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A phenazine-based conjugated microporous polymer as a high performing cathode for aluminium –organic batteries
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Rebecca Grieco, Olivera Luzanin, Diego Alvan, Marta Liras, Robert Dominko, Nagaraj Patil, Jan Bitenc, Rebeca Marcilla A phenazine-based conjugated microporous polymer cathode provides high cycle stability (75% retention after 127 days), low capacity fade (0.19 mA h g−1 per day) and excellent rate capability (62 mA h g−1; 54% retention at 50C). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - November 21, 2023 Category: Chemistry Authors: Rebecca Grieco Source Type: research

An organic transistor for detecting the oxidation of an organic sulfur compound at a solid –liquid interface and its chemical sensing applications
Faraday Discuss., 2023, Advance Article DOI: 10.1039/D3FD00149K, PaperYui Sasaki, Yijing Zhang, Kohei Ohshiro, Kazuhiko Tsuchiya, Xiaojun Lyu, Masao Kamiko, Yoshinori Ueno, Hikaru Tanaka, Tsuyoshi Minami An OFET device enables the simultaneous detection of the reversible and irreversible oxidation of an organic sulfur compound by H2O2 at a solid –liquid interface, which was applied to the monitoring of an enzymatic reaction in an aqueous solution. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Farada...
Source: RSC - Faraday Discuss. latest articles - November 17, 2023 Category: Chemistry Authors: Yui Sasaki Source Type: research

Excited-state dynamics of C3-symmetric heptazine-based thermally activated delayed-fluorescence emitters
Faraday Discuss., 2023, Advance Article DOI: 10.1039/D3FD00121K, PaperKatrina Bergmann, Zachary M. Hudson The excited-state character and symmetry of four heptazine-based TADF materials with C3-symmetric ground states are investigated to explain differences in their photophysical properties and rates of reverse intersystem crossing. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - November 17, 2023 Category: Chemistry Authors: Katrina Bergmann Source Type: research

Giant Seebeck effect over 0.1  V K−1 – is this an intrinsic phenomenon in organic semiconductors?
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Masakazu Nakamura, Hirotaka Kojima, Ryo Abe, Yongyoon Cho, Shotaro Hayashi, Masahiro Hiramoto The mechanism of the giant Seebeck effect over 0.1 V K−1 in pure organic semiconductors is discussed based on recent experimental findings. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - November 16, 2023 Category: Chemistry Authors: Masakazu Nakamura Source Type: research

Effects of halogen atom substitution on luminescent radicals: a case study on tris(2,4,6-trichlorophenyl)methyl radical-carbazole dyads
Faraday Discuss., 2023, Advance Article DOI: 10.1039/D3FD00130J, PaperKazuhiro Nakamura, Kenshiro Matsuda, Rui Xiaotian, Minori Furukori, Satoshi Miyata, Takuya Hosokai, Kosuke Anraku, Kohei Nakao, Ken Albrecht A series of halogenated carbazole-TTM radical dyads are evaluated, and the absence of heavy atom effects was systematically studied. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - November 15, 2023 Category: Chemistry Authors: Kazuhiro Nakamura Source Type: research

Study of the electron-doping mechanism in single-walled carbon nanotubes using dimethylbenzimidazole
Faraday Discuss., 2023, Advance Article DOI: 10.1039/D3FD00128H, PaperN. Tanaka, I. Yamaguchi, R. Yamaguchi, T. Fujigaya The presence of O2 was found to cause the reduction of O2 on the SWCNT surface in protic solvent, resulting in production of dimethylbenzimidazole cations and water through proton-coupled electron transfer from the n-doped SWCNT and ethanol. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - November 15, 2023 Category: Chemistry Authors: N. Tanaka Source Type: research

High-performance n-type organic thermoelectrics enabled by modulating cyano-functionalized polythiophene backbones
Faraday Discuss., 2023, Advance Article DOI: 10.1039/D3FD00135K, PaperJunwei Wang, Suxiang Ma, Sang Young Jeong, Wanli Yang, Jianfeng Li, Young Woo Han, Kui Feng, Xugang Guo Via modulating cyano-functionalized polythiophene backbones, the new polymer CNg4T2-CNT2 delivered an impressive n-type power factor of 10.84 μW m−1 K−2 with a high conductivity of 13.2 S cm−1. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - November 15, 2023 Category: Chemistry Authors: Junwei Wang Source Type: research

