Conjugated Polymers with Self ‐Immolative Sidechain Linkers for Carbon Nanotube Dispersion

Single-walled carbon nanotubes (SWNTs) are selectively dispersed with a novel poly(fluorene-co-phenylene) having a self-immolative linker within its sidechains. Cleavage of the linker causes rapid removal of the sidechains, allowing the SWNTs to closely contact one another. Within a thin film, this led to an immediate 60-fold increase in conductivity, opening new possibilities for producing high-conductivity SWNT materials for numerous applications. AbstractSingle-walled carbon nanotubes (SWNTs) are promising materials for generating high-performance electronic devices. However, these applications are greatly restricted by their lack of purity and solubility. Commercially available SWNTs are a mixture of semi-conducting (sc-) and metallic (m-) SWNTs and are insoluble in common solvents. Conjugated polymers can selectively disperse either sc- or m-SWNTs and increase their solubility; however, the conductivity of conjugated polymer-wrapped SWNTs is largely affected by the polymer side chains. Here, a poly(fluorene-co-phenylene) polymer that contains a self-immolative linker as part of its sidechains is reported. The self-immolative linker is stabilized with a tert-butyldimethylsilyl ether group that, upon treatment with tetra-n-butylammonium fluoride (TBAF), undergoes a 1,6-elimination reaction to release the sidechain. Sonication of this polymer with SWNTs in tetrahydrofuran (THF) results in concentrated dispersions that are used to prepare polymer-SWNT thin films. Treatment w...
Source: Small - Category: Nanotechnology Authors: Tags: Research Article Source Type: research