapeptides by backbone amide activation CyClick strategy
Tetrahedron. 2022 Nov 5;126:133071. doi: 10.1016/j.tet.2022.133071. Epub 2022 Oct 5.ABSTRACTCyclic tetrapeptides exhibit high cellular permeability and a wide range of biological properties and thus have gained great interest in the field of medicinal chemistry. We synthesized highly strained 12-membered head to tail cyclic peptides with varying reactive amino acids, without oligomerization using the exclusively intramolecular CyClick chemistry. This occurs by a two-step process involving the low-energy formation of a 15 atom-containing cyclic imine, followed by a chemoselective ring contraction of the peptide backbone gen...
Source: Tetrahedron - November 23, 2023 Category: Chemistry Authors: Rachel Wills Victor Adebomi Caroline Spancake Ryan D Cohen Monika Raj Source Type: research
Synthesis of L-cyclic tetrapeptides by backbone amide activation CyClick strategy
Tetrahedron. 2022 Nov 5;126:133071. doi: 10.1016/j.tet.2022.133071. Epub 2022 Oct 5.ABSTRACTCyclic tetrapeptides exhibit high cellular permeability and a wide range of biological properties and thus have gained great interest in the field of medicinal chemistry. We synthesized highly strained 12-membered head to tail cyclic peptides with varying reactive amino acids, without oligomerization using the exclusively intramolecular CyClick chemistry. This occurs by a two-step process involving the low-energy formation of a 15 atom-containing cyclic imine, followed by a chemoselective ring contraction of the peptide backbone gen...
Source: Tetrahedron - November 23, 2023 Category: Chemistry Authors: Rachel Wills Victor Adebomi Caroline Spancake Ryan D Cohen Monika Raj Source Type: research
