Convenient Synthesis of 2-Amino-3-(arylthio)indoles via Rh-Catalyzed Reaction of 3-Diazoindol-2-imines with Thioesters

Org. Biomol. Chem., 2017, Accepted Manuscript DOI: 10.1039/C7OB02597A, PaperFanghui Ma, Jing Qian, Ping Lu, Yanguang Wang 2-Amino-3-(arylthio)indoles were conveniently synthesized via the Rh(II)-catalyzed C-S/N-C coupling reaction between 3-diazoindol-2-imines and thioesters. The products could be further oxidized to 2-amino-3-(arylsulfonyl)indoles by m-chloroperbenzoic acid and the N-sulfonyl group could... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Organic and Biomolecular Chemistry - Category: Molecular Biology Authors: Source Type: research