Molecules, Vol. 29, Pages 2006: Novel Star-Shaped Viologens Containing Phenyl and Triphenylamine Moieties for Electrochromic Applications

Molecules, Vol. 29, Pages 2006: Novel Star-Shaped Viologens Containing Phenyl and Triphenylamine Moieties for Electrochromic Applications Molecules doi: 10.3390/molecules29092006 Authors: Banasz Wałęsa-Chorab The two star-shaped viologens containing 1,3,5-substituted phenyl (1) and triphenylamine (2) central cores and n-hexyl chains were synthesized and characterized. Both compounds exhibited promising optoelectronic properties and underwent multiple oxidation/reduction processes resulting in various colors. Four possible redox states of tripyridium salt containing a phenyl or triphenylamine core can occur depending on the applied potentials. The wide color range, from colorless through blue, azure to green-gray, was observed during the electrochemical reduction of compound 1. In the case of compound 2, the color change observed during spectroelectrochemical measurements was from yellow to colorless during the cathodic process and from yellow to green during the anodic process. The observed color change for both viologens was reversible. The triphenylamine-cored viologen (2) also exhibited emission in visible range and solvatochromism. It also exhibited luminescence in the solid state when excited with a UV lamp. These studies provide insights into the design of advanced materials for applications in displays.
Source: Molecules - Category: Chemistry Authors: Tags: Article Source Type: research