Dissociation-Induced Depletion of High-Energy Reactant Molecules as a Mechanism for Pressure-Dependent Rate Constants for Bimolecular Reactions
Faraday Discuss., 2022, Accepted Manuscript DOI: 10.1039/D2FD00054G, PaperM. P. Burke, Qinghui Meng, Christopher Sabaitis In 1922, Lindemann proposed the now-well-known mechanism for pressure-dependent rate constants for unimolecular reactions: reactant molecules with sufficiently high energies dissociate more quickly than collisions can reestablish the Boltzmann distribution... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - May 20, 2022 Category: Chemistry Authors: M. P. Burke Source Type: research

Spiers Memorial Lecture: Prospects for photoelectron spectroscopy
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Wendy Flavell An overview is presented of recent advances in photoelectron spectroscopy, focussing on advances in in situ and time-resolved measurements, and in extending the sampling depth of the technique. The future... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - May 20, 2022 Category: Chemistry Authors: Wendy Flavell Source Type: research

Mechanochemical synthesis of non-stoichiometric copper sulfide Cu1.8S applicable as photocatalyst and antibacterial agent and synthesis scalability verification
Faraday Discuss., 2022, Accepted Manuscript DOI: 10.1039/D2FD00082B, PaperMatej Bal áž, Adrian Augustyniak, Batukhan Talykayev, Zhandos Shalabayev, Gairat Burashev, Erika Dutkova, Nina Daneu, Jaroslav Briančin, Ľudmila Balážová, Ľudmila Tkáčiková, Martin Stahorský, Marcela Achimovičová, Peter Baláž An effort to prepare different non-stoichiometric CuxSy compounds starting from elemental precursors using mechanochemistry was made in this study. However, out of 7 stoichiometries tested, it was only possible to... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - May 18, 2022 Category: Chemistry Authors: Matej Bal áž Source Type: research

Reaction surfaces and interfaces of metal sulfides: cryo-XPS meets HAXPES and DFT
Faraday Discuss., 2022, Advance Article DOI: 10.1039/D1FD00104C, PaperYuri Mikhlin, Vladimir Nasluzov, Yevgeny Tomashevich, Sergey Vorobyev, Alexander Romanchenko, Maxim Likhatski Cryo-XPS study of fast-frozen particulate PbS and ZnS in aqueous solutions allows the minimizing of the distortions of the reaction interfaces. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - May 12, 2022 Category: Chemistry Authors: Yuri Mikhlin Source Type: research

Electron scattering properties of biological macromolecules and their use for cryo-EM map sharpening
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Alok Bharadwaj, Arjen Jakobi Resolution-dependent loss of contrast in cryo-EM maps may obscure features at high resolution that are critical for map interpretation. Post-processing of cryo-EM maps can improve the interpretability by adjusting the... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - May 12, 2022 Category: Chemistry Authors: Alok Bharadwaj Source Type: research

Chemical and electronic structure of the heavily intermixed (Cd,Zn)S:Ga/CuSbS2 interface
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Claudia Hartmann, Riley E. Brandt, Lauryn L Baranowski, Leonard K öhler, Evelyn Handick, Roberto Félix, Regan George Wilks, Andriy Zakutayev, Tonio Buonassisi, Marcus Bär The interface formation and chemical and electronic structure of the (Cd,Zn)S:Ga/CuSbS2 thin-film solar cell heterojunction was studied using hard X-ray photoelectron spectroscopy (HAXPES) of the bare absorber and a buffer/absorber... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - May 11, 2022 Category: Chemistry Authors: Claudia Hartmann Source Type: research

Gently does it!: in situ preparation of alkali metal –solid electrolyte interfaces for photoelectron spectroscopy
Faraday Discuss., 2022, Advance Article DOI: 10.1039/D1FD00118C, PaperJoshua S. Gibson, Sudarshan Narayanan, Jack E. N. Swallow, Pardeep Kumar-Thakur, Mauro Pasta, Tien-Lin Lee, Robert S. Weatherup In situ deposition is critical to studying interfacial reactions between alkali-metals and solid electrolytes. The species formed on Li6PS5Cl are found to vary with deposition method, with impingement of more energetic atoms causes physical damage. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - May 11, 2022 Category: Chemistry Authors: Joshua S. Gibson Source Type: research

Dynamics over a Cu –graphite electrode during the gas-phase CO2 reduction investigated by APXPS
Faraday Discuss., 2022, Advance Article DOI: 10.1039/D1FD00121C, PaperRosa Arrigo, Raoul Blume, Alexander Ian Large, Juan Jesus Velasco-V élez, Michael Hävecker, Axel Knop-Gericke, Georg Held We use ambient pressure X-ray photoelectron and absorption spectroscopies coupled with on-line gas detection to investigatein situ performance and interface chemistry of an electrodeposited Cu on a carbon support under conditions of CO2 reduction. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - May 11, 2022 Category: Chemistry Authors: Rosa Arrigo Source Type: research