Photocatalytic CO2 reduction by topologically matched polymer –polymer heterojunction nanosheets
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Catherine M. Aitchison, Yu Zhang, Wanpeng Lu, Iain McCulloch 2D donor –acceptor polymer heterojunctions formedvia templation are found to give materials with higher photocatalytic activity than the individual semiconductor components. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - November 15, 2023 Category: Chemistry Authors: Catherine M. Aitchison Source Type: research

Single-crystalline oligomer-based conductors modeling the doped poly(3,4-ethylenedioxythiophene) family
Faraday Discuss., 2023, Advance Article DOI: 10.1039/D3FD00134B, PaperTomoko Fujino, Ryohei Kameyama, Kota Onozuka, Kazuki Matsuo, Shun Dekura, Kazuyoshi Yoshimi, Hatsumi Mori Oligomer-based charge-transfer complexes display a diversified carrier-to-carrier Coulomb repulsion (Ueff) and intermolecular interactions (W), enabling flexible tuning of electrical conductivities. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - November 14, 2023 Category: Chemistry Authors: Tomoko Fujino Source Type: research

Flow cells and reactor design: general discussion
DiscussionAnas Alkayal, Micka ël Avanthay, Belen Batanero, Pim Broersen, Richard C. D. Brown, Luke Chen, Ping-Chang Chuang, Toshio Fuchigami, Shinsuke Inagi, Dipannita Kalyani, Kevin Lam, Maya Landis, T. Leo Liu, Matthew J. Milner, Robert Price, Naoki Shida, Thomas Wirth To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - October 18, 2023 Category: Chemistry Authors: Anas Alkayal Source Type: research

A lithium –air battery and gas handling system demonstrator
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Jack W. Jordan, Ganesh Vailaya, Conrad Holc, Max Jenkins, Rory C. McNulty, Constantin Puscalau, Begum Tokay, Andrea Laybourn, Xiangwen Gao, Darren A. Walsh, Graham N. Newton, Peter G. Bruce, Lee R. Johnson A Li –air battery is described with in-line gas handling that allows control over the flow and composition of the gas supplied to the cell, allowing simultaneous evaluation of the cell and scrubber performance. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The R...
Source: RSC - Faraday Discuss. latest articles - October 17, 2023 Category: Chemistry Authors: Jack W. Jordan Source Type: research

Insight into the K channel's selectivity from binding of K+, Na+ and water to N-methylacetamide
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Mark J. Stevens, Susan L. B. Rempe Binding site occupancy and the mechanism of K selectivity involve multiple K binding in multiple neighboring layers, or sites, of the K channel selectivity filter. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - October 16, 2023 Category: Chemistry Authors: Mark J. Stevens Source Type: research

An organic transistor for detecting the oxidation of an organic sulfur compound at a solid-liquid interface and its chemical sensing applications
Faraday Discuss., 2023, Accepted Manuscript DOI: 10.1039/D3FD00149K, PaperYui Sasaki, Yijing Zhang, Kohei Ohshiro, Kazuhiko Tsuchiya, Xiaojun Lyu, Masao Kamiko, Yoshinori Ueno, Hikaru Tanaka, Tsuyoshi Minami The development of chemical sensors has been promoted with an increase in demand, whereas the potential of chemical sensors as devices to monitor organic reactions has not been revealed yet.... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - October 16, 2023 Category: Chemistry Authors: Yui Sasaki Source Type: research

Unraveling the solvent stability on the cathode surface of Li –O2 batteries by using in situ vibrational spectroscopies
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Aimin Ge, Ryuuta Nagai, Kota Nemoto, Bingbing Li, Koki Kannari, Ken-ichi Inoue, Shen Ye The stability of a series of glyme solvents with different chain lengths during ORR/OER has been investigated usingin situ vibrational spectroscopy measurements. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - October 16, 2023 Category: Chemistry Authors: Aimin Ge Source Type: research

Bio-based ether solvent and ionic liquid electrolyte for sustainable sodium –air batteries
Faraday Discuss., 2023, Advance Article DOI: 10.1039/D3FD00096F, PaperPierre L. Stigliano, Nagore Ortiz-Vitoriano, Lidia Medinilla, Jason E. Bara, Juan Miguel L ópez del Amo, Luis Lezama, Maria Forsyth, David Mecerreyes, Cristina Pozo-Gonzalo A green, low-toxic diglyme isomer, 1,2,3-trimethoxypropane, has been studied, for the first time, as the electrolyte in sodium –air batteries reaching 2.31 mA h cm−2 discharge capacity and with NaO2 as the main discharge product. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemist...
Source: RSC - Faraday Discuss. latest articles - October 10, 2023 Category: Chemistry Authors: Pierre L. Stigliano Source Type: research