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Observation of cavitation dynamics in viscous deep eutectic solvents during power ultrasound sonication
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Ben Jacobson, Shida Li, Paul Daly, Christopher E Elgar, Andrew Feeney, Paul Prentice, Andrew P Abbott Deep Eutectic Solvents (DESs) are a class of ionic liquid with emerging applications in ionometallurgy. The characteristic high viscosity of DESs, however, limit mass transport and result in slow dissolution... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - March 15, 2024 Category: Chemistry Authors: Ben Jacobson Source Type: research

Overdetermination Method for Accurate Dynamic Ion Correlations in Highly Concentrated Electrolytes
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Bernhard Roling, Tabita Pothmann, Maleen Middendorf, Monika Sch önhoff, Christian Gerken, Pinchas Nürnberg Highly concentrated battery electrolytes exhibit a low flammability as well as a high thermal and electrochemical stability, and they typically form stable solid electrolyte interphases in contact to electrode materials.... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - March 15, 2024 Category: Chemistry Authors: Bernhard Roling Source Type: research

Overcoming passivation through improved mass transport in dense ionic fluids
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Evangelia Daskalopoulou, Philip Hunt, Christopher E Elgar, Minjun Yang, Andrew P Abbott, Jennifer Hartley Deep Eutectic Solvents (DESs) have recently been shown to be part of a dense ionic fluid continuum between ionic liquids and concentrated aqueous brines. Charge transport was shown to be... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - March 13, 2024 Category: Chemistry Authors: Evangelia Daskalopoulou Source Type: research

Identification of reaction intermediates in the decomposition of formic acid on Pd
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Jan Fingerhut, Lo ïc Lecroart, Michael Schwarzer, Stefan Hörandl, Dmitriy Borodin, Alexander Kandratsenka, Alec M Wodtke, Daniel J Auerbach, Theofanis N. Kitsopoulos Uncovering the role of reaction intermediates is crucial to developing an understanding of heterogeneous catalysis because catalytic reactions often involve complex networks of elementary steps. Unfortunately, the short lifetimes and... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - March 7, 2024 Category: Chemistry Authors: Jan Fingerhut Source Type: research

Tuning peroxidase activity of artificial P450 peroxygenase by engineering redox-sensitive residues
Faraday Discuss., 2024, Accepted Manuscript DOI: 10.1039/D4FD00008K, PaperFengjie Jiang, Zihan Wang, Zhiqi Cong Cytochrome P450 monooxygenases (P450s) are well recognized as versatile bio-oxidation catalysts. However, the catalytic functions of P450s are highly dependent on NAD(P)H and the redox partner proteins. Our group has... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - March 7, 2024 Category: Chemistry Authors: Fengjie Jiang Source Type: research

An Efficient Pyrrolysyl-tRNA Synthetase for Economical Production of MeHis-containing Enzymes
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Amy Elizabeth Hutton, Jake Foster, James E. J. Sanders, Christopher J Taylor, Stefan A Hoffmann, Yizhi Cai, Sarah Louise Lovelock, Anthony Green Genetic code expansion has emerged as a powerful tool in enzyme design and engineering, providing new insights into sophisticated catalytic mechanisms and enabling the development of enzymes with new catalytic... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - March 7, 2024 Category: Chemistry Authors: Amy Elizabeth Hutton Source Type: research

Adsorption and Vibrational Spectroscopy of CO on the Surface of MgO from Periodic Local Coupled-Cluster Theory
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Hong-Zhou Ye, Timothy C. Berkelbach The adsorption of CO on the surface of MgO has long been a model problem in surface chemistry. Here, we report periodic Gaussian-based calculations for this problem using second-order perturbation... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - March 7, 2024 Category: Chemistry Authors: Hong-Zhou Ye Source Type: research

Heterogeneous Li coordination in Solvent-in-Salt electrolytes enables high Li transference numbers
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Anne Hockmann, Florian Ackermann, Diddo Diddens, Isidora Cekic-Laskovic, Monika Sch önhoff The transport properties and the underlying coordination structure of a ternary electrolyte consisting of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), 1,2-dimethoxyethane (DME), and 1,3-dioxolane (DOL) is studied over a wide concentration range up... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - March 6, 2024 Category: Chemistry Authors: Anne Hockmann Source Type: research

