Intramolecular Nucleophilic Addition of Carbanions Generated from N-Benzylamides to Cyclopropenes

Org. Biomol. Chem., 2017, Accepted Manuscript DOI: 10.1039/C7OB02068F, PaperVladimir A Maslivetc, Colby Barrett, Nicolai A Aksenov, Marina Rubina, Michael Rubin Unusual reaction is described, involving a formal intramolecular nucleophilic substitution of bromocyclopropanes with nitrogen ylides generated in situ from N-benzyl carboxamides. It is shown that this reaction involves cyclopropene intermediates... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Organic and Biomolecular Chemistry - Category: Molecular Biology Authors: Source Type: research