Studies of pure and nitrogen gas mixed xenon ECR plasma: Signature of abundance dependent unusual trends in isotope anomaly

We report the effect of N2 gas-mixing in the xenon electron cyclotron resonance (ECR) plasma, and abundance-dependent novel, exciting and unusual trends of the isotope anomaly. The xenon plasma was produced using a 10 GHz all-permanent-magnet NANOGAN ECR ion source, and the charge state distributions of naturally abundant six stable xenon isotopes with and without N2 gas-mixing (at 25%, 50%, and 75%) were recorded. The intensity ratio of the heavier to lighter isotope, where the heavier isotope is less abundant, showed a clear signature of the isotope anomaly as explained by the linear Landau wave damping theory. Contrary to the theoretical prediction that the isotope anomaly should vanish with a relatively large fraction of the heavier isotope in mixed plasmas, the trends of intensity ratios observed in such cases are very unusual and have almost the mirror-symmetrical shapes of those trends recorded with less abundant heavier isotope. Further, the effect of relative mass difference on the isotope anomaly was also evidenced. The N2 gas-mixing of the xenon plasma at 25% and 50% shifted the entire charge state distribution toward the higher intensity side owing to the supply of additional electrons that caused high ionization efficiency. However, a prominent gas-mixing effect was observed at 75% of N2 mixing in the xenon plasma beyond the +7 charge state. The abundance-dependent unusual trends in isotope anomaly have been explained by considering different ionic temperatures, ...
Source: Journal of Mass Spectrometry - Category: Chemistry Authors: Tags: RESEARCH ARTICLE Source Type: research