Anti-Freezing Electrolytes in Aqueous Multivalent Metal-Ion Batteries: Progress, Challenges, and Optimization Strategies
Chem Rec. 2023 Aug 22:e202300212. doi: 10.1002/tcr.202300212. Online ahead of print.ABSTRACTAqueous rechargeable multivalent metal-ion batteries (ARMMBs) have attracted considerable attention due to their high capacity, high energy density, and low cost. However, their performance is often limited by low temperature operation, which requires the development of anti-freezing electrolytes. In this review, we summarize the anti-freezing mechanisms and optimization strategies of anti-freezing electrolytes for aqueous batteries (especially for Zn-ion batteries). Besides, we investigate the possible interactions and side reactio...
Source: Chemical Record - August 22, 2023 Category: Chemistry Authors: Hongfei Bao Hele Guo Xuan Zhang Zhihong Tian Jiajia Huang Tianxi Liu Feili Lai Source Type: research

Development of Membranes and Separators to Inhibit Cross-Shuttling of Sulfur in Polysulfide-Based Redox Flow Batteries: A Review
Chem Rec. 2023 Aug 22:e202300171. doi: 10.1002/tcr.202300171. Online ahead of print.ABSTRACTThe global rapid transition from fossil fuels to renewable energy resources necessitates the implementation of long-duration energy storage technologies owing to the intermittent nature of renewable energy sources. Therefore, the deployment of grid-scale energy storage systems is inevitable. Sulfur-based batteries can be exploited as excellent energy storage devices owing to their intrinsic safety, low cost of raw materials, low risk of environmental hazards, and highest theoretical capacities (gravimetric: 2600 Wh/kg and volumetric...
Source: Chemical Record - August 22, 2023 Category: Chemistry Authors: Ibad Ali Khan Atif Saeed Alzahrani Shahid Ali Muhammad Mansha Muhammad Nawaz Tahir Majad Khan Hafiz Adil Qayyum Safyan Akram Khan Source Type: research

Cyclic Sulfinamides
Chem Rec. 2023 Aug 18:e202300221. doi: 10.1002/tcr.202300221. Online ahead of print.ABSTRACTThe literature on cyclic sulfinamides (put simply, sultims) published from 1989 to 2022 has been summarized and reviewed. The information is divided into two sections: the analysis of synthetic methods on the preparation of cyclic sulfinamides and the discussion of the chemical properties of cyclic sulfinamides focusing on their reactions and applications. The survey of the reaction conditions, provided in the most detailed way, and a critical view of the reaction mechanisms add an extra dimension to the text. The data presented wil...
Source: Chemical Record - August 18, 2023 Category: Chemistry Authors: Alexey V Dobrydnev Maria V Popova Yulian M Volovenko Source Type: research

Cyclic Sulfinamides
Chem Rec. 2023 Aug 18:e202300221. doi: 10.1002/tcr.202300221. Online ahead of print.ABSTRACTThe literature on cyclic sulfinamides (put simply, sultims) published from 1989 to 2022 has been summarized and reviewed. The information is divided into two sections: the analysis of synthetic methods on the preparation of cyclic sulfinamides and the discussion of the chemical properties of cyclic sulfinamides focusing on their reactions and applications. The survey of the reaction conditions, provided in the most detailed way, and a critical view of the reaction mechanisms add an extra dimension to the text. The data presented wil...
Source: Chemical Record - August 18, 2023 Category: Chemistry Authors: Alexey V Dobrydnev Maria V Popova Yulian M Volovenko Source Type: research

Cyclic Sulfinamides
Chem Rec. 2023 Aug 18:e202300221. doi: 10.1002/tcr.202300221. Online ahead of print.ABSTRACTThe literature on cyclic sulfinamides (put simply, sultims) published from 1989 to 2022 has been summarized and reviewed. The information is divided into two sections: the analysis of synthetic methods on the preparation of cyclic sulfinamides and the discussion of the chemical properties of cyclic sulfinamides focusing on their reactions and applications. The survey of the reaction conditions, provided in the most detailed way, and a critical view of the reaction mechanisms add an extra dimension to the text. The data presented wil...
Source: Chemical Record - August 18, 2023 Category: Chemistry Authors: Alexey V Dobrydnev Maria V Popova Yulian M Volovenko Source Type: research