Sensors, Vol. 24, Pages 2599: Co3O4-Based Materials as Potential Catalysts for Methane Detection in Catalytic Gas Sensors
Sensors, Vol. 24, Pages 2599: Co3O4-Based Materials as Potential Catalysts for Methane Detection in Catalytic Gas Sensors
Sensors doi: 10.3390/s24082599
Authors:
Olena Yurchenko
Patrick Diehle
Frank Altmann
Katrin Schmitt
Jürgen Wöllenstein
The present work deals with the development of Co3O4-based catalysts for potential application in catalytic gas sensors for methane (CH4) detection. Among the transition-metal oxide catalysts, Co3O4 exhibits the highest activity in catalytic combustion. Doping Co3O4 with another metal can further improve its catalytic performance. Despite their promising properties, Co3O4 materials have rarely been tested for use in catalytic gas sensors. In our study, the influence of catalyst morphology and Ni doping on the catalytic activity and thermal stability of Co3O4-based catalysts was analyzed by differential calorimetry by measuring the thermal response to 1% CH4. The morphology of two Co3O4 catalysts and two NixCo3−xO4 with a Ni:Co molar ratio of 1:2 and 1:5 was studied using scanning transmission electron microscopy and energy dispersive X-ray analysis. The catalysts were synthesized by (co)precipitation with KOH solution. The investigations showed that Ni doping can improve the catalytic activity of Co3O4 catalysts. The thermal response of Ni-doped catalysts was increased by more than 20% at 400 °C and 450 °C compared to one of the studied Co3O4 oxides. However, the thermal response of t...
Source: Sensors - Category: Biotechnology Authors: Olena Yurchenko Patrick Diehle Frank Altmann Katrin Schmitt J ürgen Wöllenstein Tags: Article Source Type: research