Degradation of PET microplastic particles to monomers in human serum by PETase
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Ximena Lopez-Lorenzo, David Hueting, Eliott Bosshard, Per-Olof Syr én More than 8 bton of plastic waste has been generated posing severe environmental consequences and health risks. Due to prolonged exposure, microplastic particles are found in human blood and other... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - March 4, 2024 Category: Chemistry Authors: Ximena Lopez-Lorenzo Source Type: research

Developing Deprotectase Biocatalysts for Synthesis.
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Lisa Kennedy, Mariyah Sajjad, Michael Herrera, Peter Szieber, Natasza Rybacka, Yinan Zhao, Craig Steven, Zainab Alghamdi, Ivan Zlatkov, Julie Hagen, Chloe Lauder, Natalie Rudolfova, Magdalena Abramiuk, Karolina Bolimowska, Daniel Joynt, Angelica Lucero, Gustavo Perez Ortiz, Annamaria Lilienkampf, Alison N Hulme, Dominic James Campopiano Organic synthesis often requires multiple steps where a functional group (FG) is concealed from reaction by a protecting group (PG). Common PGs include N-carbobenzyloxy (Cbz or Z) of amines and... The content ...
Source: RSC - Faraday Discuss. latest articles - March 2, 2024 Category: Chemistry Authors: Lisa Kennedy Source Type: research

Friends and Relatives: Insight Into Conformational Regulation from Orthologues and Evolutionary Lineages using KIF and KIN
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Dariia Yehorova, Rory M. Crean, Peter M Kasson, Shina Caroline Lynn Kamerlin Noncovalent interaction networks provide a powerful means to represent and analyze protein structure. Such networks can represent both static structures and dynamic conformational ensembles. We have recently developed two tools... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - March 1, 2024 Category: Chemistry Authors: Dariia Yehorova Source Type: research

Vibrational energy transfer in ammonia-helium collisions
This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.J érôme Loreau, Ad van der Avoird While the rotational energy transfer of ammonia by rare gas atoms and hydrogen molecules has been the focus of many studies, little is known about its vibrational relaxation, even though... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - February 28, 2024 Category: Chemistry Authors: J érôme Loreau Source Type: research

Exploring the Selectivity of Cytochrome P450 for Enhanced Novel Anticancer Agent Synthesis
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Janko Čivić, Neil Rory Mcfarlane, Joleen Masschelein, Jeremy Harvey Cytochrome P450 monooxygenases are an extensive and unique class of enzymes, which can regio- and stereo-selectively functionalise hydrocarbons by way of oxidation reactions. These enzymes are naturally occurring but have... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - February 28, 2024 Category: Chemistry Authors: Janko Čivić Source Type: research

Organic neuromorphics and bioelectronics: general discussion
DiscussionCatherine  M. Aitchison, Ken Albrecht, Kunio Awaga, Joseph Cameron, Przemyslaw Data, Florian Glöcklhofer, Xugang Guo, Martin Heeney, Zachary M. Hudson, Yutaka Ie, Christine K. Luscombe, Takumi Matsuo, Takashi Nakanishi, Nako Nakatsuka, Hiroyuki Nishide, Yui Sasaki, Bob C. Schroeder, Manpreet Singh, Peter Sk abara, Youhei Takeda, Yosuke Tani, Luisa Torsi, Youichi Tsuchiya, Taro Uematsu, Deepak Yadav, Nobuhiro Yanai To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - February 23, 2024 Category: Chemistry Authors: Catherine  M. Aitchison Source Type: research

Organic thermoelectrics: general discussion
DiscussionCatherine  M. Aitchison, Kunio Awaga, Przemyslaw Data, Tsuyohiko Fujigaya, Tomoko Fujino, Aiko Fukazawa, Xugang Guo, Martin Heeney, Yutaka Ie, Sakura Nakagawa, Masakazu Nakamura, Nako Nakatsuka, Hiroyuki Nishide, Bob C. Schroeder, Peter Skabara, Manpreet Singh, Yosuke Tani, Yuya Tanaka, Youichi Tsuchiya, Tar o Uematsu, Yumi Yakiyama To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - Faraday Discuss. latest articles)
Source: RSC - Faraday Discuss. latest articles - February 22, 2024 Category: Chemistry Authors: Catherine  M. Aitchison Source Type: research