Crystalline phase transformation of electrospinning TiO2 nanofibres carried out by high temperature annealing

Publication date: Available online 24 May 2019Source: Journal of Molecular StructureAuthor(s): O. Secundino-Sánchez, J. Diaz-Reyes, J. Aguila-López, J.F. Sánchez-RamírezAbstractIn this work reports the crystalline phase transformation of electrospinning TiO2 nanofibres by annealing at high temperatures. The nanofibres chemical stoichiometry was determined by Energy-dispersive X-ray spectroscopy (EDS), which allowed find that the TiO2 crystal phase transformation is caused by oxygen vacancy generating. The TiO2 nanofibres diameter varied from 137.0 to 115.3 nm in the temperature range of 100-1000°C, which was estimated by Scanning Electron Microscopy. The TiO2 nanofibres structural transformation from pure anatase to pure rutile structures, including the quasi-amorphous and anatase-rutile mixed phases has been confirmed by Raman scattering and X-ray diffraction. The Raman spectroscopy exhibits the anomalous behaviour for band broadening and shifting of Raman bands with increasing crystallite size that form the nanofibres. By X-ray diffraction was found that the nanofibres crystalline phases present as preferential growth direction (101) for anatase and (110) for rutile.Graphical abstract
Source: Journal of Molecular Structure - Category: Molecular Biology Source Type: research