Consecutive one-/two-step relaxation transformations of single-molecule magnets via coupling dinuclear dysprosium compounds with chloride bridges.

Consecutive one-/two-step relaxation transformations of single-molecule magnets via coupling dinuclear dysprosium compounds with chloride bridges.
Chem Commun (Camb). 2018 Oct 10;:
Authors: Tian H, Wang BL, Lu J, Liu HT, Su J, Li D, Dou J
Abstract
The double chloride-bridged dimer of a dinuclear dysprosium(iii) single-molecule magnet (SMM) was successfully isolated by assembling centrosymmetric dinuclear Dy2 SMMs. Such structural transformation involves the generation and cleavage of chloride bridges and leads to consecutive transformations of one- and two-step slow relaxation of magnetization.
PMID: 30302448 [PubMed - as supplied by publisher]

Source: Chemical Communications - October 10, 2018 Category: Chemistry Authors: Tian H, Wang BL, Lu J, Liu HT, Su J, Li D, Dou J Tags: Chem Commun (Camb) Source Type: research