Resonant X-ray photoelectron spectroscopy: identification of atomic contributions to valence states
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.J.  M. Seymour, E. Gousseva, R. A. Bennett, A. I. Large, G. Held, D. Hein, G. Wartner, W. Quevedo, R. Seidel, C. Kolbeck, C. J. Clarke, R. M. Fogarty, R. A. Bourne, R. G. Palgrave, P. A. Hunt, K. R. J. Lovelock We demonstrate the validity of using valence resonant X-ray photoelectron spectroscopy to identify atomic contributions for both solutes and solvents. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - May 11, 2022 Category: Chemistry Authors: J.  M. Seymour Source Type: research

Evolution of surface and sub-surface morphology and chemical state of exsolved Ni nanoparticles
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Heath Kersell, Moritz  L. Weber, Lorenz Falling, Qiyang Lu, Christoph Baeumer, Nozomi Shirato, Volker Rose, Christian Lenser, Felix Gunkel, Slavomír Nemšák Dynamic surface and subsurface morphology and chemistry of socketed nanoparticles is monitoredin situ for an important emerging class of nanoparticles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - May 11, 2022 Category: Chemistry Authors: Heath Kersell Source Type: research

Spiers Memorial Lecture: Assembly-based pathways of crystallization
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.James J. De Yoreo, Elias Nakouzi, Biao Jin, Jaehun Chun, Christopher J. Mundy We review recent investigations into crystal growth by particle attachment, with an emphasis on oriented attachment. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - May 10, 2022 Category: Chemistry Authors: James J. De Yoreo Source Type: research

Characterization of buried interfaces using Ga K α hard X-ray photoelectron spectroscopy (HAXPES)
Faraday Discuss., 2022, Advance Article DOI: 10.1039/D2FD00021K, PaperB. F. Spencer, S. A. Church, P. Thompson, D. J. H. Cant, S. Maniyarasu, A. Theodosiou, A. N. Jones, M. J. Kappers, D. J. Binks, R. A. Oliver, J. Higgins, A. G. Thomas, T. Thomson, A. G. Shard, W. R. Flavell HAXPES enables the detection of buried interfaces with an increased photo electron sampling depth. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - May 9, 2022 Category: Chemistry Authors: B. F. Spencer Source Type: research

Small molecule activation and synthetic analogues: general discussion
DiscussionLeigh Aldous, Peter Comba, Serena DeBeer, Abhishek Dey, Apparao Draksharapu, Carole Duboc, Shinobu Itoh, Kenneth Karlin, Subrata Kundu, Roc ío López Domene, Jean-Didier Maréchal, Shyamalava Mazumdar, Rabindranath Mukherjee, David Parker, Anca Pordea, Lawrence Que, Sankar Prasad Rath, Peter Sadler, Chivukula Sastri, Siegfried Schindler, Volker Schünemann, Sayam Sen Gupta, Edward I. Solomon, T. Daniel P. Stack To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - May 9, 2022 Category: Chemistry Authors: Leigh Aldous Source Type: research

Selective hydrogenation of graphene on Ir(111): an X-ray standing wave study
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Claus F. P. Kastorp, David A. Duncan, Anders  L. Jørgensen, Martha Scheffler, John D. Thrower, Tien-Lin Lee, Liv Hornekær, Richard Balog Graphene on Ir(111) was hydrogenated selectively in the HCP and FCC regions by controlling the substrate temperature during exposure. Hydrogenated carbon in these areas both form ordered clusters, but are found to contribute to different components. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (So...
Source: RSC - Faraday Discuss. latest articles - May 6, 2022 Category: Chemistry Authors: Claus F. P. Kastorp Source Type: research

Electron transfer, spectroscopy and theory: general discussion
DiscussionAnjali Anilkumar, Philip Ash, Akhil R. Chakravarty, Peter Comba, Serena DeBeer, Abhishek Dey, Apparao Draksharapu, Debabrata Goswami, Shinobu Itoh, Kenneth Karlin, K.  V. Lakshmi, Shyamalava Mazumdar, Dimitrios Pantazis, David Parker, Lawrence Que, Gopalan Rajaraman, Sankar Prasad Rath, Chivukula Sastri, Sayam Sen Gupta, Edward I. Solomon To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - May 5, 2022 Category: Chemistry Authors: Anjali Anilkumar Source Type: research