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Exploring electrolyte effects on metal –alkyl bond stability: impact and implications for electrosynthesis
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Dylan G. Boucher, Zachary A. Nguyen, Shelley D. Minteer We explore the often neglected impact of supporting electrolyte on homogeneous electrocatalytic mechanisms using the catalytic reduction of benzyl chloridesvia Co and Fe tetraphenylporphyrins as a model reaction. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - July 25, 2023 Category: Chemistry Authors: Dylan G. Boucher Source Type: research

Concluding remarks -- lontronics, from fundamentals to ion-controlled devices: Random Access Memories
Faraday Discuss., 2023, Accepted Manuscript DOI: 10.1039/D3FD00138E, PaperLyderic Bocquet (no abstract) The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - July 25, 2023 Category: Chemistry Authors: Lyderic Bocquet Source Type: research

Understanding the Impact of Ammonium Ion Substitutions on Heterogeneous Ice Nucleation
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Katarina Blow, Thomas F. Whale, David Quigley, Gabriele Cesare Sosso Understanding the mechanisms underpinning heterogeneous ice nucleation in the presence of ionic inclusions is important for fields such as cryopreservation and for improved models of climate and weather prediction. Feldspar... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - July 24, 2023 Category: Chemistry Authors: Katarina Blow Source Type: research

Make – underpinning concepts of the synthesis of systems where non-covalent interactions are important: general discussion
DiscussionTorsten Beweries, Michael R. Buchmeiser, Frances E. Bugden, Neil R. Champness, Basheer Chanbasha, Miquel Costas, Jorge Echeverria, Odile Eisenstein, Calum Ferguson, Joe C. Goodall, Rafael Gramage-Doria, Mark Greenhalgh, Matthew Gyton, Rens Ham, Pierre Kennepohl, Bartosz Lewandowski, Wei-Chun Liu, Stuart A. Macgregor, Kamran T. Mahmudov, Eva Meeus, Josh Morris, Pinkie Ntola, Tatjana N. Parac-Vogt, Robin N. Perutz, Albert Poater, David Powers, Paul R. Raithby, Joost N. H. Reek, Imogen Riddell, Thomas R. Ward, Andrew S. Weller, Helma Wennemers To cite this article before page numbers are assigned, use the DOI form o...
Source: RSC - Faraday Discuss. latest articles - July 24, 2023 Category: Chemistry Authors: Torsten Beweries Source Type: research

Properties of aqueous electrolyte solutions at carbon electrodes: effects of concentration and surface charge on solution structure, ion clustering and thermodynamics in the electric double layer
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Aaron R. Finney, Matteo Salvalaglio Surfaces are able to control physical-chemical processes in multi-component solution systems and, as such, find application in a wide range of technological devices. Understanding the structure, dynamics and thermodynamics of... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - July 22, 2023 Category: Chemistry Authors: Aaron R. Finney Source Type: research

Effect of [Na+]/[Li+] concentration ratios in brines on lithium carbonate production through membrane electrolysis
Faraday Discuss., 2023, Advance Article DOI: 10.1039/D3FD00051F, PaperWalter R. Torres, Nadia C. Zeballos, Victoria Flexer Lithium carbonate is crystallized from a complex mixture of Li+, Na+ and K+ chlorides in a water electrolyzer where CO2 is absorbed. The efficiency of the process is studied upon increasing the Na+/Li+ concentration ratios. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - July 21, 2023 Category: Chemistry Authors: Walter R. Torres Source Type: research

Primary vs. secondary alkylpyridinium salts: a comparison under electrochemical and chemical reduction conditions
Faraday Discuss., 2023, Advance Article DOI: 10.1039/D3FD00120B, PaperBria Garcia, Jessica Sampson, Mary P. Watson, Dipannita Kalyani For primary and secondary alkylpyridinium salts, trends in ArBr scope are similar, and electrochemical conditions compare well to chemical methods. Our study offers increased understanding in the application of deaminative reductive cross-couplings. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - July 21, 2023 Category: Chemistry Authors: Bria Garcia Source Type: research

