Relative extents, mechanisms, and kinetics of fluoride removal from synthetic groundwater by prevalent sorbents

Chemosphere. 2023 Sep 14:140161. doi: 10.1016/j.chemosphere.2023.140161. Online ahead of print.ABSTRACTFluoride (F) contamination in groundwater affects millions of people across the world. Although several sorbents have been identified for low-cost F removal, the choice of the optimal sorbent is dictated by the specific chemistry of contaminated groundwater. In this contribution, eight prevalent sorbents-activated alumina (AA), calcite, hydroxyapatite-coated calcite (HCC), natural chitosan, chalk, Mg-Al-CO3 layered double hydroxide (LDH), calcined Mg-Al-CO3 LDH (cLDH), and hydrous ferric oxide (HFO)-were categorized on their relative F removal mechanisms, extents, and kinetics from a typical synthetic groundwater, representative of contaminated aquifers of North India. Initially, batch experiments containing sorbents at 4 g L-1 were conducted at a high F concentration (2.9 mM). The dominant F removal processes were identified by aqueous- and solid-phase characterization of reaction by-products. While chalk and calcite removed F by secondary precipitation of fluorite, HCC removed F by fluorapatite precipitation, and other sorbents removed F by sorption. Depending on the immobilization mechanism identified, the F uptake kinetics on each sorbent was modeled with either pseudo-second order or generalized rate equations. Among sorptive F uptake, cLDH exhibited the highest (10-2.15 mg g-1·h-1) and HFO showed the lowest (10-4.15 mg g-1·h-1) rates. Fluoride removal by precipitatio...
Source: Chemosphere - Category: Chemistry Authors: Source Type: research