Study of Intermediates in Iridium –(Phosphoramidite,Olefin)-Catalyzed Enantioselective Allylic Substitution - Journal of the American Chemical Society (ACS Publications)

Study of Intermediates in Iridium –(Phosphoramidite,Olefin)-Catalyzed Enantioselective Allylic Substitution - Journal of the American Chemical Society (ACS Publications)Experimental mechanistic studies of iridium-catalyzed, enantioselective allylic substitution enabled by (phosphoramidite,olefin) ligands are reported. ( η2-Allylic alcohol)iridium(I) and ( η3-allyl)iridium(III) complexes were synthesized and characterized by NMR spectroscopy as well as X-ray crystallography. 
Source: Organometallic Current - Category: Chemistry Tags: Allylic Ir catalyzed Source Type: blogs