Fluorenyl-tethered N-heterocyclic carbene (NHC): an exclusive C-donor ligand for heteroleptic calcium and strontium chemistry

We report herein the aptitude of a combination of NHC with fluorenyl connected by a flexible -(CH2)2- linker as a ligand support for heteroleptic Ca- and Sr-N(SiMe3)2 and iodides. The Ca-N(SiMe3)2 complex even catalyzes the intramolecular hydroamination of aminoalkenes to showcase the effectiveness of this ligand framework.PMID:38568715 | DOI:10.1039/d4cc00397g

Source: Chemical Communications - April 3, 2024 Category: Chemistry Authors: Sumana Mondal Subham Sarkar Chhotan Mandal Dibyendu Mallick Debabrata Mukherjee Source Type: research