One-step synthesis of Pd-NPs@Cu2(BDC)2DABCO as efficient heterogeneous catalyst for the Suzuki –Miyaura cross-coupling reaction

Publication date: 15 December 2017 Source:Journal of Organometallic Chemistry, Volume 853 Author(s): Sharareh Tahmasebi, Javad Mokhtari, Mohammad Reza Naimi-Jamal, Armaqan Khosravi, Leila Panahi A new heterogeneous palladium catalyst has been synthesized by one-step encapsulation in nanoporous metal-organic framework Cu2(BDC)2(DABCO) (BDC = 1,4-benzenedicarboxylate, DABCO = 1,4-diazabicyclo[2.2.2]octane) under a temperature control program. Supported Pd nanoparticles (Pd-NPs@Cu2(BDC)2(DABCO)) were characterized by X-ray diffraction, BET analysis, field emission scanning electron microscopy, transmission electron microscopy, inductively coupled plasma atomic emission and X-ray photoelectron spectroscopy (XPS). The Highly dispersed Pd particles (Pd-NPs@Cu2(BDC)2(DABCO)) offered a very efficient catalytic activity towards the Suzuki–Miyaura cross-coupling reaction. Graphical abstract
Source: Journal of Organometallic Chemistry - Category: Chemistry Source Type: research