Quantification of ultra-trace organolead species in environmental water by inductively coupled plasma mass spectrometry with online solid-phase extraction and high performance liquid chromatographic separation.

Quantification of ultra-trace organolead species in environmental water by inductively coupled plasma mass spectrometry with online solid-phase extraction and high performance liquid chromatographic separation. Anal Chim Acta. 2020 Oct 09;1133:30-38 Authors: Yang S, Song Y, Ma Q, Cheng H, Wang Y, Liu J Abstract Quantification of organolead compounds in environmental water is an essential task considering much higher toxicity and bioavailability of organolead species than inorganic plumbic ions. However, the speciation of ultra-trace organolead compounds at sub ng L-1 levels is challengeable for current instruments incorporating high performance liquid chromatography with inductively coupled plasma mass spectrometry (HPLC-ICP-MS) and even offline enrichment that offer detection limits around several to tens of ng L-1. In this paper, an online solid-phase extraction (SPE) coupled HPLC-ICP-MS method was developed for speciation analysis of trace lead in water. Graphene oxide bounded silica particles (GO@SiO2) was utilized as the SPE adsorbent because of its superior performance over graphene bounded silica particles and commercial C18 packing particles. High enrichment factors (1603 for TML and 1376 for TEL) were obtained when lead species in 10 mL sample was adsorbed by 1 mM sodium dodecyl benzene sulfonate (SDBS) preconditioned GO@SiO2 at 10 mL min-1 and then eluted by 5 μL of 5 mM SDBS. Because of the highly efficient preconce...
Source: Analytica Chimica Acta - Category: Chemistry Authors: Tags: Anal Chim Acta Source Type: research