Insight into the K channel ’s selectivity from binding of K+, Na+ and water to N-methylacetamide†
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Mark Stevens, Susan B. Rempe In potassium channels that conduct K+ selectively over Na+, which sites are occupied by K+ or water and the mechanism of selectivity are unresolved questions. The combination of the energetics... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - July 21, 2023 Category: Chemistry Authors: Mark Stevens Source Type: research

Model – state-of-the-art modelling and computational analysis of reactive sites: general discussion
DiscussionBasheer Chanbasha, Miquel Costas, Jorge Echeverr ía, Odile Eisenstein, Mark Greenhalgh, Pierre Kennepohl, Adam Kirrander, Pim R. Linnebank, Stuart A. Macgregor, Kamran T. Mahmudov, Carlos Martín-Fernández, Eva Meeus, Josh Morris, Robin N. Perutz, Albert Poater, Joost N. H. Reek, Ian Rouse, Dean Toste, Cristina Trujillo, Thomas R. Ward, Julia A. Weinstein, Andrew S. Weller To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - July 21, 2023 Category: Chemistry Authors: Basheer Chanbasha Source Type: research

First-Principles Spectroscopy of Aqueous Interfaces using Machine-Learned Electronic and Quantum Nuclear Effects
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Venkat Kapil, David Peter Kovacs, G ábor Csányi, Angelos Michaelides Vibrational spectroscopy is critical to understanding the structure and dynamics of interfacial water, which plays a key role in natural and technologically-relevant phenomena. However, interpreting the vibrational spectra of complex... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - July 21, 2023 Category: Chemistry Authors: Venkat Kapil Source Type: research

Electrochemical synthesis of the protected cyclic (1,3;1,6)- β-glucan dodecasaccharide
Faraday Discuss., 2023, Advance Article DOI: 10.1039/D3FD00045A, PaperAkito Shibuya, Yui Ishisaka, Asuka Saito, Moeko Kato, Sujit Manmode, Hiroto Komatsu, Md Azadur Rahman, Norihiko Sasaki, Toshiyuki Itoh, Toshiki Nokami A protected cyclic (1,3;1,6)- β-glucan dodecasaccharide was synthesized by the electrochemical one-pot dimerisation–cyclisation of a semi-circular hexasaccharide. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - July 19, 2023 Category: Chemistry Authors: Akito Shibuya Source Type: research

Electrochemical decarboxylation of acetic acid on boron-doped diamond and platinum-functionalised electrodes for pyrolysis-oil treatment
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Talal Ashraf, Ainoa Paradelo Rodriguez, Bastian Timo Mei, Guido Mul Tuning the surface of boron-doped diamond functionalised with platinum nanoparticles and thin films alters the selectivity of hydroxyl-radical-mediated indirect electrooxidation of acetic acid to the Kolbe product. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - July 19, 2023 Category: Chemistry Authors: Talal Ashraf Source Type: research

Photoelectrocatalyzed undirected C –H trifluoromethylation of arenes: catalyst evaluation and scope
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Julia Struwe, Lutz Ackermann More than a dozen different mediators were employed in the trifluoromethylation of (hetero-)arenes to compare them in their efficacies. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - July 19, 2023 Category: Chemistry Authors: Julia Struwe Source Type: research

Core –shell nanostructured Cu-based bi-metallic electrocatalysts for co-production of ethylene and acetate
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Jeannie Z. Y. Tan, Ashween Kaur Virdee, John M. Andresen, M. Mercedes Maroto-Valer A three-compartment alkaline flow-through electrolyser was successfully developed and the single pass conversion of syngas to ethylene achieved was 2.5 mM cm−2 in the optimised conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - July 19, 2023 Category: Chemistry Authors: Jeannie Z. Y. Tan Source Type: research

Self-assembly of random networks of zirconium-doped manganese oxide nanoribbons and poly(3,4-ethylenedioxythiophene) flakes at the water/chloroform interface
Faraday Discuss., 2023, Advance Article DOI: 10.1039/D3FD00077J, PaperSubin Kaladi Chondath, Mini Mol Menamparambath A facile water/chloroform interfacial polymerisation was employed to synthesize PEDOT/Zr-K-OMS-2 (PZrK) microscale films ( ∼21 nm thickness), formed by a random network of PEDOT flakes and Zr-K-OMS-2 nanoribbons. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - July 19, 2023 Category: Chemistry Authors: Subin Kaladi Chondath Source Type: research