Constructing a cellulose based chiral liquid crystal film with high flexibility, water resistance, and optical property

Int J Biol Macromol. 2023 Aug 3:126132. doi: 10.1016/j.ijbiomac.2023.126132. Online ahead of print.ABSTRACTCellulose nanocrystal (CNC) derived from cellulose can form a liquid crystal film with bright structural color by evaporative-induced self-assembly (EISA). As a new class of photonic liquid crystals material, it has attracted much attention because of its intrinsic unique structural characteristics and excellent optical properties. However, the brittleness and water sensitivity of CNC film have hindered its practical application. Herein, multiple cross-linked networks CNC/(polyethylene glycol diacrylate:polyethylene oxide) (PEGDA:PEO) composite film was prepared through EISA and UV irradiation strategies. The as-prepared film exhibits high-flexibility with a fracture strain of up to 36.40 % and strong water resistance, with water absorption at an equilibrium of only 17.41 %. Moreover, the film retains its structural color in aqueous solution for a long time due to its water stability. The outstanding flexibility and water resistance of CNC composite film are attributed to multiple crosslinked networks (i.e. PEGDA, PEO, and PEDGA-PEO networks), which endow the film with excellent stress dispersion and transferability when stretched and limit film swelling in water without affecting chiral nematic structures of CNC. Overall, this work provides a promising strategy to prepare CNC-based film with high-flexibility, water resistance, and optical property for applications like ...
Source: International Journal of Biological Macromolecules - Category: Biochemistry Authors: Source Type: research