Water and Oxygen Barrier Properties of All-Cellulose Nanocomposites

Biomacromolecules. 2024 Feb 23. doi: 10.1021/acs.biomac.3c01337. Online ahead of print.ABSTRACTHydroxypropyl cellulose (HPC) is potentially interesting as a biobased, rigid food packaging material, but its stiffness and strength are somewhat low, and its water and oxygen transport rates are too high. To improve these characteristics, we investigated nanocomposites of HPC and cellulose nanocrystals (CNCs). These high-aspect-ratio nanoparticles display high stiffness and strength, and their high crystallinity renders them virtually impermeable. Exchanging the counterions of sulfate-ester decorated CNCs with cetyltrimethylammonium ions affords particles that are dispersible in ethanol (CTA.CNC) and allows solvent casting of HPC/CTA.CNC nanocomposite films, which, even at a CTA.CNC content of 90 wt %, are highly transparent. The introduction of CTA.CNC considerably increases the Young's modulus (Ey) and upper tensile strength (σUTS). For example, in the nanocomposite with 90% CTA.CNC, Ey = 7.6 GPa is increased 20-fold and σUTS = 42.7 MPa is more than doubled in comparison to HPC, whereas the extensibility (1.1%) remains appreciable. Composites with a CTA.CNC content of 70 wt % or less show a lower water vapor permeability (6.4-9.2 × 10-5 g μm m-2 s-1 Pa-1) than the neat HPC (1.5 × 10-4 g μm m-2 s-1 Pa-1), whereas the oxygen permeability (5.6 × 10-7-1.3 × 10-6 cm3 μm m-2 s-1 Pa-1) is reduced by 1 order of magnitude compared to HPC (3.2 × 10-6 cm3 μm m-2 s-1 Pa-1). The b...
Source: Biomacromolecules - Category: Biochemistry Authors: Source Type: research